Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 8 19 2008 10.5194/acp-8-5919-2008 http://www.atmos-chem-phys.net/8/5919/2008/ http://www.atmos-chem-phys.net/8/5919/2008/acp-8-5919-2008.html http://www.atmos-chem-phys.net/8/5919/2008/acp-8-5919-2008.pdf 5919 5939 2008-10-15 Consistent simulation of bromine chemistry from the marine boundary layer to the stratosphere – Part 2: Bromocarbons A. Kerkweg akerkweg@mpch-mainz.mpg.de P. Jöckel N. Warwick S. Gebhardt C. A. M. Brenninkmeijer J. Lelieveld MPI for Chemistry (Otto Hahn Institute), Atmospheric Chemistry Department, P.O. Box 3060, 55020 Mainz, Germany Institute for Atmospheric Physics, University of Mainz, Mainz, Germany University of Cambridge, Chemistry Department, Lensfield Road, Cambridge, CB2 1EW, UK In this second part of a series of articles dedicated to a detailed analysis of bromine chemistry in the atmosphere we address one (out of two) dominant natural sources of reactive bromine. The two main source categories are the release of bromine from sea salt and the decomposition of bromocarbons by photolysis and reaction with OH. Here, we focus on C₁-bromocarbons. We show that the atmospheric chemistry general circulation model ECHAM5/MESSy realistically simulates their emission, transport and decomposition from the boundary layer up to the mesosphere. We included oceanic emission fluxes of the short-lived bromocarbons CH₂Br₂, CH₂ClBr, CHClBr₂, CHCl₂Br, CHBr₃ and of CH₃Br. The vertical profiles and the surface mixing ratios of the bromocarbons are in general agreement with the (few available) observations, especially in view of the limited information available and the consequent coarseness of the emission fields. For CHBr₃, CHCl₂Br and CHClBr₂ photolysis is the most important degradation process in the troposphere. In contrast to this, tropospheric CH₂Br₂, CH₃Br and CH₂ClBr are more efficiently decomposed by reaction with OH. 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