Atmos. Chem. Phys., 7, 4281-4294, 2007
www.atmos-chem-phys.net/7/4281/2007/
doi:10.5194/acp-7-4281-2007
© Author(s) 2007. This work is licensed under the
Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
Vertical profiles of lightning-produced NO2 enhancements in the upper troposphere observed by OSIRIS
C. E. Sioris1,2,3, C. A. McLinden1, R. V. Martin3,4, B. Sauvage4, C. S. Haley5, N. D. Lloyd2, E. J. Llewellyn2, P. F. Bernath6,7, C. D. Boone6, S. Brohede8, and C. T. McElroy1
1Experimental Studies Section, Environment Canada, Toronto, ON, Canada
2Institute of Space and Atmospheric Studies, University of Saskatchewan, Saskatoon, SK, Canada
3Atomic and Molecular Physics Division, Harvard-Smithsonian Center for Astrophysics, Cambridge, MA, USA
4Department of Physics and Atmospheric Science, Dalhousie University, Halifax, NS, Canada
5Department of Physics and Atmospheric Science, Dalhousie University, Centre for Research in Earth and Space Science, York University, Toronto, Ontario, Canada
6Department of Chemistry, University of Waterloo, Waterloo, ON, Canada
7Department of Chemistry, University of York, Heslington, York, UK
8Department of Radio and Space Science, Chalmers University of Technology, Göteborg, Sweden

Abstract. The purpose of this study is to perform a global search of the upper troposphere (z≥10 km) for enhancements of nitrogen dioxide and determine their sources. This is the first application of satellite-based limb scattering to study upper tropospheric NO2. We have searched two years (May 2003–May 2005) of OSIRIS (Optical Spectrograph and Infrared Imager System) operational NO2 concentrations (version 2.3/2.4) to find large enhancements in the observations by comparing with photochemical box model calculations and by identifying local maxima in NO2 volume mixing ratio. We find that lightning is the main production mechanism responsible for the large enhancements in OSIRIS NO2 observations as expected. Similar patterns in the abundances and spatial distribution of the NO2 enhancements are obtained by perturbing the lightning within the GEOS-Chem 3-dimensional chemical transport model. In most cases, the presence of lightning is confirmed with coincident imagery from LIS (Lightning Imaging Sensor) and the spatial extent of the NO2 enhancement is mapped using nadir observations of tropospheric NO2 at high spatial resolution from SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric Chartography) and OMI (Ozone Monitoring Instrument). The combination of the lightning and chemical sensors allows us to investigate globally the role of lightning to the abundance of NO2 in the upper troposphere (UT). Lightning contributes 60% of the tropical upper tropospheric NO2 in GEOS-Chem simulations. The spatial and temporal distribution of NO2 enhancements from lightning (May 2003–May 2005) is investigated. The enhancements generally occur at 12 to 13 km more frequently than at 10 to 11 km. This is consistent with the notion that most of the NO2 is forming and persisting near the cloud top altitude in the tropical upper troposphere. The latitudinal distribution is mostly as expected. In general, the thunderstorms exhibiting weaker vertical development (e.g. 11≤z≤13 km) extend latitudinally as far poleward as 45° but the thunderstorms with stronger vertical development (z≥14 km) tend to be located within 33° of the equator. There is also the expected hemispheric asymmetry in the frequency of the NO2 enhancements, as most were observed in the northern hemisphere for the period analyzed.

Citation: Sioris, C. E., McLinden, C. A., Martin, R. V., Sauvage, B., Haley, C. S., Lloyd, N. D., Llewellyn, E. J., Bernath, P. F., Boone, C. D., Brohede, S., and McElroy, C. T.: Vertical profiles of lightning-produced NO2 enhancements in the upper troposphere observed by OSIRIS, Atmos. Chem. Phys., 7, 4281-4294, doi:10.5194/acp-7-4281-2007, 2007.
 
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