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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 11, issue 16
Atmos. Chem. Phys., 11, 8767–8775, 2011
https://doi.org/10.5194/acp-11-8767-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 11, 8767–8775, 2011
https://doi.org/10.5194/acp-11-8767-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 30 Aug 2011

Research article | 30 Aug 2011

Heterogeneous ice nucleation: exploring the transition from stochastic to singular freezing behavior

D. Niedermeier1, R. A. Shaw2, S. Hartmann1, H. Wex1, T. Clauss1, J. Voigtländer1, and F. Stratmann1 D. Niedermeier et al.
  • 1Leibniz Institute for Tropospheric Research, 04318 Leipzig, Germany
  • 2Dept. of Physics, Michigan Technological University, Houghton, Michigan 49931, USA

Abstract. Heterogeneous ice nucleation, a primary pathway for ice formation in the atmosphere, has been described alternately as being stochastic, in direct analogy with homogeneous nucleation, or singular, with ice nuclei initiating freezing at deterministic temperatures. We present an idealized, conceptual model to explore the transition between stochastic and singular ice nucleation. This "soccer ball" model treats particles as being covered with surface sites (patches of finite area) characterized by different nucleation barriers, but with each surface site following the stochastic nature of ice embryo formation. The model provides a phenomenological explanation for seemingly contradictory experimental results obtained in our research groups. Even with ice nucleation treated fundamentally as a stochastic process this process can be masked by the heterogeneity of surface properties, as might be typical for realistic atmospheric particle populations. Full evaluation of the model findings will require experiments with well characterized ice nucleating particles and the ability to vary both temperature and waiting time for freezing.

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