Atmospheric chemistry of trans-CF3CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation M. S. Javadi1, R. Søndergaard1, O. J. Nielsen1, M. D. Hurley2, and T. J. Wallington2 1Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark 2System Analytics and Environmental Sciences Department, Ford Motor Company, Mail Drop RIC-2122, Dearborn, Michigan 48121-2053, USA
Abstract. Smog chamber/FTIR techniques were used to study the products and mechanisms
of OH radical and Cl atom initiated oxidation of trans-CF3CH=CHF in 700 Torr
of N2/O2 diluent at 295±1 K. Hydroxyl radical initiated
oxidation leads to the formation of CF3CHO and HC(O)F in yields which
were indistinguishable from 100% and were not dependent on the O2
partial pressure. Chlorine atom initiated oxidation gives HC(O)F,
CF3CHO, CF3C(O)Cl, and CF3C(O)CHFCl. The yields of
CF3C(O)Cl and CF3C(O)CHFCl increased at the expense of HC(O)F and
CF3CHO as the O2 partial pressure was increased over the range
5–700 Torr. The results are discussed with respect to the atmospheric
chemistry and environmental impact of trans-CF3CH=CHF.
Citation: Javadi, M. S., Søndergaard, R., Nielsen, O. J., Hurley, M. D., and Wallington, T. J.: Atmospheric chemistry of trans-CF3CH=CHF: products and mechanisms of hydroxyl radical and chlorine atom initiated oxidation, Atmos. Chem. Phys., 8, 3141-3147, doi:10.5194/acp-8-3141-2008, 2008.