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<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-9-7397-2009</article-id>
<title-group>
<article-title>Performance of the line-by-line radiative transfer model (LBLRTM) for temperature and species retrievals: IASI case studies from JAIVEx</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Shephard</surname>
<given-names>M. W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Clough</surname>
<given-names>S. A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Payne</surname>
<given-names>V. H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Smith</surname>
<given-names>W. L.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kireev</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Cady-Pereira</surname>
<given-names>K. E.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Atmospheric and Environmental Research, Inc., Lexington, Massachusetts, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Clough Radiation Associates, LLC., Lexington, Massachusetts, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>University of Wisconsin, Madison, Wisconsin, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Hampton University, Hampton, Virginia, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>05</day>
<month>10</month>
<year>2009</year>
</pub-date>
<volume>9</volume>
<issue>19</issue>
<fpage>7397</fpage>
<lpage>7417</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/9/7397/2009/acp-9-7397-2009.html">This article is available from http://www.atmos-chem-phys.net/9/7397/2009/acp-9-7397-2009.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/9/7397/2009/acp-9-7397-2009.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/9/7397/2009/acp-9-7397-2009.pdf</self-uri>
<abstract>
<p>Presented here are comparisons between the Infrared Atmospheric Sounding
instrument (IASI) and the &quot;Line-By-Line Radiative Transfer Model&quot;
(LBLRTM). Spectral residuals from radiance closure studies during the IASI
JAIVEx validation campaign provide insight into a number of spectroscopy
issues relevant to remote sounding of temperature, water vapor and trace
gases from IASI. In order to perform quality IASI trace gas retrievals, the
temperature and water vapor fields must be retrieved as accurately as
possible. In general, the residuals in the CO&lt;sub&gt;2&lt;/sub&gt;  &amp;nu;&lt;sub&gt;2&lt;/sub&gt; region are of
the order of the IASI instrument noise. However, outstanding issues with the
CO&lt;sub&gt;2&lt;/sub&gt; spectral regions remain. There is a large residual ~&amp;minus;1.7 K in
the 667 cm&lt;sup&gt;&amp;minus;1&lt;/sup&gt; Q-branch, and residuals in the CO&lt;sub&gt;2&lt;/sub&gt;  &amp;nu;&lt;sub&gt;2&lt;/sub&gt; and
N&lt;sub&gt;2&lt;/sub&gt;O/CO&lt;sub&gt;2&lt;/sub&gt;  &amp;nu;&lt;sub&gt;3&lt;/sub&gt; spectral regions that sample the troposphere
are inconsistent, with the N&lt;sub&gt;2&lt;/sub&gt;O/CO&lt;sub&gt;2&lt;/sub&gt;  &amp;nu;&lt;sub&gt;3&lt;/sub&gt; region being too
negative (warmer) by ~0.7 K. Residuals on this lower wavenumber side
of the CO&lt;sub&gt;2&lt;/sub&gt;  &amp;nu;&lt;sub&gt;3&lt;/sub&gt; band will be improved by line parameter
updates, while future efforts to reduce the residuals reaching ~&amp;minus;0.5 K
on the higher wavenumber side of the CO&lt;sub&gt;2&lt;/sub&gt;  &amp;nu;&lt;sub&gt;3&lt;/sub&gt; band will focus
on addressing limitations in the modeling of the CO&lt;sub&gt;2&lt;/sub&gt; line shape (line
coupling and duration of collision) effects. Brightness temperature
residuals from the radiance closure studies in the &amp;nu;&lt;sub&gt;2&lt;/sub&gt; water vapor
band have standard deviations of ~0.2–0.3 K with some large peak
residuals reaching &amp;plusmn;0.5–1.0 K. These are larger than the instrument
noise indicating that systematic errors still remain. New H&lt;sub&gt;2&lt;/sub&gt;O line
intensities and positions have a significant \mbox{impact} on the
retrieved water vapor, particularly in the upper troposphere where the water
vapor retrievals are 10% drier when using line intensities
compared with HITRAN 2004. In addition to O&lt;sub&gt;3&lt;/sub&gt;, CH&lt;sub&gt;4&lt;/sub&gt;, and CO,
of the IASI instrument combined with an accurate
forward model allows for the detection of minor species with weak
atmospheric signatures in the nadir radiances, such as HNO&lt;sub&gt;3&lt;/sub&gt; and OCS.</p>
</abstract>
<counts><page-count count="21"/></counts>
</article-meta>
</front>
<body/>
<back>
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