<?xml version="1.0" encoding="utf-8" standalone="no"?>
<!DOCTYPE article SYSTEM "http://www.atmos-chem-phys.net/inc/acp/copernicus.dtd">
<article language="en">
	<journal>
		<journal_title>Atmospheric Chemistry and Physics</journal_title>
		<journal_url>www.atmos-chem-phys.net</journal_url>
		<issn>1680-7316</issn>
		<eissn>1680-7324</eissn>
		<volume_number>8</volume_number>
		<issue_number>13</issue_number>
		<publication_year>2008</publication_year>
	</journal>
	<doi>10.5194/acp-8-3427-2008</doi>
	<article_url>http://www.atmos-chem-phys.net/8/3427/2008/</article_url>
	<abstract_html>http://www.atmos-chem-phys.net/8/3427/2008/acp-8-3427-2008.html</abstract_html>
	<fulltext_pdf>http://www.atmos-chem-phys.net/8/3427/2008/acp-8-3427-2008.pdf</fulltext_pdf>
	<start_page>3427</start_page>
	<end_page>3439</end_page>
	<publication_date>2008-07-02</publication_date>
	<article_title content_type="html">Modelling the optical properties of fresh biomass burning  aerosol produced in a smoke chamber: results from the EFEU campaign</article_title>
	<authors>
		<author numeration="1" affiliations="1,9">
			<name>K. Hungershoefer</name>
			<email>hungershoefer@lisa.univ-paris12.fr</email>
		</author>
		<author numeration="2" affiliations="2,4">
			<name>K. Zeromskiene</name>
		</author>
		<author numeration="3" affiliations="2">
			<name>Y. Iinuma</name>
		</author>
		<author numeration="4" affiliations="3">
			<name>G. Helas</name>
		</author>
		<author numeration="5" affiliations="5">
			<name>J. Trentmann</name>
		</author>
		<author numeration="6" affiliations="1,6">
			<name>T. Trautmann</name>
		</author>
		<author numeration="7" affiliations="3,8">
			<name>R. S. Parmar</name>
		</author>
		<author numeration="8" affiliations="2">
			<name>A. Wiedensohler</name>
		</author>
		<author numeration="9" affiliations="3">
			<name>M. O. Andreae</name>
		</author>
		<author numeration="10" affiliations="3,7">
			<name>O. Schmid</name>
		</author>
	</authors>
	<affiliations>
		<affiliation numeration="1" content_type="html">Institute for Meteorology, University of Leipzig,  Leipzig, Germany</affiliation>
		<affiliation numeration="2" content_type="html">Leibniz-Institute for Tropospheric Research,  Leipzig, Germany</affiliation>
		<affiliation numeration="3" content_type="html">Max Planck Institute for  Chemistry, Biogeochemistry Dept., Mainz, Germany</affiliation>
		<affiliation numeration="4" content_type="html">Centre for Atmospheric Chemistry, York University, Toronto, Canada</affiliation>
		<affiliation numeration="5" content_type="html">Institute for Atmospheric Physics, Johannes Gutenberg University Mainz, Mainz, Germany</affiliation>
		<affiliation numeration="6" content_type="html">Remote Sensing Technology Institute, German Aerospace Centre, Wessling, Germany</affiliation>
		<affiliation numeration="7" content_type="html">Institute for Inhalation Biology, GSF-National Research Centre for Environment and Health, Neuherberg, Germany</affiliation>
		<affiliation numeration="8" content_type="html">IIMT Engineering College, Department of Applied Science, Ganga Nagar, Meerut, India</affiliation>
		<affiliation numeration="9" content_type="html">now at: Laboratoire Inter-Universitaire des Systèmes Atmosphériques (LISA), Université Paris 7/12 and CNRS (UMR 7583), Créteil, France</affiliation>
	</affiliations>
	<abstract content_type="html">A better characterisation of the optical properties of biomass
  burning aerosol as a function of the burning conditions is required
  in order to quantify their effects on climate and atmospheric
  chemistry. Controlled laboratory combustion experiments with
  different fuel types were carried out at the combustion facility of
  the Max Planck Institute for Chemistry (Mainz, Germany) as part of
  the &quot;Impact of Vegetation Fires on the Composition and Circulation
  of the Atmosphere&quot; (EFEU) project. The combustion conditions were
  monitored with concomitant CO&lt;sub&gt;2&lt;/sub&gt; and CO measurements. The mass
  scattering efficiencies of 8.9&amp;plusmn;0.2 m&lt;sup&gt;2&lt;/sup&gt; g&lt;sup&gt;&amp;minus;1&lt;/sup&gt; and
  9.3&amp;plusmn;0.3 m&lt;sup&gt;2&lt;/sup&gt; g&lt;sup&gt;&amp;minus;1&lt;/sup&gt; obtained for aerosol particles from the
  combustion of savanna grass and an African hardwood (musasa),
  respectively, are larger than typically reported mainly due to
  differences in particle size distribution. The photoacoustically
  measured mass absorption efficiencies of
  0.51&amp;plusmn;0.02 m&lt;sup&gt;2&lt;/sup&gt; g&lt;sup&gt;&amp;minus;1&lt;/sup&gt; and 0.50&amp;plusmn;0.02 m&lt;sup&gt;2&lt;/sup&gt; g&lt;sup&gt;&amp;minus;1&lt;/sup&gt;
  were at the lower end of the literature values. Using the measured
  size distributions as well as the mass scattering and absorption
  efficiencies, Mie calculations provided effective refractive indices
  of 1.60&amp;minus;0.010&lt;i&gt;i&lt;/i&gt; (savanna grass) and 1.56&amp;minus;0.010&lt;i&gt;i&lt;/i&gt; (musasa)
  (λ=0.55 μm).
  The apparent discrepancy between the low imaginary part of the
  refractive index and the high apparent elemental carbon
  (EC&lt;sub&gt;a&lt;/sub&gt;) fractions (8 to 15%) obtained from
  the thermographic analysis of impactor samples can be explained by a
  positive bias in the elemental carbon data due to the presence of
  high molecular weight organic substances.  Potential artefacts in
  optical properties due to instrument bias, non-natural burning
  conditions and unrealistic dilution history of the laboratory smoke
  cannot be ruled out and are also discussed in this study.</abstract>
	<references>
		<reference numeration="1" content_type="text"> Anderson, T. L. and Ogren, J. A.: Determine aerosol radiative properties using the TSI 3563 integrating nephelometer, Aerosol Sci. Technol., 29, 57–69, 1998. </reference>
		<reference numeration="2" content_type="text"> Andreae, M. O. and Gelencsér, A.: Black carbon or brown carbon? The nature of light absorbing carbonaceous aerosols, Atmos. Chem. Phys., 6, 3131–3148, 2006. </reference>
		<reference numeration="3" content_type="text"> Andreae, M. O. and Merlet, P.: Emission of trace gases and aerosols from biomass burning, Global Biogeochem. Cy., 14, 955–966, 2001. </reference>
		<reference numeration="4" content_type="text"> Andreae, M. O., Atlas, E., Cachier, H., Cofer III, W R., Harris, G., Helas, G., Koppmann, R., Lacaux, J., and Ward, D.: Trace gas and aerosol emissions from savanna fires, in: Biomass Burning and Global Change, edited by: Levine, J., MIT Press, Cambridge, Mass., 278–295, 1996. </reference>
		<reference numeration="5" content_type="text"> Andreae, M O.: Biomass Burning: Its History, Use, and Distribution and Its Impact on Environmental Quality and Global Climate, in: Global Biomass Burning: Atmospheric, Climatic, and Biospheric Implications, edited by: Levine, J., MIT Press, Cambridge, Mass., 3–21, 1991. </reference>
		<reference numeration="6" content_type="text"> Bergstrom, R W. and Russell, P B.: Wavelength dependence of the absorption of black carbon particles: Predictions and results from the TARFOX experiment and implications for the aerosol single scattering albedo, J.\ Atmos. Sci., 59, 567–77, 2002. </reference>
		<reference numeration="7" content_type="text"> Bohren, C F. and Huffman, D R.: Absorption and Scattering of Light by Small Particles, John Wiley &amp; Sons, Inc., 1983. </reference>
		<reference numeration="8" content_type="text"> Bond, T C., Bergstrom, R W., and Campbell, D.: Calibration and intercomparison of filter-based measurements of visible light absorption by aerosols, Aerosol Sci. Technol., 30, 582–600, 1999. </reference>
		<reference numeration="9" content_type="text"> Bond, T C.: Spectral dependence of visible light absorption by carbonaceous particles emitted from coal combustion, Geophys. Res. Lett., 28, 4075–4078, 2001. </reference>
		<reference numeration="10" content_type="text"> Bond, T C. and Bergstrom, R W.: Light absorption by carbonaceous particles: An investigative review, Aerosol Sci. Technol., 40, 27–67, \doi10.1080/02786820500421521, 2006. </reference>
		<reference numeration="11" content_type="text"> Carrico, C M., Kreidenweis, S M., Collett, Jr., J L., Engling, G., and McMeeking, G R.: Smoke Properties Derived from the Laboratory Combustion of Forest Fuels, Poster at the 23rd Annual AAAR Conference, Atlanta, Georgia, US, 2004. </reference>
		<reference numeration="12" content_type="text"> Chakrabarty, R K., Moosmüller, H., Garro, M A., Arnott, W P., Walker, J., Susott, R A., Babbitt, R E., Wold, C E., Lincoln, E N., and Hao, W M.: Emissions from the laboratory combustion of wildland fuels: Particle morphology and size, J. Geophys. Res., 111, D07204, \doi10.1029/2005JD006659, 2006. </reference>
		<reference numeration="13" content_type="text"> Chen, L.-W A., Moosmüller, H., Arnott, W P., Chow, J C., and Watson, J G.: Particle emissions from laboratory combustion of wildland fuels: In situ optical and mass measurements, Geophys. Res. Lett., 33, L04803, \doi10.1029/2005GL024838, 2006. </reference>
		<reference numeration="14" content_type="text"> Christian, T., Kleiss, B., Yokelson, R., Holzinger, R., Crutzen, P., Hao, W., Saharjo, B., and Ward, D.: Comprehensive laboratory measurements of biomass-burning emissions: 1. Emissions from Indonesian, African, and other fuels, J. Geophys. Res., 108, 4719, \doi10.1029/2003JD003704, 2003. </reference>
		<reference numeration="15" content_type="text"> Ch\&apos;ylek, P., Srivastava, V., Pinnick, R G., and Wang, R.: Scattering of electromagnetic waves by composite spherical particles: Experiment and effective medium approximation, Appl. Opt., 27, 2396–2404, 1988. </reference>
		<reference numeration="16" content_type="text"> Colarco, P R., Schoeberl, M R., Doddridge, B G., Marufu, L T., Torres, O., and Welton, E J.: Transport of smoke from Canadian forest fires to the surface near Washington, D.C.: Injection height, entrainment, and optical properties, J. Geophys. Res., 109, D06203, \doi10.1029/2003JD004248, 2004. </reference>
		<reference numeration="17" content_type="text"> Crutzen, P J. and Andreae, M. O.: Biomass burning in the tropics: Impact on the atmospheric chemistry and biogeochemical cycles, Science, 250, 1669–1678, 1990. </reference>
		<reference numeration="18" content_type="text"> Dubovik, O., Holben, B., Eck, T F., Smirnov, A., Kaufman, Y J., King, M D., Tanré, D., and Slutsker, I.: Variability of absorption and optical properties of key aerosol types observed in worldwide locations, J. Atmos.\ Sci., 59, 590–608, 2002. </reference>
		<reference numeration="19" content_type="text"> Ferek, R J., Reid, J S., Hobbs, P V., Blake, D R., and Liousse, C.: Emission factors of hydrocarbons, halocarbons, trace gases and particles from biomass burning in Brazil, J. Geophys. Res., 103, 32 107–32 118, 1998. </reference>
		<reference numeration="20" content_type="text"> Guyon, P., Boucher, O., Graham, B., Becka, J., Mayol-Bracero, O L., Roberts, G C., Maenhaut, W., Artaxo, P., and Andreae, M O.: Refractive index of aerosol particles over the Amazon tropical forest during LBA-EUSTACH 1999, J. Aerosol Sci., 34, 883–907, 2003. </reference>
		<reference numeration="21" content_type="text"> Hao, W M. and Liu, M.-H.: Spatial and temporal distribution of tropical biomass burning, Global Biogeochem. Cy., 8, 495–504, 1994. </reference>
		<reference numeration="22" content_type="text"> Haywood, J., Osborne, S., Francis, P., Keil, A., Formenti, P., Andreae, M. O., and Kaye, P H.: The mean physical and optical properties of regional haze dominated by biomass burning aerosol measured from the C-130 aircraft during SAFARI 2000, J. Geophys. Res., 108, 8473, \doi10.1029/2002JD002226, 2003. </reference>
		<reference numeration="23" content_type="text"> Hoffer, A., Gelencsér, A., Guyon, P., Kiss, G., Schmid, O., Frank, G., Artaxo, P., and Andreae, M O.: Optical properties of humic-like substances (HULIS) in biomass-burning aerosols, Atmos. Chem. Phys., 6, 3563–3570, 2006. </reference>
		<reference numeration="24" content_type="text"> Horvath, H.: Atmospheric light absorption – A review, Atmos. Environ., 27A, 293–317, 1993. </reference>
		<reference numeration="25" content_type="text"> Iinuma, Y., Brüggemann, E., Gnauk, T., Andreae, M. O., Helas, G., Müller, K., Parmar, R., and Herrmann, H.: Source characterization of biomass burning particles: The combustion of selected European conifers, African hardwood, savannah grass, German peat and Indonesian peat, J. Geophys.\ Res., 112, D08209, \doi10.1029/2006JD007120, 2007. </reference>
		<reference numeration="26" content_type="text"> Kaufman, Y., Hobbs, P., Kirchhoff, V., Artaxo, P., Remer, L., Holben, B., King, M., Ward, D., Prins, E., Longo, K., Mattos, L F., Nobre, C., Spinhirne, J., Ji, Q., Thompson, A., Gleason, J., Christopher, S., and Tsay, S.-C.: Smoke, Clouds, and Radiation-Brazil (SCAR-B) experiment, J. Geophys. Res., 103, 31 783–31 808, 1998. </reference>
		<reference numeration="27" content_type="text"> Koppmann, R., von Czapiewski, K., and Reid, J S.: A review of biomass burning emissions, Part I: Gaseous emissions of carbon monoxide, methane, volatile organic compounds, and nitrogen containing compounds, Atmos. Chem. Phys. Discuss., 5, 10 455–10 516, 2005. </reference>
		<reference numeration="28" content_type="text"> Lenoble, J.: The Particulate Matter from Biomass Burning: A Tutorial and Critical Review of Its Radiative Impact, in: Global Biomass Burning: Atmospheric, Climatic, and Biospheric Implications, edited by: Levine, J.,  MIT Press, Cambridge, Mass., 381–386, 1991. </reference>
		<reference numeration="29" content_type="text"> Lindesay, J., Andreae, M. O., Goldammer, J., Harris, G., Annegarn, H., Garstang, M., Scholes, R., and van Wilgen, B W.: International Geosphere Biosphere Programme/International Global Atmospheric Chemistry SAFARI-92 field experiment: Background and overview, J. Geophys. Res., 101, 23 521–23 530, 1996. % </reference>
		<reference numeration="30" content_type="text"> % Masonis, S. J. and Anderson, T. L. and Covert, D. S. and Kapustin, V. and % Clarke, A. D. and Howell, S. and Moore, K.: A study of the % extinction-to-backscatter ratio of marine % aerosol during the shoreline environment aerosol study, J. Atmos. Ocean. Technol., % 20, 1388–1402, 2003. </reference>
		<reference numeration="31" content_type="text"> Massling, A., Wiedensohler, A., Busch, B., Neusüss, C., Quinn, P., Bates, T., and Covert, D.: Hygroscopic properties of different aerosol types over the Atlantic and Indian Oceans, Atmos. Chem. Phys., 3, 1377–1397, 2003. </reference>
		<reference numeration="32" content_type="text"> Maxwell Garnett, J.: Colours in metal glasses and in metallic films, Philos.\ Trans. R. Soc. London, 203, 385–420, 1904. </reference>
		<reference numeration="33" content_type="text"> Mayol-Bracero, O L., Guyon, P., Graham, B., Roberts, G., Andreae, M O., Decesari, S., Facchini, M., Fuzzi, S., and Artaxo, P.: Water-soluble organic compounds in biomass burning aerosols over Amazonia. 2. Apportionment of the chemical composition and importance of the polyacidic fraction, J.\ Geophys. Res., D20, 8091, \doi10.1029/2001JD000522, 2002. </reference>
		<reference numeration="34" content_type="text"> McMeeking, G R., Kreidenweis, S M., Carrico, C M., Collett, J L., Day, D. E., and Malm, W C.: Observations of smoke-influenced aerosol during the Yosemite Aerosol Characterization Study: 2. Aerosol scattering and absorbing properties, J. Geophys. Res., 110, D18209, \doi10.1029/2005JD005907, 2005. </reference>
		<reference numeration="35" content_type="text"> Mugnai, A. and Wiscombe, W J.: Scattering from nonspherical Chebyshev particles. 1: Cross sections, single scattering albedo, asymmetry factor, and backscattered fraction, Appl. Opt., 25, 1235–1244, 1986. </reference>
		<reference numeration="36" content_type="text"> Patterson, E. and McMahon, C.: Absorption characteristics of forest fire particulate matter, Atmos. Environ., 18, 2541–2551, 1984. </reference>
		<reference numeration="37" content_type="text"> Patterson, E., McMahon, C., and Ward, D.: Absorption properties and graphitic carbon emission factors of forest fire aerosols, Geophys. Res. Lett., 13, 129–132, 1986. </reference>
		<reference numeration="38" content_type="text"> Penner, J., Dickinson, R., and O`Neill, C.: Effects of aerosol from biomass burning on the global radiation budget, Science, 256, 1432–1434, 1992. </reference>
		<reference numeration="39" content_type="text"> Penner, J., Chuang, C., and Grant, K.: Climate forcing by carbonaceous and sulfate aerosols, Clim. Dynam., 14, 839–851, 1998. </reference>
		<reference numeration="40" content_type="text"> Reid, J S. and Hobbs, P V.: Physical and optical properties of young smoke from individual biomass fires in Brazil, J. Geophys. Res., 103, 32 013–32 030, 1998. </reference>
		<reference numeration="41" content_type="text"> Reid, J S., Eck, T F., Christopher, S A., Koppmann, R., Dubovik, O., Eleuterio, D P., Holben, B N., Reid, E A., and Zhang, J.: A review of biomass burning emissions, Part III: Intensive optical properties of biomass burning particles, Atmos. Chem. Phys., 5, 827–849, 2005a. </reference>
		<reference numeration="42" content_type="text"> Reid, J S., Koppmann, R., Eck, T F., and Eleuterio, D P.: A review of biomass burning emissions, Part II: Intensive physical properties of biomass burning particles, Atmos. Chem. Phys., 5, 799–825, 2005b.  </reference>
		<reference numeration="43" content_type="text"> Rissler, J., Vestin, A., Swietlicki, E., Fisch, G., Zhou, J., Artaxo, P., and  Andreae, M O.: Size distribution and hygroscopic properties of aerosol  particles from dry-season biomass burning in Amazonia, Atmos. Chem.  Phys., 6, 471–491, 2006. %% </reference>
		<reference numeration="44" content_type="text"> %% Schkolnik, G., Chand, D., Hoffer, A., Andreae, M. O., Erlick, C., %% Swietlicki, E. and Rudich, Y.: %% Constraining the density and complex refractive index of elemental and %% organic carbon in biomass burning aerosol using optical and chemical %% measurements, %% Atmos. Environ., 41, 1107–1118, 2007 </reference>
		<reference numeration="45" content_type="text"> Schmid, H., Laskus, L., Abraham, H J., Baltensperger, U., Lavanchy, V., Bizjak, M., Burba, P., Cachier, H., Crow, D., Chow, J., Gnauk, T., Even, A., ten Brink, H M., Giesen, K.-P., Hitzenberger, R., Hueglin, C., Maenhaut, W., Pio, C., Carvalho, A., Putaud, J.-P., Toom-Sauntry, D., and Puxbaum, H.: Results of the &quot;carbon conference&quot; international aerosol carbon round robin test stage I, Atmos. Environ., 35, 2111–2121, 2001  </reference>
		<reference numeration="46" content_type="text"> Schmid, O., Artaxo, P., Arnott, W., Chand, D., Gatti, L., Franck, G., Hoffer, A., Schnaiter, M., and Andreae, M. O.: Spectral light absorption by ambient aerosols influenced by biomass burning in the Amazon Basin. I: Comparison and field calibration of absorption measurement techniques, Atmos. Chem. Phys., 6, 3443–3462, 2006. </reference>
		<reference numeration="47" content_type="text"> Schmid, O., Karg, E., Hagen, D E., Whitefield, P D., Ferron, G.: On the effective density of non-spherical particles as derived from combined measurements of aerodynamic and mobility equivalent size, J. Aerosol Sci., 38, 431–443, 2007. </reference>
		<reference numeration="48" content_type="text"> Schnaiter, M., Schmid, O., Petzold, A., Fritzsche, L., Klein, K.-F., Andreae, M O., Helas, G., Thielmann, A., Gimmler, M., Moehler, O., Linke, C., and Schurath, U.: Measurement of wavelength.resolved light absorption by aerosol utilizing a UV-VIS extinction cell, Aerosol Sci. Technol., 39, 249–260, 2005. </reference>
		<reference numeration="49" content_type="text"> Schneider, J., Weimer, S., Drewnick, F., Borrmann, S., Helas, G., Gwaze, P., Schmid, O., Andreae, M. O., and U. Kirchner, U.: Mass spectrometric analysis and aerodynamic properties of various types of combustion-related aerosol particles, Int. J. Mass. Spec., 258, 37–49, 2006. </reference>
		<reference numeration="50" content_type="text"> Simoneit, B. R T.: Biomass burning – a review of organic tracers for smoke from incomplete combustion, Appl. Geochem., 17, 129–162, 2002. </reference>
		<reference numeration="51" content_type="text"> Swap, R., Annegarn, H., Suttles, J., Haywood, J., Helmlinger, M., Hely, C., Hobbs, P., Holben, B., Ji, J., King, M., Landmann, T., Maenhaut, W., Otter, L., Pak, B., Piketh, S., Platnick, S., Privette, J., Roy, D., Thompson, A., Ward, D., and Yokelson, R.: The Southern African Regional Science Initiative (SAFARI 2000): Overview of the dry season field campaign, S Afr J Sci., 98, 125–130, 2002. </reference>
		<reference numeration="52" content_type="text"> Wurzler, S., Herrmann, H., Neusüß, C., Stratmann, F., Wiedensohler, A., Wilck, M., Trautmann, T., Andreae, M O., Helas, G., Trentmann, J., Langmann, B., Graf, H., and Textor, C.: Impact of vegetation fires on the composition and circulation of the atmosphere: Introduction of the research project EFEU, J. Aerosol Sci., 32, Suppl. 1, S199–S200, 2001. </reference>
	</references>
</article>

