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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-9-667-2009</article-id>
<title-group>
<article-title>Classifying previously undefined days from eleven years of aerosol-particle-size distribution data from the SMEAR II station, Hyytiälä, Finland</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Buenrostro Mazon</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Riipinen</surname>
<given-names>I.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schultz</surname>
<given-names>D. M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Valtanen</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dal Maso</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sogacheva</surname>
<given-names>L.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Junninen</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Nieminen</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kerminen</surname>
<given-names>V.-M.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kulmala</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Physics, University of Helsinki, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Finnish Meteorological Institute, Helsinki, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Environmental Science, University of Kuopio, Finland</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Institut für Chemie und Dynamik der Geosphäre, Forschungszentrum Jülich, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>28</day>
<month>01</month>
<year>2009</year>
</pub-date>
<volume>9</volume>
<issue>2</issue>
<fpage>667</fpage>
<lpage>676</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/9/667/2009/acp-9-667-2009.html">This article is available from http://www.atmos-chem-phys.net/9/667/2009/acp-9-667-2009.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/9/667/2009/acp-9-667-2009.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/9/667/2009/acp-9-667-2009.pdf</self-uri>
<abstract>
<p>Studies of secondary aerosol-particle formation depend on identifying days
in which new particle formation occurs and, by comparing them to days with
no signs of particle formation, identifying the conditions favourable for
formation. Continuous aerosol size distribution data has been collected at
the SMEAR II station in a boreal forest in Hyytiälä, Finland, since
1996, making it the longest time series of aerosol size distributions
available worldwide. In previous studies, the data have been classified as
particle-formation event, nonevent, and undefined days, with almost 40%
of the dataset classified as undefined. In the present study, eleven years
(1996–2006) of undefined days (1630 days) were reanalyzed and subdivided
into three new classes: failed events (37% of all previously undefined
days), ultrafine-mode concentration peaks (34%), and pollution-related
concentration peaks (19%). Unclassified days (10%) comprised the rest
of the previously undefined days. The failed events were further subdivided
into tail events (21%), where a tail of a formation event presumed to be
advected to Hyytiälä from elsewhere, and quasi events (16%) where
new particles appeared at sizes 3–10 nm, but showed unclear growth, the
mode persisted for less than an hour, or both. The ultrafine concentration
peaks days were further subdivided into nucleation-mode peaks (24%) and
Aitken-mode peaks (10%), depending on the size range where the particles
occurred. The mean annual distribution of the failed events has a maximum
during summer, whereas the two peak classes have maxima during winter. The
summer minimum previously found in the seasonal distribution of event days
partially offsets a summer maximum in failed-event days. Daily-mean relative
humidity and condensation sink values are useful in discriminating the new
classes from each other. Specifically, event days had low values of relative
humidity and condensation sink relative to nonevent days. Failed-event days
possessed intermediate condensation sink and relative humidity values,
whereas both ultrafine-mode peaks and, to a greater extent,
pollution-related peaks had high values of both, similar to nonevent days.
Using 96-h back trajectories, particle-size concentrations were plotted as a
function of time the trajectory spent over land. Increases in particle size
and number concentration during failed-event days were similar to that
during the later stages of event days, whereas the particle size and number
concentration for both nonevent and peaks classes did not increase as fast
as for event and failed events days.</p>
</abstract>
<counts><page-count count="10"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Aalto, P., Hämeri, K., Becker, E., Weber. R., Salm, J., Mäkelä, J., Hoel, C., O&apos;Down, C., Karlsson, H., Hansson, H.-C., Väkevä, M., Koponen, I., Buzorius, G., and Kulmala, M.: Physical characterization of aerosol particles during nucleation events, Tellus, 53B, 344–358, 2001. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Allen, G., Remedios, J. J., and Smith, K. M.: Low temperature mid-infrared cross-sections for peroxyacetyl nitrate (PAN) vapour, Atmos. Chem. Phys., 5, 3153–3158, 2005. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Birmili, W., Berresheim, H., Plass-Dülmer, C., Elste, T., Gilge, S., Wiedensohler, A., and Uhrner, U.: The Hohenpeissenberg aerosol formation experiment (HAFEX): a long-term study including sizeresolved aerosol, H2SO4, OH, and monoterpenes measurements, Atmos. Chem. Phys., 3, 361–376, 2003. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Dal Maso, M., Kulmala, M., Riipinen, I., Wagner, R., Hussein, T., Aalto, P. P., and Lehtinen, E. J.: Formation and growth of fresh atmospheric aerosol: eight years of aerosol size distribution data from SMEAR II, Hyytiälä, Finland, Boreal Env. Res., 10, 323–336, 2005. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Dal Maso, M., Sogacheva, L., Aalto, P., Riipinen, I., Komppula, M., Tunved, P., Korhonen, L., Suur-uski, V., Hirsikko, A., Kurten. T., Kerminen, V., Lihavainen, H., Viisanen, Y., Hansson, H., and Kulmala, M.: Aerosol size distribution measurements at four Nordic field stations: identification, analysis and trajectories analysis of new particle formation bursts, Tellus ,59B, 350–361, 2007. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Draxler R. R and Hess G. D.: An Overview of the HYSPLIT_4 Modeling System for Trajectories, Dispersion and Deposition. Australian Meteorological Magazine 47, 295–308, 1998. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Doswell III., C. A.: Comments on &quot;Mesoscale convective patterns of the southern high plains.&quot;, B. Am. Meteor. Soc., 72, 389–390, 1991. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Hari, P. and Kulmala, M.: Station for Measuring Ecosystems – Atmosphere Relations (SMEAR II), Boreal Env. Res., 10, 315–322, 2005. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Heintzenberg, J., Wehner, B., and Birmili W.: How to find bananas in the atmospheric aerosol: New approach for analyzing atmospheric nucleation and growth events, Tellus, 59B, 273–282, 2007. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Hirsikko, A., Laakso, L., Horrak, U., Aalto, P., Kerminen, V., and Kulmala, M.: Annual and size dependent variations of growth rates and ion concentrations in boreal forest, Boreal Env. Res., 10, 357–369, 2005. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Hyvönen, S., Junninen, H., Laakso, L., Dal Maso, M., Grönholm, T., Bonn, B., Kernonen, P., Aalto, P., Hiltunen, V., Pohja, T., Launiainen, S., Hari, P., Mannila, H., and Kulmala, M.: A look at aerosol formation using data mining techniques, Atmos. Chem. Phys., 5, 3345–3356, 2005. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Intergovernmental Panel on Climate Change (IPCC), Summary for Policymakers, in: Climate Change 2007: The Physical Science Basis, Cambridge University Press, Cambridge, 2007. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Kulmala, M., Toivonen, A., Mäkelä, J. M., and Laaksonen, A.: Analysis of the growth of nucleation mode particles observed in Boreal forest, Tellus, 50B, 449–462, 1998. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Kulmala, M., Hämeri, K., Aalto, P. P., Mäkelä, J. M., Pirjola, L., Nilsson, E. D., Buzorius, G., Rannik, Ü., Dal Maso, M., Seidl, W., Hoffman, T., Janson, R., Hansson, H.-C., Viisanen, Y., Laaksonen, A., and O&apos;Dowd, C. D.: Overview of the international project on biogenic aerosol formation in the boreal forest (BIOFOR), Tellus, 53B, 324–343, 2001. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Kulmala, M., Vehkamäki, H., Petäjä, T., Dal Maso, M., Lauri, A., Kerminen, V.-M., Birmili, W., and McMurry, P. H.: Formation and growth rates of ultrafine atmospheric particles: A review of observations, J. Aerosol Sci., 35, 143–176, 2004a. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Kulmala, M., Suni, T., Lehtinen, K. E. J., Dal Maso, M., Boy, M., Reissell, A., Rannik, Ü., Aalto, P. P., Keronen, P., Hakola, H., Bäck, J., Hoffmann, T., Vesala, T., and Hari, P.: A new feedback mechanism linking forests, aerosols, and climate, Atmos. Chem. Phys., 4, 557–562, 2004b. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Kulmala, M., Riipinen, I., Sipilä, M., Manninen, H. E., Petäjä, T., Junninen,H., Dal Maso, M., Mordas, G., Mirme, A., Vana, M., Hirsikko, A., Laakso, L., Harrison, R. M., Hanson, I., Leung, C., Lehtinen, K. E. J., and Kerminen, V.-M.: Toward direct measurement of atmospheric nucleation, Science, 318, 89–92, 2007. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Lyubovtseva, Y. S., Sogacheva, L., Dal Maso, M., Bonn, B., Keronen. P., and Kulmala, M.: Seasonal variations of trace gases, meteorological parameters, and formation of aerosols in boreal forests, Boreal Env. Res., 10, 493–510, 2005. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> McMurry, P. H., Fink, M., Sakurai, H., Stolzenburg, M. R., Mauldin, R. L., Smith III., J., Eisele, F., Moore, K., Sjostedt, S., Tanner, D., Huey, L. G., Novak., J. B., Edgerton, E., and Voisin, D.: A criterion for new particle formation in the sulfur-rich Atlanta atmosphere, J. Geophys. Res., 110, D22S02, doi:10.1029/2005JD005901, 2005. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Mäkelä, J. M., Koponen, K. I., Aalto, P., and Kulmala, M.: One-year data of submicron size modes of tropospheric background aerosol in southern Finland, J. Aerosol Sci., 31(5), 595–611, 2000a. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Mäkelä, J. M., Dal Maso, M., Laaksonen, A., Pirjola, L., Keronon, P., amd Kulmala, M.: Characteristics of three years continuous data on new particle formation events observed at a boreal forest site, Nucleation and Atmopsheric Aerosols 2000: 15th Intl. Conf., Missouri, USA, 6–11 August 2000b. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Mäkelä, J. M., Dal Maso, M., Laaksonen, A., Pirjola, L., Keronon, P., and Kulmala, M.: Characteristics of the atmospheric particle formation events observed at a boreal forest site in southern Finland, Boreal Env. Res., 5, 299–313, 2000c. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Sogacheva, L., Dal Maso, M., Kerminen, V.-M., and Kulmala, M.: Probability of nucleation events and aerosol particle concentration in different air mass types arriving at Hyytiälä, southern Finland, based on back trajectories analysis, Boreal Env. Res., 10, 479–491, 2005. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Sogacheva, L., Saukkonen, L., Nilsson, E. D., Dal Maso, M., Schultz, D. M., de Leeuw, G., and Kulmala, M.: New aerosol particle formation in different synoptic situations at Hyytiälä, southern Finland, Tellus, 60B, 485–494, 2008. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Smart – SMEAR tool: http://www.atm.helsinki.fi/~junninen/, last access: 2007. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Tunved, P., Hansson, H.-C., Kerminen, V.-M., Ström, J., Dal Maso, M., Lihavainen, H., Viisanen, Y., Aalto, P. P., Komppula, M., AND Kulmala, M.: High natural aerosol loading over boreal forests, Science, 312, 261–263, 2006. </mixed-citation>
</ref>
</ref-list>
</back>
</article>