1Environmental Chemical Processes Laboratory, Department of Chemistry, University of Crete, Voutes, 71003, Heraklion, Greece
2Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
3Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA
4Institute of Chemical Engineering and High Temperature Chemical Processes (ICE-HT), Foundation for Research and Technology Hellas (FORTH), Patras, 26504, Greece
5Department of Chemical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213, USA
Received: 10 Mar 2009 – Published in Atmos. Chem. Phys. Discuss.: 27 Apr 2009
Abstract. Measurements of cloud condensation nuclei (CCN) concentrations (cm−3) between 0.2 and 1.0% supersaturation, aerosol size distribution and chemical composition were performed at a remote marine site in the eastern Mediterranean, from September to October 2007 during the FAME07 campaign. Most of the particles activate at ~0.6% supersaturation, characteristic of the aged nature of the aerosol sampled. Application of Köhler theory, using measurements of bulk composition, size distribution, and assuming that organics are insoluble resulted in agreement between predicted and measured CCN concentrations within 7±11% for all supersaturations, with a tendency for CCN underprediction (16±6%; r2=0.88) at the lowest supersaturations (0.21%). Including the effects of the water-soluble organic fraction (which represent around 70% of the total organic content) reduces the average underprediction bias at the low supersaturations, resulting in a total closure error of 0.6±6%. Using threshold droplet growth analysis, the growth kinetics of ambient CCN is consistent with NaCl calibration experiments; hence the presence of aged organics does not suppress the rate of water uptake in this environment. The knowledge of the soluble salt fraction is sufficient for the description of the CCN activity in this area.
Revised: 21 Aug 2009 – Accepted: 31 Aug 2009 – Published: 24 Sep 2009
Citation: Bougiatioti, A., Fountoukis, C., Kalivitis, N., Pandis, S. N., Nenes, A., and Mihalopoulos, N.: Cloud condensation nuclei measurements in the marine boundary layer of the Eastern Mediterranean: CCN closure and droplet growth kinetics, Atmos. Chem. Phys., 9, 7053-7066, doi:10.5194/acp-9-7053-2009, 2009.