Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 9 13 2009 10.5194/acp-9-4387-2009 http://www.atmos-chem-phys.net/9/4387/2009/ http://www.atmos-chem-phys.net/9/4387/2009/acp-9-4387-2009.html http://www.atmos-chem-phys.net/9/4387/2009/acp-9-4387-2009.pdf 4387 4406 2009-07-07 Photochemical production of aerosols from real plant emissions Th. F. Mentel t.mentel@fz-juelich.de J. Wildt A. Kiendler-Scharr E. Kleist R. Tillmann M. Dal Maso R. Fisseha Th. Hohaus H. Spahn R. Uerlings R. Wegener P. T. Griffiths E. Dinar Y. Rudich A. Wahner Inst. for Chemistry and Dynamics of the Geosphere, Inst. 2: Troposphere, Research Centre Jülich, 52425 Jülich, Germany Inst. for Chemistry and Dynamics of the Geosphere, Inst. 3: Phytosphere, Research Centre Jülich, 52425 Jülich, Germany Centre for Atmospheric Science, Dept. of Chemistry, Lensfield Road, Univ. of Cambridge, Cambridge, CB2 1EW, UK Dept. of Environmental Sciences, Weizmann Institute, Rehovot 76100, Israel Emission of biogenic volatile organic compounds (VOC) which on oxidation form secondary organic aerosols (SOA) can couple the vegetation with the atmosphere and climate. Particle formation from tree emissions was investigated in a new setup: a plant chamber coupled to a reaction chamber for oxidizing the plant emissions and for forming SOA. Emissions from the boreal tree species birch, pine, and spruce were studied. In addition, <i>α</i>-pinene was used as reference compound. Under the employed experimental conditions, OH radicals were essential for inducing new particle formation, although O₃ (&le;80 ppb) was always present and a fraction of the monoterpenes and the sesquiterpenes reacted with ozone before OH was generated. Formation rates of 3 nm particles were linearly related to the VOC <i>carbon</i> mixing ratios, as were the maximum observed volume and the condensational growth rates. For all trees, the threshold of new particle formation was lower than for <i>α</i>-pinene. It was lowest for birch which emitted the largest fraction of oxygenated VOC (OVOC), suggesting that OVOC may play a role in the nucleation process. Incremental mass yields were &asymp;5% for pine, spruce and <i>α</i>-pinene, and &asymp;10% for birch. <i>α</i>-Pinene was a good model compound to describe the yield and the growth of SOA particles from coniferous emissions. The mass fractional yields agreed well with observations for boreal forests. 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