1Trent University, Peterborough, Ontario, Canada
2La Trobe University, Victoria, Australia
3Formerly at the University of Saskatchewan, Saskatoon, Canada
Received: 17 Jun 2008 – Published in Atmos. Chem. Phys. Discuss.: 30 Jul 2008 – Published: 06 Feb 2009
Abstract. We present the hypothesis of homogeneous nucleation of ice nano-particles in the polar summer mesosphere. The nucleation of condensed phase is traced back to the first step on the formation pathway, which is assumed to be the transition of water vapor to amorphous cluster. Amorphous clusters then freeze into water ice, likely metastable cubic ice, when they reach the critical size. The estimates based on the equilibrium thermodynamics give the critical size (radius) of amorphous water clusters as about 1.0 nm. The same estimates for the final transition step, that is the transformation of cubic to hexagonal ice, give the critical size of about 15 nm at typical upper mesospheric conditions during the polar summer (temperature T=150 K, water vapor density ρvapor=109 cm−3).
Citation: Zasetsky, A. Y., Petelina, S. V., and Svishchev, I. M.: Thermodynamics of homogeneous nucleation of ice particles in the polar summer mesosphere, Atmos. Chem. Phys., 9, 965-971, doi:10.5194/acp-9-965-2009, 2009.