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Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
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Volume 11, issue 7 | Copyright
Atmos. Chem. Phys., 11, 3303-3318, 2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 07 Apr 2011

Research article | 07 Apr 2011

A two-dimensional volatility basis set: 1. organic-aerosol mixing thermodynamics

N. M. Donahue, S. A. Epstein, S. N. Pandis, and A. L. Robinson N. M. Donahue et al.
  • Carnegie Mellon University Center for Atmospheric Particle Studies, Pittsburgh, USA

Abstract. We develop the thermodynamic underpinnings of a two-dimensional volatility basis set (2D-VBS) employing saturation mass concentration (Co) and the oxygen content (O:C) to describe volatility, mixing thermodynamics, and chemical evolution of organic aerosol. The work addresses a simple question: "Can we reasonably constrain organic-aerosol composition in the atmosphere based on only two measurable organic properties, volatility and the extent of oxygenation?" This is an extension of our earlier one-dimensional approach employing volatility only (C* = γ Co, where γ is an activity coefficient). Using available constraints on bulk organic-aerosol composition, we argue that one can reasonably predict the composition of organics (carbon, oxygen and hydrogen numbers) given a location in the Co – O:C space. Further, we argue that we can constrain the activity coefficients at various locations in this space based on the O:C of the organic aerosol.

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