Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 9 21 2009 10.5194/acp-9-8199-2009 http://www.atmos-chem-phys.net/9/8199/2009/ http://www.atmos-chem-phys.net/9/8199/2009/acp-9-8199-2009.html http://www.atmos-chem-phys.net/9/8199/2009/acp-9-8199-2009.pdf 8199 8210 2009-11-02 Retrieval of water vapor profile in the mesosphere from satellite ozone and hydroxyl measurements by the basic dynamic model of mesospheric photochemical system M. Y. Kulikov kulm@appl.sci-nnov.ru A. M. Feigin G. R. Sonnemann Institute of Applied Physics of the Russian Academy of Science, Ulyanov Str. 46, 603950, Nizhny Novgorod, Russia Leibniz-Institute of Atmospheric Physics at the University Rostock in Kühlungsborn, Schloss-Str. 6, 18225 Ostseebad Kühlungsborn, Germany We propose an indirect method for retrieving a number of significant minor gas constituents of the atmosphere. The technique is based on the use of so-called basic dynamic models of atmospheric photochemical systems simplified mathematically correctly in a special manner. It is applied to a mesospheric system describing day evolution of key minor gas constituents at these heights. We take as initial data experimental data of the CRISTA-MAHRSI satellite campaign of August 1997 during which ozone and hydroxyl (O₃ and OH) concentrations were measured simultaneously. It is demonstrated that the use of the basic dynamic model allows retrieval of vertical distribution (within the 53–85 km range of heights) of water vapor concentration that is one of the control parameters of the mesospheric photochemistry. Brasseur, G. and Solomon, S.: Aeronomy of the Middle Atmosphere, 452 pp., D. Reidel, Norwell, Mass., 1986. Conway, R. R., Summers, M. E., Stevens, M. H., Cardon, J. G., Preusse, P., and Offermann, D.: Satellite observations of upper stratospheric and mesospheric OH: The HO_x dilemma, Geophys. Res. Lett., 27, 2613–2616, 2000. % Crutzen, P. J., Grooß, J.-U., Brühl, C., Müller, R., and Russel %III, R. J. M.: A reevaluation of the ozone budget with HALOE UARS data: No %evidence of the ozone deficit, Science, 268, 705–708, 1995. Danilov, A. D. and Kalgin, U. A.: Seasonal and latitudinal variations of eddy diffusion-coefficient in the mesosphere and lower thermosphere, J. Atmos. Terr. Phys., 54, 1481–1489, 1992. Feigin, A. M. and Konovalov, I. B.: On the possibility of complicated dynamic behaviour of atmospheric photochemical systems: Instability of the Antarctic photochemistry during the ozone hole formation, J. Geophys. Res., 101(D), 26023–26038, 1996. Feigin, A. M., Konovalov, I. B., and Molkov, Y. I.: Towards understanding nonlinear nature of atmospheric photochemistry: Essential dynamic model of the mesospheric photochemical system, J. Geophys. Res., 103, 25447–25460, 1998. Fichtelmann, B. and Sonnemann, G.: On the variation of ozone in the upper mesosphere and lower thermosphere: a comparison between theory and observation, J. Meteorol., 39, 297–308, 1989. Grossmann, K. U., Offermann, D., Gusev, O., Oberheide, J., Riese, M., and Spang, R.: The CRISTA-2 mission, J. Geophys. Res., 107(D23), 8173, doi:10.1029/2001JD000667, 2002. Gumbel, J., Murtagh, D. P., Espy, P. J., Witt, G., and Schmidlin, F. J.: Odd oxygen measurements during the Noctilucent Cloud 93 rocket campaign, J. Geophys. Res., 103, 23399–23414, 1998. Hedin, A. E.: Extension of the MSIS thermospheric model into the middle and lower atmosphere, J. Geophys. Res., 96, 1159–1172, 1991. Hervig, M., McHugh, M., and Summers, M. E.: Water vapor enhancement in the polar summer mesosphere and its relationship to polar mesospheric clouds, Geophys. Res. Lett., 30(20), 2041, doi:10.1029/2003GL018089, 2003. Hocking, W. K.: Turbulence in the region 80–120 km, Adv. Space Res., 50, 153–161, 1990. Jucks, K. W., Johnson, D. G., Chance, K. V., Traub, W. A., Margitan, J. J., Osterman, G. B., Salawitch, R. J., and Sasano, Y.: Observations of OH, HO₂, H₂O, and O₃ in the upper stratosphere: implications for HO_x photochemistry, Geophys. Res. Lett., 25, 3935–3938, 1998. Körner, U. and Sonnemann, G. R.: Global three-dimensional modeling of the water vapor concentration of the mesosphere-mesopause region and implications with respect to the noctilucent cloud region, J. Geophys. Res., 106, 9639–9651, 2001. Kulikov, M. Y., Feigin, A. M., and Sonnemann, G. R.: Retrieval of the vertical distribution of chemical components in the mesosphere from simultaneous measurements of ozone and hydroxyl distributions, Radiophysics and Quantum Electronics, 49, 683–691, 2006. Lossow, S., Khaplanov, M., Gumbel, J., Stegman, J., Witt, G., Dalin, P., Kirkwood, S., Schmidlin, F. J., Fricke, K. H., and Blum, U.: Middle atmospheric water vapour and dynamics in the vicinity of the polar vortex during the Hygrosonde-2 campaign, Atmos. Chem. Phys., 9, 4407–4417, 2009. Lübken, F. J.: Experimental results on the role of turbulence for the heat budget of the upper atmosphere, Habilitation Thesis, 160 pp., Bonn University, 1993. Lübken, F. J.: Seasonal variation of turbulent energy dissipation rates at high latitudes as determined by in situ measurements of neutral density fluctuations, J. Geophys. Res., 102, 13441–13456, 1997. McHugh, M., Hervig, M., Magill, B., Thompson, R. E., Remsberg, E., Wrotny, J., and Russell III, J.: Improved mesospheric temperature, water vapor and polar mesospheric cloud extinctions from HALOE, Geophys. Res. Lett., 30(8), 1440, doi:10.1029/2002GL016859, 2003. Sander, S. P., Finlayson-Pitts, B. J., Friedl, R. R., Golden, D. M., Huie, R. E., Keller-Rudek, H., Kolb, C. E., Kurylo, M. J., Molina, M. J., Moortgat, G. K., Orkin, V. L., Ravishankara, A. R., and Wine, P. W.: Chemical Kinetics and Photochemical Data for Use in Atmospheric Studies, Evaluation Number 15, JPL Publication 06-2, Jet Propulsion Laboratory, Pasadena, p 523, 2006. Sandor, B. J. and Clancy, R. T.: Mesospheric HO_x chemistry from diurnal microwave observations of HO₂, O₃, and H₂O, J. Geophys. Res., 103, 13337–13351, 1998. Seele, C. and Hartogh, P.: Water vapor of the polar middle atmosphere: Annual variation and summer mesosphere conditions as observed by ground-based microwave spectroscopy, Geophys. Res. Lett., 26, 1517–1520, 1999. Singer, W., Bremer, J., Hocking, W. K., Weiss, J., Latteck, R., and Zecha, M.: Temperature and wind tides around the summer mesopause at middle and Arctic latitudes, Adv. Space Res., 31(9), 2055–2060, 2003. % Sonnemann, G. and Fichtelmann, B.: Subharmonics, cascades of period of %doubling and chaotic behavior of photochemistry of the mesopause region, J. %Geophys. Res., 101, 1193–1203, 1997. Sonnemann, G., Kremp, C., Ebel, A., and Berger, U.: A three-dimensional dynamic model of the minor constituents of the mesosphere, Atmos. Environ., 32, 3157–3172, 1998. Sonnemann, G. R., Grygalashvyly, M., and Berger, U.: Autocatalytic water vapor production as a source of large mixing ratios within the middle to upper mesosphere, J. Geophys. Res., 110, D15303, doi:10.1029/2004JD005593, 2005. % Summers, M. E., Conway, R. R., Siskind, D. E., Stevens, M. H., Offermann, %D., Riese, M., Preusse, P., Strobel, D. F., and Russell, J. M.: Implications %of satellite OH observations for middle atmospheric H₂O and ozone, %Science, 277, 1967–1970, 1997. Summers, M. E. and Siskind, D. E.: Surface recombination of O and H₂ on meteoric dust as a source of mesospheric water vapor, Geophys. Res. Lett., 26, 1837–1840, 1999. Summers, M. E., Conway, R. R., Englert, C. R., Siskind, D. E., Stevens, M. H., Russell, J. M., Gordley, L. L., and McHugh, M. J.: Discovery of a water vapor layer in the Arctic summer mesosphere: Implications for polar mesospheric clouds, Geophys. Res. Lett., 28, 3601–3604, 2001. Takahashi, H., Melo, S. M. L., Clemesha, B. R., Simonich, D. M., Stegman, J., and Witt, G.: Atomic hydrogen and ozone concentrations derived from simultaneous lidar and rocket airglow measurements in the equatorial region, J. Geophys. Res., 101, 4033–4040, 1996. von Zahn, U. and Berger, U.: Persistent ice cloud in the midsummer upper mesosphere at high latitudes: Three-dimensional modeling and cloud interactions with ambient water vapor, J. Geophys. Res., 108(D8), 8451, doi:10.1029/2002JD002409, 2003.