1Spectroscopie de l'Atmosphère, Service de Chimie Quantique et de Photophysique, Université Libre de Bruxelles, Brussels, Belgium
2UPMC Univ. Paris 06; Université Versailles St-Quentin; CNRS/INSU, LATMOS-IPSL, Paris, France
*now at: Laboratoire d'Optique Atmosphérique, Université des Sciences et Technologies de Lille, 59655 Villeneuve d'Ascq cedex, France
**respectively Research Associate and Scientific Research Worker with the F.N.R.S., Belgium
Received: 19 Feb 2009 – Discussion started: 08 Apr 2009
Abstract. In this paper we analyze distributions of water vapour isotopologues in the troposphere using infrared spectra recorded by the Infrared Atmospheric Sounding Interferometer (IASI), which operates onboard the Metop satellite in nadir geometry. The simultaneous uncorrelated retrievals of H216O and HDO are performed on radiance measurements using a line-by-line radiative transfer model and an inversion procedure based on the Optimal Estimation Method (OEM). The characterizations of the retrieved products in terms of vertical sensitivity and error budgets show that IASI measurements contain up to 6 independent pieces of information on the vertical distribution of H216O and up to 3.5 for HDO from the surface up to the upper troposphere (0–20 km). Although the purpose of the paper is not validation, a restricted comparison with sonde measurements shows that the retrieved H216O profiles capture the seasonal/latitudinal variations of the water content, with good accuracy in the lowest layer but with larger uncertainties higher in the free and upper troposphere. Our results then demonstrate the ability of the IASI instrument to monitor atmospheric isotopologic water vapour distributions and to provide information on the partitioning of HDO as compared to H216O. The derivation of the δD is challenging and associated with large errors in the uncorrelated retrieval approach chosen here. As a result averaging on the vertical to produce a column-averaged δD is required to produce meaningful results for geophysical interpretation. As a case study, we analyse concentration distributions and spatio-temporal variations of H216O and δD during the October 2007 Krosa super-typhoon over South-East Asia. We show that individual δD have uncertainties of 37‰ for the vertically averaged values. Using the latter, we suggest that the typhoon produces a so-called amount-effect, where the δD is negatively correlated to the water amounts as a result of intense depletion of the deuterated species.
Revised: 19 Nov 2009 – Accepted: 25 Nov 2009 – Published: 15 Dec 2009
Herbin, H., Hurtmans, D., Clerbaux, C., Clarisse, L., and Coheur, P.-F.: H216O and HDO measurements with IASI/MetOp, Atmos. Chem. Phys., 9, 9433-9447, doi:10.5194/acp-9-9433-2009, 2009.