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<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics</journal_title>
		<journal_url>www.atmos-chem-phys.net</journal_url>
		<issn>1680-7316</issn>
		<eissn>1680-7324</eissn>
		<volume_number>8</volume_number>
		<issue_number>14</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/acp-8-3805-2008</doi>
	<article_url>http://www.atmos-chem-phys.net/8/3805/2008/</article_url>
	<abstract_html>http://www.atmos-chem-phys.net/8/3805/2008/acp-8-3805-2008.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys.net/8/3805/2008/acp-8-3805-2008.pdf</fulltext_pdf>
	<start_page>3805</start_page>
	<end_page>3815</end_page>
	<publication_date>2008-07-17</publication_date>
	<article_title content_type="html">Enhancement of N&lt;sub&gt;2&lt;/sub&gt;O during the October–November 2003 solar proton events</article_title>
	<authors>
		<author numeration="1" affiliations="1">
			<name>B. Funke</name>
		</author>
		<author numeration="2" affiliations="1">
			<name>M. García-Comas</name>
		</author>
		<author numeration="3" affiliations="1">
			<name>M. López-Puertas</name>
			<email>puertas@iaa.es</email>
		</author>
		<author numeration="4" affiliations="2">
			<name>N. Glatthor</name>
		</author>
		<author numeration="5" affiliations="2">
			<name>G. P. Stiller</name>
		</author>
		<author numeration="6" affiliations="2">
			<name>T. von Clarmann</name>
		</author>
		<author numeration="7" affiliations="3">
			<name>K. Semeniuk</name>
		</author>
		<author numeration="8" affiliations="3">
			<name>J. C. McConnell</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Instituto de Astrofísica de Andalucía, CSIC, Granada, Spain</affiliation>
		<affiliation numeration="2" content_type="html">Forschungszentrum Karlsruhe und Universität Karlsruhe, Institut für Meteorologie und Klimaforschung, Karlsruhe, Germany</affiliation>
		<affiliation numeration="3" content_type="html">Department of Earth and Space Science and Engineering, York University, Toronto, Ontario, Canada</affiliation>
	</affiliations>
	<abstract content_type="html">In this paper we present evidence of enhanced N&lt;sub&gt;2&lt;/sub&gt;O concentrations in the
upper stratosphere/lower mesosphere polar regions after the solar
proton events that occurred during October–November 2003. The
observations were performed by the MIPAS instrument on the Envisat
satellite. Simulations performed using the Canadian Middle Atmospheric
Model (CMAM) show that such enhancements are most likely produced by the
reaction of N(&lt;sup&gt;4&lt;/sup&gt;S) with NO&lt;sub&gt;2&lt;/sub&gt;, both of which species are largely
enhanced just after the solar proton events in the winter polar night.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Brasseur, G. and Solomon, S.: Aeronomy of the middle Atmosphere, 3rd revised and enlarged ed., Springer, Dordrecht, 644, 327–358, 2005. </reference>
		<reference numeration="2" content_type="text"> de Grandpr\accent 19 e, J., Beagley, S. R., Fomichev, V. I., Griffioen, E., McConnell, J. C., Medvedev, A. S., and T. G. Shepherd: Ozone climatology using interactive chemistry: Results from the Canadian Middle Atmosphere Model, J. Geophys. Res., 105, 26 475–26 491, 2000. </reference>
		<reference numeration="3" content_type="text"> European Space Agency, Envisat, MIPAS An instrument for atmospheric chemistry and climate research, ESA Publications Division, ESTEC, The Netherlands, SP-1229, 1–123, 2000. </reference>
		<reference numeration="4" content_type="text"> Fischer, H. and Oelhaf, H.: Remote sensing of vertical profiles of atmospheric trace constituents with MIPAS limb-emission spectrometers, Appl. Optics, 35, 16, 2787–2796, 1996. </reference>
		<reference numeration="5" content_type="text"> Fischer, H., Birk, M., Blom, C., Carli, B., Carlotti, M., von Clarmann, T., Delbouille, L., Dudhia, A., Ehhalt, D., Endemann, M., Flaud, J. M., Gessner, R., Kleinert, A., Koopmann, R., Langen, J., López-Puertas, M., Mosner, P., Nett, H., Oelhaf, H., Perron, G., Remedios, J., Ridolfi, M., Stiller, G., and Zander, R.: MIPAS: An Instrument for Atmospheric and Climate Research, Atmos. Chem. Phys., 8, 2151–2188, 2008. </reference>
		<reference numeration="6" content_type="text"> Funke, B., López-Puertas, M., Gil-López, S., Clarmann, T., Stiller, G., Kellmann, S., and Fischer, H.: Downward transport of upper atmospheric \nox into the polar stratosphere and lower mesosphere during the Antarctic 2003 and Arctic 2002/2003 winters, J. Geophys. Res., 110, D24308, doi:10.1029/2005JD006463, 2005. </reference>
		<reference numeration="7" content_type="text">Funke, B., López-Puertas, M., Garc\&quot;ia-Comas, M., Stiller, G. P., von Clarmann, T., and Glatthor, N.: Mesospheric N&lt;sub&gt;2&lt;/sub&gt;O enhancements as observed by MIPAS on Envisat during the polar winters in 2002-2004, Atmos. Chem. Phys. Discuss., 8, 10 561–10 596, 2008. </reference>
		<reference numeration="8" content_type="text"> Glatthor, N., von Clarmann, T., Fischer, H., Funke, B., Grabowski, U., Höpfner, M., Kellmann, S., Kiefer, M., Linden, A., Milz, M., Steck, T., Stiller, G. P., Mengistu Tsidu, G., and Wang, D.-Y.: Mixing processes during the Antarctic vortex split in September–October 2002 as inferred from source gas and ozone distributions from ENVISAT-MIPAS, J. Atmos. Sci., 62, 787–800, 2005. </reference>
		<reference numeration="9" content_type="text"> Jackman, C. H. and McPeters, R. D.: The effects of solar proton events on ozone and other constituents, Solar variability and its Effects on climate, Geophys. Mon., 141, 305–319, 2004. </reference>
		<reference numeration="10" content_type="text"> Jackman, C. H., DeLand, M. T., Labow, G. J., Fleming, E. L., Weisenstein, D. K., Ko, M., Sinnhuber, M. K. W., and Russell, J. M.: Neutral atmospheric influences of the solar proton events in October–November 2003, J. Geophys. Res., 110, A09S27, doi:10.1029/2004JA010888, 2005a. </reference>
		<reference numeration="11" content_type="text"> Jackman, C. H., DeLand, M. T., Labow, G. J., Fleming, E. L., Weisenstein, D. K., Ko, M., Sinnhuber, M. K. W., Anderson, J., and Russell, J. M.: The influence of the several very large solar proton events in Years 2000–2003 on the neutral middle atmosphere, Adv. Space Res., 35, 445–450, 2005b. </reference>
		<reference numeration="12" content_type="text"> Jackman, C. H., Marsh, D. R., Vitt, F. M., Garcia, R., Fleming, E. L., Labow, G. J., Randall, C., López-Puertas, M., and Funke, B.: Short- and medium-term atmospheric effects of very large solar proton events, Atmos. Chem. Phys., 8, 765–785, 2008. </reference>
		<reference numeration="13" content_type="text"> Jackman, C. H.: Ionization rates for 1963–2007 from Solar Proton events, www.geo.fu-berlin.de/en/met/ag/strat/research/SOLARIS/Input_data/SOLARIS_Jackman_SPEs.pdf, 2007. </reference>
		<reference numeration="14" content_type="text"> López-Puertas, M., Funke, B., Gil-López, S., von Clarmann, T., Stiller, G. P., Höpfner, M., Kellmann, S., Fischer, H., and Jackman, C. H.: Observation of \nox enhancement and ozone depletion in the Northern and Southern Hemispheres after the October–November 2003 solar proton events, J. Geophys. Res., 110, A09S43, doi:10.1029/2005JA011050, 2005a. </reference>
		<reference numeration="15" content_type="text"> López-Puertas, M., Funke, B., Gil-López, S., Mengistu Tsidu, G., Fischer, H., and Jackman, C. H.: \hno3, \ndo5, and \clono2 enhancements after the October–November 2003 solar proton events, J. Geophys. Res., 110, A09S44, doi:10.1029/2005JA011051, 2005b. </reference>
		<reference numeration="16" content_type="text"> López-Puertas, M., Funke, B., Clarmann, T., Fischer, H., and Stiller, G.: The Variability of Stratospheric and Mesospheric NO&lt;sub&gt;y&lt;/sub&gt; in the Arctic and Antarctic 2002–2004 Polar Winters, Space Sci. Rev., 125, 403–416, doi:10.1007/s11214-006-9073-2, 2006. </reference>
		<reference numeration="17" content_type="text"> Nett, H., Carli, B., Carlotti, M., et al.: MIPAS ground processor and data products, Proc. IEEE 1999 Inter. Geosci. and Remote Sensing Symp., Hamburg, Germany, 1692–1696, 1999. </reference>
		<reference numeration="18" content_type="text"> Nett, H., Perron, G., Sanchez, M., Burgess, A., and Mosner, P.: MIPAS in-flight calibration and processor verification, in: ENVISAT Calibration Review–Proc. of the European Workshop, 9–13 September 2002, ESTEC, Noordwijk, The Netherlands, CD-ROM, SP–520, edited by: H Sawaya-Lacoste, ESA Publications Division, ESTEC, Postbus 299, 2200 AG Noordwijk, The Netherlands, 1–10, 2002. </reference>
		<reference numeration="19" content_type="text"> Orsolini, Y. J., Manney, G. L., Santee, M. L., and Randall, C. E.: An upper stratospheric layer of enhanced \hno3 following exceptional solar storms, Geophys. Res. Lett., 32, L12S01, doi:10.1029/2004GL021588, 2005. </reference>
		<reference numeration="20" content_type="text"> Randall, C. E., Harvey, V. L., Manney, G. L., et al.: Stratospheric effects of energetic particle precipitation in 2003–2004, Geophys. Res. Lett., 32, L05802, doi:10.1029/2004GL022003, 2005. </reference>
		<reference numeration="21" content_type="text"> Rohen, G., von Savigny, C., Sinnhuber, M., Llewellyn, E. J., Kaiser, J. W., Jackman, C. H., Kallenrode, M.-B., Schroter, J., Eichmann, K.-U., Bovensmann, H., and Burrows, J. P.: Ozone depletion during the solar proton events of Oct./Nov. 2003 as seen by SCIAMACHY, J. Geophys. Res., 110, A09S39, doi:10.1029/2004JA010984, 2005. </reference>
		<reference numeration="22" content_type="text"> Rusch, D. W., Gerard, J.-C., Solomon, S., Crutzen, P. J., and Reid, G. C.: The effect of particle precipitation events on the neutral and ion chemistry of the middle atmosphere, 1, Odd nitrogen, Planet. Space Sci., 29, 767–774, 1981. </reference>
		<reference numeration="23" content_type="text"> Semeniuk, K., McConnell, J. C., Jin, J. J., Jarosz, J. R., Boone, C. D., and Bernath, P. F.: N&lt;sub&gt;2&lt;/sub&gt;O production by high energy auroral electron precipitation, J. Geophys. Res., doi:10.10.29/2008JD010634, in press, 2008. </reference>
		<reference numeration="24" content_type="text"> Semeniuk, K., McConnell, J. C., and Jackman, C. H.: Simulation of the October–November 2003 solar proton events in the CMAM GCM: Comparison with observations, Geophys. Res. Lett., 32, L15S02, doi:10.1029/2004GL022392, 2005. </reference>
		<reference numeration="25" content_type="text"> Seppälä, A., Verronen, P. T., Kyrölä, E., Hassinen, S., Backman, L., Hauchecorne, A., Bertaux, J. L., and Fussen, D.: Solar proton events of October–November 2003: Ozone depletion in the Northern Hemisphere polar winter as seen by GOMOS/Envisat, Geophys. Res. Lett., 31, L19107, doi:10.1029/2004GL021042, 2004. </reference>
		<reference numeration="26" content_type="text"> Stiller, G. P.: The Karlsruhe Optimized and Precise Radiative Transfer Algorithm (KOPRA), Wiss. Ber. FZKA 6487, Forschungszentrum, Karlsruhe, Germany, 521–540, 2000. </reference>
		<reference numeration="27" content_type="text"> Verronen, P. T., Seppälä, A., Kyrölä, E., Tamminen, J., Pickett, H. M., and Turunen, E.: Production of odd hydrogen in the mesosphere during the January 2005 solar proton event, Geophys. Res. Lett., 33, L24811, doi:10.1029/2006GL028115, 2006. </reference>
		<reference numeration="28" content_type="text"> von Clarmann, T. and Echle, G.: Selection of optimized microwindows for atmospheric spectroscopy, Appl. Optics, 37, 7661–7669, 1998. </reference>
		<reference numeration="29" content_type="text"> von Clarmann, T., Chidiezie Chineke, T., Fischer, H., et al.: Remote sensing of the middle atmosphere with MIPAS, in: Remote Sensing of Clouds and the Atmosphere VII, 4882, edited by: Schäfer, K., Lado-Bordowsky, O., Comerón, A., and Picard, R H., SPIE, Bellingham, WA, USA, 172–183, 2003a. </reference>
		<reference numeration="30" content_type="text"> von Clarmann, T., Glatthor, N., Grabowski, U., et al.: Retrieval of temperature and tangent altitude pointing from limb emission spectra recorded from space by the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), J. Geophys. Res., 108(D23), 4736, doi:10.1029/2003JD003602, 2003b. </reference>
		<reference numeration="31" content_type="text"> von Clarmann, T., Glatthor, N., Höpfner, M., et al.: Stratospheric HOCl measurements provide evidence of increased stratospheric odd hydrogen abundances due to solar proton events 2003, J. Geophys. Res., 110, A09S45, doi:10.1029/2005JA011053, 2005. </reference>
		<reference numeration="32" content_type="text"> Wennberg, P. O., Anderson, J. G., and Weisenstein, D. K.: Kinetics of reactions of ground state nitrogen atoms ($^4$S$_3/2$) with NO and NO&lt;sub&gt;2&lt;/sub&gt;, J. Geophys. Res., 99, 18 839–18 846, 1994. </reference>
	</references>
</article>

