<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-7-4203-2007</article-id>
<title-group>
<article-title>Insights into the role of soot aerosols in cirrus cloud formation</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kärcher</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Möhler</surname>
<given-names>O.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>DeMott</surname>
<given-names>P. J.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pechtl</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yu</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Deutsches Zentrum für Luft- und Raumfahrt (DLR), Institut  für Physik der Atmosphäre (IPA), Oberpfaffenhofen, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Forschungszentrum Karlsruhe, Institut  für Meteorologie und Klimaforschung (IMK-AAF), Karlsruhe, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Atmospheric Science, Colorado State University,  Fort Collins, CO, 80523, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Ruprecht-Karls-Universität Heidelberg, Institut für  Umweltphysik (IUP), Heidelberg, Germany</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>State University of New York at Albany (SUNY), Atmospheric  Sciences Research Center (ASRC), NY, USA</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>now at: Deutsches Patent- und Markenamt, München, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>17</day>
<month>08</month>
<year>2007</year>
</pub-date>
<volume>7</volume>
<issue>16</issue>
<fpage>4203</fpage>
<lpage>4227</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/7/4203/2007/acp-7-4203-2007.html">This article is available from http://www.atmos-chem-phys.net/7/4203/2007/acp-7-4203-2007.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/7/4203/2007/acp-7-4203-2007.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/7/4203/2007/acp-7-4203-2007.pdf</self-uri>
<abstract>
<p>Cirrus cloud formation is believed to be dominated by homogeneous freezing
of supercooled liquid aerosols in many instances. Heterogeneous ice nuclei
such as mineral dust, metallic, and soot particles, and some crystalline
solids within partially soluble aerosols are suspected to modulate cirrus
properties. Among those, the role of ubiquitous soot particles is perhaps
the least understood. Because aviation is a major source of upper
tropospheric soot particles, we put emphasis on ice formation in dispersing
aircraft plumes. The effect of aircraft soot on cirrus formation in the
absence of contrails is highly complex and depends on a wide array of
emission and environmental parameters. We use a microphysical-chemical model
predicting the formation of internally mixed, soot-containing particles up to
two days after emission, and suggest two principal scenarios: high
concentrations of original soot emissions could slightly increase the number
of ice crystals; low concentrations of particles originating from coagulation
of emitted soot with background aerosols could lead to a significant reduction
in ice crystal number. Both scenarios assume soot particles to be moderate ice
nuclei relative to cirrus formation by homogeneous freezing in the presence of
few efficient dust ice nuclei. A critical discussion of laboratory experiments
reveals that the ice nucleation efficiency of soot particles depends strongly
on their source, and, by inference, on atmospheric aging processes. Mass and
chemistry of soluble surface coatings appear to be crucial factors. Immersed
soot particles tend to be poor ice nuclei, some bare ones nucleate ice at low
supersaturations. However, a fundamental understanding of these studies is
lacking, rendering extrapolations to atmospheric conditions speculative. In
particular, we cannot yet decide which indirect aircraft effect scenario is
more plausible, and options suggested to mitigate the problem remain uncertain.</p>
</abstract>
<counts><page-count count="25"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Abbatt, J. P. D., Benz, S., Cziczo, D. J., Kanji, Z., Lohmann, U., and Möhler, O.: Solid ammonium sulfate aerosols as ice nuclei: A Pathway for cirrus cloud formation, Science, 313, 5794, 1770&amp;ndash;1773, 2006. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Ackerman, S., Toon, O. B., Stevens, D. E., Heymsfield, A. J., Ramanathan, V., and Welton, E. J.: Reduction of tropical cloudiness, Science, 288, 1042&amp;ndash;1047, 2000. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Anderson, B. E., Cofer, W. R., Crawford, J., Gregory, G. L., Vay, S. A., Brunke, K. E., Kondo, Y., Koike, M., Schlager, H., Baughcum, S. L., Jensen, E., Zhao, Y., and Kita, K.: An assessment of aircraft as a source of particles to the upper troposphere, Geophys. Res. Lett., 26, 3069&amp;ndash;3072, 1999. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Archeluta, C. M., DeMott, P. J., and Kreidenweis, S. M.: Ice nucleation by surrogates for atmospheric mineral dust and mineral dust/sulfate particles at cirrus temperatures, Atmos. Chem. Phys., 5, 2617&amp;ndash;2634, 2005. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Baumgardner, D., Kok, G., and Raga, G.: Warming of the Arctic lower stratosphere by light absorbing particles, Geophys. Res. Lett., 31, L06117, doi:10.1029/2003GL018883, 2004. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Beaver, M. R., Elrod, M. J., Garland, R. M., and Tolbert, M. A.: Ice nucleation in sulfuric acid/organic aerosols: Implications for cirrus cloud formation, Atmos. Chem. Phys., 6, 3231&amp;ndash;3242, 2006. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Blake, D. F. and Kato, K.: Latitudinal distribution of black carbon soot in the upper troposphere and lower stratosphere, J. Geophys. Res., 100, 7195&amp;ndash;7202, 1995. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Buck, A.L.: New equations for computing vapor pressures and enhancement factor, J. Appl. Meteorol., 20, 1527&amp;ndash;1532, 1981. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Cantrell, W. and Heymsfield, A. J.: Production of ice in tropospheric clouds &amp;ndash; a review, Bull. Amer. Meteorol. Soc., 86, 795&amp;ndash;807, 2005. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Chen, Y., Kreidenweis, S. M., McInnes, L. M., Rogers, D. C., and DeMott, P. J.: Single particle analysis of ice nucleation aerosols in the upper troposphere and lower stratosphere, Geophys. Res. Lett., 25, 1391&amp;ndash;1394, 1998. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Cziczo, D. J., Murphy, D. M., Hudson, P. K., and Thomson, D. S.: Single particle measurements of the composition of cirrus ice residues during CRYSTAL-FACE, J. Geophys. Res., 109, D04201, doi:10.1029/2004JD004032, 2004. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Clarke, A. D., Shinozuka, Y., Kapustin, V. N., Howell, S., Huebert, B., Doherty, S., Anderson, T., Covert, D., Anderson, J., Hua, X., Moore II, K. G., McNaughton, C., Carmichael, G., and Weber, R.: Size distributions and mixtures of dust and black carbon aerosol in Asian outflow: Physiochemistry and optical properties, J. Geophys. Res., 109, D15S09, doi:10.1029/2003JD004378, 2004. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Chylek, P., Dubey, M. K., Lohmann, U., Ramanathan, V., Kaufman, Y. J., Lesins, G., Hudson, J., Altmann, G., and Olsen, S.: Aerosol indirect effect over the Indian Ocean, Geophys. Res. Lett., 33, L06806, doi:10.1029/2005GL025397, 2006. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Danilin, M. Y., Fahey, D. W., Schumann, U., Prather, M. J., Penner, J. E., Ko, M. K. W., Weisenstein, D. K., Jackman, C. H., Pitari, G., Köhler, I., Sausen, R., Weaver, C. J., Douglass, A. R., Connell, P. S., Kinnison, D. E., Dentener, F. J., Fleming, E. L., Berntsen, T. K., Isaksen, I. S. A., Haywood, J. M., and Kärcher, B.: Aviation fuel tracer simulations: Model intercomparison and implications, Geophys. Res. Lett., 25, 3947&amp;ndash;3950, 1998. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> DeMott, P. J.: An exploratory study of ice nucleation by soot aerosols, J. Appl. Meteorol., 29, 1072&amp;ndash;1079, 1990. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> DeMott, P. J., Rogers, D. C., and Kreidenweis, S. M.: The susceptibility of ice formation in upper tropospheric clouds to insoluble aerosol components, J. Geophys. Res., 102, 19 575&amp;ndash;19 584, 1997. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> DeMott, P. J., Chen, Y., Kreidenweis, S. M., Rogers, D. C., and Sherman, D. E.: Ice formation by black carbon particles, Geophys. Res. Lett., 26, 2429&amp;ndash;2432, 1999. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> DeMott, P. J., Cziczo, D. J., Prenni, A. J., Murphy, D. M., Kreidenweis, S. M., Thomson, D. S., Borys, R., and Rogers, D. C.: Measurements of the concentration abd composition of nuclei for cirrus formation, Proc. Natl. Acad. Sci., 100, 14 655&amp;ndash;14 660, 2003. %</mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> %DeMott, P. J., Petters, M. D., Prenni, A. J., Kreidenweis, S. M., Stanglmaier, %R., Bennett, M., Willson, B., and Volckens, J.: Cloud activation behaviors of %some diesel exhaust particles, J. Geophys. Res., to be submitted, 2007a. %</mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> %DeMott, P. J., Petters, M. D., Prenni, A. J., Carrico, C. M., and Kreidenweis, %S. M.: Ice nucleation behavior of biomass combustion particles, Atmos. Chem. %Phys., to be submitted, 2007b. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Diehl, K. and Mitra, S. K.: A laboratory study of the effects of a kerosene burner exhaust on ice nucleation and the evaporation rate of ice crystals, Atmos. Environ., 32, 3145&amp;ndash;3151, 1998. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Dymarska, M., Murray, B. J., Sun, L., Eastwood, M. L., Knopf, D. A., and Bertram, A. K.: Deposition ice nucleation on soot at temperatures relevant for the lower troposphere, J. Geophys. Res., 111, D04204, doi:10.1029/2005JD006627, 2006. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Fahey, D. W., Keim, E. R., Boering, K. A., Brock, C. A., Wilson, J. C., Jonsson, H. H., Anthony, S., Hanisco, T. F., Wennberg, P. O., Miake-Lye, R. C., Salawitch, R. J., Louisnard, N., Woodbridge, E. L., Gao, R. S., Donnelly, S. G., Wamsley, R. C., DelNegro, L. A., Solomon, S., Danube, B. C., Wofsy, S. C., Webster, C.R., May, R. D., Kelly, K. K., Loewenstein, M., Podolske, J. R., and Chan, K. R.: Emission measurements of the Concorde supersonic aircraft in the lower stratosphere, Science, 270, 70&amp;ndash;74, 1995. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Gerz, Th., Dürbeck, T., and Konopka, P.: Transport and effective diffusion of aircraft emissions, J. Geophys. Res., 103, 25 905&amp;ndash;25 914, 1998. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Gierens, K.: On the transition between heterogeneous and homogeneous freezing, Atmos. Chem. Phys., 3, 437&amp;ndash;446, 2003. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Gorbunov, B., Baklanov, A., Kakutkina, N., Windsor, H. L., and Tuomi, R.: Ice nucleation on soot particles, J. Aerosol Sci., 32, 199&amp;ndash;215, 2001. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Haag, W., Kärcher, B., Ström, J., Minikin, A., Ovarlez, J., Lohmann, U., and Stohl, A.: Freezing thresholds and cirrus cloud formation mechanisms inferred from in situ measurements of relative humidity, Atmos. Chem. Phys., 3, 1791&amp;ndash;1806, 2003a. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> Haag, W., Kärcher, B., Schaefers, S., Stetzer, O., Möhler, O., Schurath, U., Krämer, M., and Schiller, C.: Numerical simulations of homogeneous freezing processes in the aerosol chamber AIDA, Atmos. Chem. Phys., 3, 195&amp;ndash;210, 2003b. </mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple"> Haag, W. and Kärcher, B.: The impact of aerosols and gravity waves on cirrus clouds at midlatitudes, J. Geophys. Res., 109, D12202, doi:10.1029/2004JD004579, 2004. </mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple"> Hagen, D. E., Trueblood, M. B., and Podzimek, J.: Combustion aerosol scavenging, Atmos. Environ., 25A, 2581&amp;ndash;2586, 1991. </mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple"> Hansen, J. and Nazarenko, L.: Soot climate forcing via snow and ice albedo, Proc. Natl. Acad. Sci., 100, 423&amp;ndash;428, 2004. </mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple"> Heintzenberg, J., Okada, K., and Ström, J.: On the composition of non-volatile material in upper tropospheric aerosols and cirrus crystals, Atmos. Res., 41, 81&amp;ndash;88, 1996. </mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple"> Hendricks, J., Kärcher, B., Döpelheuer, A., Feichter, J., Lohmann, U., and Baumgardner, D.: Simulating the global black carbon cycle: A revisit to the contribution of aircraft emissions, Atmos. Chem. Phys., 4, 2521&amp;ndash;2541, 2004. </mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple"> Hendricks, J., Kärcher, B., Lohmann, U., and Ponater, M.: Do aircraft black carbon emissions affect cirrus clouds on the global scale?, Geophys. Res. Lett., 32, L12814, doi:10.1029/2005GL022740, 2005. </mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple"> Hobbs, P. V.: Ice Physics, Clarendon Press, Oxford, UK, 837p., 1974. </mixed-citation>
</ref>
<ref id="ref36">
<label>36</label><mixed-citation publication-type="other" xlink:type="simple"> Hofmann, D. J.: Twenty years of balloon-borne tropospheric aerosol measurements at Laramie, Wyoming, J. Geophys. Res., 98, 12 753&amp;ndash;12 766, 1993. </mixed-citation>
</ref>
<ref id="ref37">
<label>37</label><mixed-citation publication-type="other" xlink:type="simple"> Hofmann, D. J., Stone, R. S., Wood, M. E., Deshler, T., and Harris, J. M.: An analysis of 25 years of balloon-borne aerosol data in search of a signature of the subsonic commercial aircraft fleet, Geophys. Res. Lett., 25, 2433&amp;ndash;2436, 1998. </mixed-citation>
</ref>
<ref id="ref38">
<label>38</label><mixed-citation publication-type="other" xlink:type="simple"> Hung, H. M., Malinowski, A., and Martin, S. T.: Kinetics of heterogeneous ice nucleation on the surfaces of mineral dust coresinserted into aqueous ammonium sulfate particles, J. Phys. Chem. A, 107, 1296&amp;ndash;1306, 2003. </mixed-citation>
</ref>
<ref id="ref39">
<label>39</label><mixed-citation publication-type="other" xlink:type="simple"> Jacobson, M. Z.: Strong radiative heating due to the mixing state of black carbon in atmospheric aerosols, Nature, 409, 695&amp;ndash;697, 2001. </mixed-citation>
</ref>
<ref id="ref40">
<label>40</label><mixed-citation publication-type="other" xlink:type="simple"> Jacobson, M. Z.: Analysis of aerosol interactions with numerical techniques for solving coagulation, nucleation, condensation, dissolution, and reversible chemistry among multiple size distributions, J. Geophys. Res., 107, 4366, doi:10.1029/2001JD002044, 2002. </mixed-citation>
</ref>
<ref id="ref41">
<label>41</label><mixed-citation publication-type="other" xlink:type="simple"> Jensen E. J. and Toon, O. B.: The potential impact of soot particles from aircraft exhaust on cirrus clouds, Geophys. Res. Lett., 24, 249&amp;ndash;252, 1997. </mixed-citation>
</ref>
<ref id="ref42">
<label>42</label><mixed-citation publication-type="other" xlink:type="simple"> Jensen, E. J., Ackerman, A. S., Stevens, D. E., Toon, O. B., and Minnis, P.: Spreading and growth of contrails in a sheared environment, J. Geophys. Res., 103, 31 557&amp;ndash;31 567, 1998. </mixed-citation>
</ref>
<ref id="ref43">
<label>43</label><mixed-citation publication-type="other" xlink:type="simple"> Johnson, B. T., Shine, K. P., and Forster, P. M.: The semi-direct aerosol effect: Impact of absorbing aerosols on marine stratocumulus, Quart. J. Roy. Meteorol. Soc., 130, 1407&amp;ndash;1422, 2004. </mixed-citation>
</ref>
<ref id="ref44">
<label>44</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B.: Aviation-produced aerosols and contrails, Surv. Geophys., 20, 113&amp;ndash;167, 1999. </mixed-citation>
</ref>
<ref id="ref45">
<label>45</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B.: Contrails: Observations, formation mechanisms, atmospheric impacts, uncertainties, Research Report, Deutsches Zentrum f. Luft- u. Raumfahrt, DLR-Mitt., 2000-01, 47pp, 2000. </mixed-citation>
</ref>
<ref id="ref46">
<label>46</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B. and Meilinger, S. K.: Perturbation of the aerosol layer by aviation-produced aerosols: A Parametrization of plume processes, Geophys. Res. Lett., 25, 4465&amp;ndash;4468, 1998. </mixed-citation>
</ref>
<ref id="ref47">
<label>47</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B. and Ström, J.: The roles of dynamical variability and aerosols in cirrus cloud formation, Atmos. Chem. Phys., 3, 823&amp;ndash;838, 2003. </mixed-citation>
</ref>
<ref id="ref48">
<label>48</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B., Peter, Th., and Ottmann, R.: Contrail formation: Homogeneous nucleation of \chemH_2SO_4/H_2O droplets, Geophys. Res. Lett., 22, 1501&amp;ndash;1504, 1995. </mixed-citation>
</ref>
<ref id="ref49">
<label>49</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B., Peter, Th., Biermann, U. M., and Schumann, U.: The initial composition of jet condensation trails, J. Atmos. Sci., 53, 3066&amp;ndash;3083, 1996. </mixed-citation>
</ref>
<ref id="ref50">
<label>50</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B., Turco, R. P., Yu, F., Danilin, M. Y., Weisenstein, D. K., Miake-Lye, R. C., and Busen, R.: A unified model for ultrafine aircraft particle emissions, J. Geophys. Res., 105, 29 379&amp;ndash;29 386, 2000. </mixed-citation>
</ref>
<ref id="ref51">
<label>51</label><mixed-citation publication-type="other" xlink:type="simple"> Kärcher, B., Hendricks, J., and Lohmann, U.: Physically-based parameterization of cirrus cloud formation for use in global atmospheric models, J. Geophys. Res., 111, D01205, doi:10.1029/JD006219, 2006. </mixed-citation>
</ref>
<ref id="ref52">
<label>52</label><mixed-citation publication-type="other" xlink:type="simple"> Kanji, Z. A. and Abbatt, J. P. D.: Laboratory studies of ice formation via deposition mode nucleation onto mineral dust and n-hexane soot samples, J. Geophys. Res., 111, D16204, doi:10.1029/2005JD006766, 2006. </mixed-citation>
</ref>
<ref id="ref53">
<label>53</label><mixed-citation publication-type="other" xlink:type="simple"> Kjellström, E., Feichter, J., Sausen, R., and Hein, R.: The contribution of aircraft emissions to the atmospheric sulfur budget, Atmos. Environ., 33, 3455&amp;ndash;3465, 1999. %</mixed-citation>
</ref>
<ref id="ref54">
<label>54</label><mixed-citation publication-type="other" xlink:type="simple"> %Koehler, K., Petters, M. D., DeMott, P. J., Kreidenweis, S. M., and %Popovicheva, O. B.: Cloud condensation nuclei activity and ice nucleation %ability of selected combustion particles, Atmos. Chem. Phys., to be %submitted, 2007. </mixed-citation>
</ref>
<ref id="ref55">
<label>55</label><mixed-citation publication-type="other" xlink:type="simple"> Knopf, D. A. and Koop, T.: Heterogeneous nucleation of ice on surrogates of mineral dust, J. Geophys. Res., 111, D12201, doi:10.1029/2005JD006894, 2006. </mixed-citation>
</ref>
<ref id="ref56">
<label>56</label><mixed-citation publication-type="other" xlink:type="simple"> Koop, T., Luo, B. P., Tsias, A., and Peter, Th.: Water activity as the determinant for homogeneous ice nucleation in aqueous solutions, Nature, 406, 611&amp;ndash;614, 2000. </mixed-citation>
</ref>
<ref id="ref57">
<label>57</label><mixed-citation publication-type="other" xlink:type="simple"> Law, K., Pan, L., Wernli, H., Fischer, H., Haynes, P., Salawitch, R., Kärcher, B., Prather, M., Doherty S., and Ravishankara, A. R.: Processes governing the chemical composition of the extratropical UTLS, SPARC Newsletter No 26, 8&amp;ndash;19, 2006. </mixed-citation>
</ref>
<ref id="ref58">
<label>58</label><mixed-citation publication-type="other" xlink:type="simple"> Liu, L. and Mishchenko, M. I.: Effects of aggregation on scattering and radiative properties of soot aerosols, J. Geophys. Res., 110, D11211, doi:10.1029/2004JD005649, 2005. </mixed-citation>
</ref>
<ref id="ref59">
<label>59</label><mixed-citation publication-type="other" xlink:type="simple"> Luo, B. P., Carslaw, K. S., Peter, Th., and Clegg, S. L.: Vapour pressures of \chemH_2SO_4/HNO_3/HCl/HBr/H_2O solutions to low stratospheric temperatures, Geophys. Res. Lett., 22, 247&amp;ndash;250, 1995. %</mixed-citation>
</ref>
<ref id="ref60">
<label>60</label><mixed-citation publication-type="other" xlink:type="simple"> %Mannstein, H. and Schumann, U.: Aircraft-induced contrail cirrus over %Europe, Meteorol. Z., 14, 549&amp;ndash;554, 2005. </mixed-citation>
</ref>
<ref id="ref61">
<label>61</label><mixed-citation publication-type="other" xlink:type="simple"> Marquart, S., Ponater, M., Mager, F., and Sausen, R.: Future development of contrail cover, optical depth, and radiative forcing: Impacts of increasing air traffic and climate change, J. Clim., 16, 2890&amp;ndash;2904, 2003. </mixed-citation>
</ref>
<ref id="ref62">
<label>62</label><mixed-citation publication-type="other" xlink:type="simple"> Minikin, A., Petzold, A., Ström, J., Krejci, R., Seifert, M., van Velthoven, P., Schlager, H., and Schumann, U.: Aircraft observations of the upper tropospheric fine particle aerosol in the northern and southern hemispheres at midlatitudes, Geophys. Res. Lett., 30, 1503, doi:10.1029/2002GL016458, 2003. </mixed-citation>
</ref>
<ref id="ref63">
<label>63</label><mixed-citation publication-type="other" xlink:type="simple"> Minnis, P., Schumann, U., Doelling, D. R., Gierens, K., and Fahey, D. W.: Global distribution of contrail radiative forcing, Geophys. Res. Lett., 26, 1853&amp;ndash;1856, 1999. </mixed-citation>
</ref>
<ref id="ref64">
<label>64</label><mixed-citation publication-type="other" xlink:type="simple"> Möhler, O., Stetzer, O., Schaefers, S., Linke, C., Schnaiter, M., Tiede, R., Saathoff, H., Krämer, M., Mangold, A., Budz, P., Zink., P., Schreiner, J., Mauersberger, K., Haag, W., Kärcher, B., and Schurath, U.: Experimental investigations of homogeneous freezing of sulphuric acid particles in the aerosol chamber AIDA, Atmos. Chem. Phys., 3, 211&amp;ndash;223, 2003. </mixed-citation>
</ref>
<ref id="ref65">
<label>65</label><mixed-citation publication-type="other" xlink:type="simple"> Möhler, O., Büttner, S., Linke, C., Schnaiter, M., Saathoff, H., Stetzer, O., Wagner, R., Krämer, M., Mangold, A., Ebert, V., and Schurath, U.: Effect of sulfuric acid coating on heterogeneous ice nucleation by soot aerosol particles, J. Geophys. Res., 110, D11210, doi:10.1029/2004JD005169, 2005a. </mixed-citation>
</ref>
<ref id="ref66">
<label>66</label><mixed-citation publication-type="other" xlink:type="simple"> Möhler, O., Linke, C., Saathoff, H., Schnaiter, M., Wagner, R., Mangold, A., Krämer, M., and Schurath, U.: Ice nucleation on flame soot aerosol of different organic carbon content, Meteorol. Z., 14, 477&amp;ndash;484, 2005b. </mixed-citation>
</ref>
<ref id="ref67">
<label>67</label><mixed-citation publication-type="other" xlink:type="simple"> Möhler, O., Field, P. R., Connolly, P., Benz, S., Saathoff, H., Schnaiter, M., Wagner, R., Cotton, R., Krämer, M., Mangold, A., and Heymsfield, A.: Efficiency of the deposition mode ice nucleation on mineral dust particles, Atmos. Chem. Phys., 6, 3007&amp;ndash;3021, 2006. </mixed-citation>
</ref>
<ref id="ref68">
<label>68</label><mixed-citation publication-type="other" xlink:type="simple"> Murphy, D. M., Thomson, D. S., and Mahoney, M. J.: In situ measurements of organics, meteoritic material, mercury, and other elements in aerosols at 5 to 19 kilometers, Science, 282, 1664&amp;ndash;1669, 1998. </mixed-citation>
</ref>
<ref id="ref69">
<label>69</label><mixed-citation publication-type="other" xlink:type="simple"> Murphy, D. M. and Koop, T.: Review of the vapour pressures of ice and supercooled water for atmospheric applications, Quart. J. Roy. Meteorol. Soc., 131, 1539&amp;ndash;1565, 2005. </mixed-citation>
</ref>
<ref id="ref70">
<label>70</label><mixed-citation publication-type="other" xlink:type="simple"> Murphy, D. M., Cziczo, D. J., Froyd, K. D., Hudson, P. K., Matthew, B. M., Middlebrook, A. M., Peltier, R. E., Sullivan, A., Thomson, D. S., and Weber, R. J.: Single-particle mass spectrometry of tropospheric aerosol particles, J. Geophys. Res., 111, D23S32, doi:10.1029/2006JD007340, 2006. </mixed-citation>
</ref>
<ref id="ref71">
<label>71</label><mixed-citation publication-type="other" xlink:type="simple"> Murphy, D. M., Cziczo, D. J., Hudson, P. K., and Thomson, D. S.: Carbonaceous material in aerosol particles in the lower stratosphere and tropopause region, J. Geophys. Res., 112, D04203, doi:10.1029/2006JD007297, 2007. </mixed-citation>
</ref>
<ref id="ref72">
<label>72</label><mixed-citation publication-type="other" xlink:type="simple"> Novakov, T., Menon, S., Kirchstetter, T. W., Koch, D., and Hansen, J. E.: Aerosol organic carbon to black carbon ratios: Analysis of published data and implications for climate forcing, J. Geophys. Res., 110, D21205, doi:10.1029/2005JD005977, 2005. </mixed-citation>
</ref>
<ref id="ref73">
<label>73</label><mixed-citation publication-type="other" xlink:type="simple"> Petzold, A., Döpelheuer, A., Brock, C. A., and Schröder, F.: In situ observations and model calculations of black carbon emission by aircraft at cruise altitude, J. Geophys. Res., 104, 22 171&amp;ndash;22 181, 1999. </mixed-citation>
</ref>
<ref id="ref74">
<label>74</label><mixed-citation publication-type="other" xlink:type="simple"> Ponater, M., Marquart, S., and Sausen, R.: Contrails in a comprehensive global climate model: parameterisation and radiative forcing results, J. Geophys. Res., 107, 4164, doi:10.1029/2001JD000429, 2002. </mixed-citation>
</ref>
<ref id="ref75">
<label>75</label><mixed-citation publication-type="other" xlink:type="simple"> Pruppacher, H. R. and Klett, J. D.: Microphysics of Clouds and Precipitation, Kluwer Acad. Pub., Dordrecht, 976p., 1997. </mixed-citation>
</ref>
<ref id="ref76">
<label>76</label><mixed-citation publication-type="other" xlink:type="simple"> Pueschel, R. F., Blake, D. F., Snetsinger, K. G., Hansen, A. D. A., Verma, S., and Kato, K.: Black carbon (soot) aerosol in the lower stratosphere and upper troposphere, Geophys. Res. Lett., 19, 1659&amp;ndash;1662, 1992. </mixed-citation>
</ref>
<ref id="ref77">
<label>77</label><mixed-citation publication-type="other" xlink:type="simple"> Rahmes, T. F., Omar, A. H., and Wuebbles, D. J.: Atmospheric distributions of soot particles by current and future aircraft fleets and resulting radiative forcing of climate, J. Geophys. Res., 103, 31 657&amp;ndash;31 667, 1998. </mixed-citation>
</ref>
<ref id="ref78">
<label>78</label><mixed-citation publication-type="other" xlink:type="simple"> Richardson, M. S., DeMott, P. J., Kreidenweis, S. M., Cziczo, D. J., Dunlea, E. J., Jimenez, J. L., Thomson, D. S., Ashbaugh, L. L., Borys, R. D., Westphal, D. L., Casuccio, G. S., and Lersch, T. L.: Measurements of heterogeneous ice nuclei in the western United States in springtime and their relation to aerosol characteristics, J. Geophys. Res., 112, D02209, doi:10.1029/2006JD007500, 2007. </mixed-citation>
</ref>
<ref id="ref79">
<label>79</label><mixed-citation publication-type="other" xlink:type="simple"> Roeckner, E., Stier, P., Feichter, J., Kloster, S., Esch, M., and Fischer-Bruns, I.: Impact of carbonaceous aerosol emissions on regional climate change, Clim. Dyn., 27, 553&amp;ndash;571, 2006. </mixed-citation>
</ref>
<ref id="ref80">
<label>80</label><mixed-citation publication-type="other" xlink:type="simple"> Rogers, D. C., DeMott, P. J., and Kreidenweis, S. M.: Measurements of ice nucleating aerosols during SUCCESS, Geophys. Res. Lett., 25, 1383&amp;ndash;1386, 1998. </mixed-citation>
</ref>
<ref id="ref81">
<label>81</label><mixed-citation publication-type="other" xlink:type="simple"> Sassen, K., DeMott, P. J., Prospero, J. M., and Poellot, M. R.: Saharan dust storms and indirect aerosol effects on clouds: CRYSTAL-FACE results, Geophys. Res. Lett., 30, 1633, doi:10.1029/2003GL017371, 2003. </mixed-citation>
</ref>
<ref id="ref82">
<label>82</label><mixed-citation publication-type="other" xlink:type="simple"> Sastry, S.: Ins and outs of ice nucleation, Nature, 438, 746&amp;ndash;747, 2005. </mixed-citation>
</ref>
<ref id="ref83">
<label>83</label><mixed-citation publication-type="other" xlink:type="simple"> Sausen, R., Isaksen, I., Grewe, V., Hauglustaine, D., Lee, D. S., Myhre, G., Köhler, M. O., Pitari, G., Schumann, U., Stordal, F., and Zerefos, C.: Aviation radiative forcing in 2000: An update of IPCC (1999), Meteorol. Z., 14, 555&amp;ndash;561, 2005. </mixed-citation>
</ref>
<ref id="ref84">
<label>84</label><mixed-citation publication-type="other" xlink:type="simple"> Schnaiter, M., Linke, C., Möhler, O., Naumann, K.-H., Saathoff, H., Wagner, R., Schurath, U., and Wehner, B.: Absorption amplification of black carbon internally mixed with secondary organic aerosol, J. Geophys. Res., 110, D19204, doi:10.1029/2005JD006046, 2005. </mixed-citation>
</ref>
<ref id="ref85">
<label>85</label><mixed-citation publication-type="other" xlink:type="simple"> Schröder, F., Brock, C. A., Baumann, R., Petzold, A., Busen, R. Schulte, P., and Fiebig, M.: In situ studies on volatile jet exhaust particle emissions: Impact of fuel sulfur content and environmental conditions on nuclei mode aerosols, J. Geophys. Res., 105, 19 941&amp;ndash;19 954, 2000. </mixed-citation>
</ref>
<ref id="ref86">
<label>86</label><mixed-citation publication-type="other" xlink:type="simple"> Schröder, F. P., Kärcher, B., Fiebig, M., and Petzold, A.: Aerosol states in the free troposphere at northern midlatitudes, J. Geophys. Res., 107, 8126, doi:10.1029/2000JD000194, 2002. </mixed-citation>
</ref>
<ref id="ref87">
<label>87</label><mixed-citation publication-type="other" xlink:type="simple"> Schumann, U.: Formation, properties and climatic effects of contrails, C. R. Physique, 6, 549&amp;ndash;565, 2005. </mixed-citation>
</ref>
<ref id="ref88">
<label>88</label><mixed-citation publication-type="other" xlink:type="simple"> Schumann U., Schlager, H., Arnold, F., Baumann, R., Haschberger, P., and Klemm, O.: Dilution of aircraft exhaust plumes at cruise altitudes, Atmos. Environ., 32, 3097&amp;ndash;3103, 1998. </mixed-citation>
</ref>
<ref id="ref89">
<label>89</label><mixed-citation publication-type="other" xlink:type="simple"> Schumann U., Arnold, F., Busen, R., Curtius, J., Kärcher, B., Kiendler, A., Petzold, A., Schlager, H., Schröder, F., and Wohlfrom, K.-H.: Influence of fuel sulfur on the composition of aircraft exhaust plumes: The experiments SULFUR 1&amp;ndash;7, J. Geophys. Res., 107, doi:10.1029/2001JD000813, 2002. </mixed-citation>
</ref>
<ref id="ref90">
<label>90</label><mixed-citation publication-type="other" xlink:type="simple"> Schwarz, J. P., Gao, R. S., Fahey, D. W., Thomson, D. S., Watts, L. A., Wilson, J. C., Reeves, J. M., Baumgardner, D. G., Kok, G. L., Chung, S., Schulz, M., Hendricks, J., Lauer, A., Kärcher, B., Slowik, J. G., Rosenlof, K. H., Thompson, T. L., Langford, A. O., Lowenstein, M., and Aikin, K. C.: Single-particle measurements of midlatitude black carbon and light-scattering aerosols from the boundary layer to the lower stratosphere, J. Geophys. Res., 111, D16207, doi:10.1029/2006JD007076, 2006. </mixed-citation>
</ref>
<ref id="ref91">
<label>91</label><mixed-citation publication-type="other" xlink:type="simple"> Shilling, J. E., Fortin, T. J., and Tolbert, M. A.: Depositional ice nucleation on crystalline organic and inorganic solids, J. Geophys. Res., 111, D12204, doi:10.1029/2005JD006664, 2006. </mixed-citation>
</ref>
<ref id="ref92">
<label>92</label><mixed-citation publication-type="other" xlink:type="simple"> Stockwell, W. R. and Calvert, J. G.: The mechanism of the \chemHO-SO_2 reaction, Atmos. Environ., 17, 2231&amp;ndash;2235, 1983. </mixed-citation>
</ref>
<ref id="ref93">
<label>93</label><mixed-citation publication-type="other" xlink:type="simple"> Strawa, A. W., Drdla, K., Ferry, G. V., Verma, S., Pueschel, R. F., Yasuda, M., Salawitch, R. J., Gao, R. S., Howard, D. D., Bui, P. T., Loewenstein, M., Elkins, J. W., Perkins, K. K., and Cohen, R.: Carbonaceous aerosol (soot) measured in the lower stratosphere during POLARIS and its role in stratospheric photochemistry, J. Geophys. Res., 104, 26 753&amp;ndash;26 766, 1999. </mixed-citation>
</ref>
<ref id="ref94">
<label>94</label><mixed-citation publication-type="other" xlink:type="simple"> Ström, J. and Ohlsson, S.: In-situ measurements of enhanced crystal number densities in cirrus clouds caused by aircraft exhaust, J. Geophys. Res., 103, 11 355&amp;ndash;11 361, 1998. </mixed-citation>
</ref>
<ref id="ref95">
<label>95</label><mixed-citation publication-type="other" xlink:type="simple"> Stuber, N., Forster, P., Rädel, G., and Shine, K.: The importance of the diurnal and annual cycle of air traffic for contrail radiative forcing, Nature, 441, 864&amp;ndash;867, 2006. </mixed-citation>
</ref>
<ref id="ref96">
<label>96</label><mixed-citation publication-type="other" xlink:type="simple"> Suzanne, J., Ferry, D., Popovitcheva, O., and Shonija, N. K.: Ice nucleation by kerosene soot under upper tropospheric conditions, Canad. J. Phys., 81, 423&amp;ndash;429, 2003. </mixed-citation>
</ref>
<ref id="ref97">
<label>97</label><mixed-citation publication-type="other" xlink:type="simple"> Twohy, C. H. and Poellot, M. R.: Chemical characteristics of ice residual nuclei in anvil cirrus clouds: Evidence for homogeneous and heterogeneous ice formation, Atmos. Chem. Phys., 5, 2289&amp;ndash;2297, 2005. </mixed-citation>
</ref>
<ref id="ref98">
<label>98</label><mixed-citation publication-type="other" xlink:type="simple"> Wuebbles, D., Gupta, M., and Ko, M.: Evaluating the impacts of aviation on climate change, EOS Transactions, 88, 157&amp;ndash;160, Full workshop report available from http://www.faa.gov, 2007. </mixed-citation>
</ref>
<ref id="ref99">
<label>99</label><mixed-citation publication-type="other" xlink:type="simple"> Yu, F. and Turco, R. P.: The formation and evolution of aerosols in stratospheric aircraft plumes: Numerical simulations and comparisons with observations, J. Geophys. Res., 103, 25 915&amp;ndash;25 934, 1998. </mixed-citation>
</ref>
<ref id="ref100">
<label>100</label><mixed-citation publication-type="other" xlink:type="simple"> Yu, F., Turco, R. P., and Kärcher, B.: The possible role of organics in the formation and evolution of ultrafine aircraft particles, J. Geophys. Res., 104, 4079&amp;ndash;4087, 1999. </mixed-citation>
</ref>
<ref id="ref101">
<label>101</label><mixed-citation publication-type="other" xlink:type="simple"> Zobrist, B., Marcolli, C., Koop, T., Luo, B. P., Murphy, D. M., Lohmann, U., Zardini, A. A., Krieger, U. K., Corti, T., Cziczo, D. J., Fueglistaler, S., Hudson, P. K., Thomson, D. S., and Peter, Th.: Oxalic acid as a heterogeneous ice nucleus in the upper troposphere and its indirect aerosol effect, Atmos. Chem. Phys., 6, 3115&amp;ndash;3129, 2006. </mixed-citation>
</ref>
<ref id="ref102">
<label>102</label><mixed-citation publication-type="other" xlink:type="simple"> Zuberi, B., Bertram, A. K., Koop, T., Molina, L. T., and Molina, M. J.: Heterogeneous nucleation of aqueous particles induced by crystallized (NH&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;-H&lt;sub&gt;2&lt;/sub&gt;O, ice and letovicite, J. Phys. Chem., A 105, 6458&amp;ndash;6464, 2001. </mixed-citation>
</ref>
<ref id="ref103">
<label>103</label><mixed-citation publication-type="other" xlink:type="simple"> Zuberi, B., Bertram, A. K., Cassa, C. A., Molina, L. T., and Molina, M. J.: Heterogeneous nucleation of ice in (NH&lt;sub&gt;4&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;SO&lt;sub&gt;4&lt;/sub&gt;-H&lt;sub&gt;2&lt;/sub&gt;O particles with mineral dust immersions, Geophys. Res. Lett., 29, 1504, doi:10.1029/2001GL014289, 2002. </mixed-citation>
</ref>
</ref-list>
</back>
</article>