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<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics</journal_title>
		<journal_url>www.atmos-chem-phys.net</journal_url>
		<issn>1680-7316</issn>
		<eissn>1680-7324</eissn>
		<volume_number>9</volume_number>
		<issue_number>14</issue_number>
		<publication_year>2009</publication_year>
	</journal>
	<doi>10.5194/acp-9-4559-2009</doi>
	<article_url>http://www.atmos-chem-phys.net/9/4559/2009/</article_url>
	<abstract_html>http://www.atmos-chem-phys.net/9/4559/2009/acp-9-4559-2009.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys.net/9/4559/2009/acp-9-4559-2009.pdf</fulltext_pdf>
	<start_page>4559</start_page>
	<end_page>4573</end_page>
	<publication_date>2009-07-15</publication_date>
	<article_title content_type="html">Modelling multi-phase halogen chemistry in the remote marine boundary  layer: investigation of the influence of aerosol size resolution on predicted  gas- and condensed-phase chemistry</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>D. Lowe</name>
			<email>douglas.lowe@manchester.ac.uk</email>
		</author>
		<author numeration="2" affiliations="1">
			<name>D. Topping</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>G. McFiggans</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">School of Earth, Atmospheric and Environmental Science, University of Manchester, Manchester, UK</affiliation>
	</affiliations>
	<abstract content_type="html">A coupled box model of photochemistry and aerosol microphysics which explicitly
accounts for size-dependent chemical properties of the condensed-phase has been
developed to simulate the multi-phase chemistry of chlorine, bromine and iodine in
the marine boundary layer (MBL). The model contains separate seasalt and
non-seasalt modes, each of which may be composed of 1â€“16 size-bins. By
comparison of gaseous and aerosol compositions predicted using different
size-resolutions with both fixed and size-dependent aerosol turnover rates, it
was found that, for halogen-activation processes, the physical property
initialisation of the aerosol-mode has a significant influence on gas-phase
chemistry. Failure to adequately represent the appropriate physical properties
can lead to substantial errors in gas-phase chemistry. The size-resolution of
condensed-phase composition has a less significant influence on gas-phase chemistry.</abstract>
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</article>

