Hit from both sides: tracking industrial and volcanic plumes in Mexico City with surface measurements and OMI SO2 retrievals during the MILAGRO field campaign 1Department of Earth and Atmospheric Sciences, Saint Louis University, St. Louis, MO, USA
2Goddard Earth Sciences and Technology Center, University of Maryland, MD, USA
3Molina Center for Energy and the Environment, La Jolla, CA, USA
4Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA, USA
5Aerodyne Research Inc., Billerica, MA, USA
6Georgia Institute of Technology, Atlanta, GA, USA
7General Direction of the National Center for Environmental Research and Training (CENICA), National Institute of Ecology (INE), Mexico
8Centro de Ciencias de la Atmósfera, Universidad Nacional Autónoma de México, Mexico
Received: 17 Jul 2009 – Published in Atmos. Chem. Phys. Discuss.: 06 Aug 2009 Abstract. Large sulfur dioxide plumes were measured in the
Mexico City Metropolitan Area (MCMA) during the MILAGRO field campaign.
This paper seeks to identify the sources of these plumes and the
meteorological processes that affect their dispersion in a complex
Surface measurements of SO2 and winds are analysed in combination
with radar wind profiler data to identify transport directions.
Satellite retrievals of vertical SO2 columns from the Ozone
Monitoring Instrument (OMI) reveal the dispersion from both the Tula
industrial complex and the Popocatepetl volcano.
Oversampling the OMI swath data to a fine grid (3 by 3 km)
and averaging over the field campaign yielded a high resolution image of
the average plume transport.
Numerical simulations are used to identify possible transport scenarios.
The analysis suggests that both Tula and Popocatepetl contribute
to SO2 levels in the MCMA, sometimes on the same day due
to strong vertical wind shear.
During the field campaign, model estimates suggest that the volcano
accounts for about one tenth of the SO2 in the MCMA, with a roughly
equal split for the rest between urban sources and the Tula industrial complex.
The evaluation of simulations with known sources and pollutants suggests
that the combination of observations and meteorological models
will be useful in identifying sources and transport processes
of other plumes observed during MILAGRO.
Revised: 03 Dec 2009 – Accepted: 04 Dec 2009 – Published: 22 Dec 2009
Citation: de Foy, B., Krotkov, N. A., Bei, N., Herndon, S. C., Huey, L. G., Martínez, A.-P., Ruiz-Suárez, L. G., Wood, E. C., Zavala, M., and Molina, L. T.: Hit from both sides: tracking industrial and volcanic plumes in Mexico City with surface measurements and OMI SO2 retrievals during the MILAGRO field campaign, Atmos. Chem. Phys., 9, 9599-9617, doi:10.5194/acp-9-9599-2009, 2009.