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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-7-1851-2007</article-id>
<title-group>
<article-title>Mesoscale circulations over complex terrain in the Valencia coastal region,  Spain &amp;ndash; Part 2: Modeling CO&lt;sub&gt;2&lt;/sub&gt; transport using idealized surface fluxes</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pérez-Landa</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ciais</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gangoiti</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Palau</surname>
<given-names>J. L.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Carrara</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gioli</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Miglietta</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schumacher</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Millán</surname>
<given-names>M. M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sanz</surname>
<given-names>M. J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Fundación CEAM. Parque Tecnológico, c/ Charles R. Darwin 14, 46980 Paterna (Valencia), Spain</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Laboratoire des Sciences du Climat et de l&apos;Environnement, UMR Commissariat à l&apos;Energie Atomique/CNRS 1572, Gif-sur-Yvette, France</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Escuela Técnica Superior de Ingenieros Industriales de Bilbao, Universidad del País Vasco/Euskal Herriko Unibertsitatea, Bilbao, Spain</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>IBIMET-CNR, Instituto di Biometeorologia, Consiglio Nazionale delle Ricerche, Firenze, Italy</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Max-Planck-Institut für Biogeochemie, Hans-Knöll-Strasse 10, 07745 Jena, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>16</day>
<month>04</month>
<year>2007</year>
</pub-date>
<volume>7</volume>
<issue>7</issue>
<fpage>1851</fpage>
<lpage>1868</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<abstract>
<p>Vertical profiles of CO&lt;sub&gt;2&lt;/sub&gt; concentration were collected during an
intensive summer campaign in a coastal complex-terrain region within the
frame of the European Project RECAB (Regional Assessment and Modelling of
the Carbon Balance in Europe). The region presents marked diurnal mesoscale
circulation patterns. These circulations result in a specific coupling
between atmospherically transported CO&lt;sub&gt;2&lt;/sub&gt; and its surface fluxes. To
understand the effects of this interaction on the spatial variability of the
observed CO&lt;sub&gt;2&lt;/sub&gt; concentrations, we applied a high-resolution transport
simulation to an idealized model of land biotic fluxes. The regional Net
Ecosystem Exchange fluxes were extrapolated for different land-use classes
by using a set of eddy-covariance measurements. The atmospheric transport
model is a Lagrangian particle dispersion model, driven by a simulation of
the RAMS mesoscale model. Our simulations were able to successfully
reproduce some of the processes controlling the mesoscale transport of
CO&lt;sub&gt;2&lt;/sub&gt;. A semi-quantitative comparison between simulations and data
allowed us to characterize how the coupling between mesoscale transport and
surface fluxes produced CO&lt;sub&gt;2&lt;/sub&gt; spatial gradients in the domain. Temporal
averages in the simulated CO&lt;sub&gt;2&lt;/sub&gt; field show a covariance between flux and
transport consisting of: 1) horizontally, a CO&lt;sub&gt;2&lt;/sub&gt; deficit over land,
mirrored by a CO&lt;sub&gt;2&lt;/sub&gt; excess over the sea and 2) vertically, the prevalence
of a mean CO&lt;sub&gt;2&lt;/sub&gt; depletion between 500 and 2000 m, and a permanent
build-up of CO&lt;sub&gt;2&lt;/sub&gt; in the lower levels.</p>
</abstract>
<counts><page-count count="18"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Aubinet, M., Grelle, A., Ibrom, A., Rannik, U., Moncrieff, J., Foken, T., Kowalski, A. S., Martin, P. H., Berbigier, P., Bernhofer, C., Clement, R., Elbers, J., Granier, A., Grunwald, T., Morgenstern, K., Pilegaard, K., Rebmann, C., Snijders, W., Valentini, R., and Vesala, T.: Estimates of the annual net carbon and water exchange of European forests: the EUROFLUX methodology, Adv. Ecol. Res., 30, 113&amp;ndash;175, 2000. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Bousquet, P., Peylin, P., Ciais, P., LeQuere, C., Friedlingstein, P., and Tans, P.: Regional Changes in Carbon Dioxide Fluxes of Land and Oceans Since 1980, Science, 290, 1342&amp;ndash;1346, 2000. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Caplan, P., Derber, J., Gemmill, W., Hong, S. Y., Pan, H. L., and Parish, D.: Changes to the NCEP operational medium-range forecast model analysis/forecast system, Wea. Forecasting, 12, 581&amp;ndash;594, 1997. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> CEC (Commission of the European Communities): CORINE Land cover, Guide Technique, Brussels, available online: http://reports.eea.eu.int/COR0-landcover/en, 1995. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Chevillard, A., Karstens, U., Ciais, P., Lafont, S., and Heimann, M.: Simulation of atmospheric CO&lt;sub&gt;2&lt;/sub&gt; over Europe and Siberia using the regional scale model REMO, Tellus, 54B, 872&amp;ndash;894, 2002. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Ciais, P., Tans, P. P., Trolier, M., White, J. W. C., and Francey, R. J.: A large northern hemisphere terrestrial CO&lt;sub&gt;2&lt;/sub&gt; sink indicated by the 13C/12C ratio of atmospheric CO&lt;sub&gt;2&lt;/sub&gt;, Science, 269, 1098&amp;ndash;1102, 1995. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Crawford, T. L. and Dobosy, R. J.: A sensitive fast response probe to measure turbulence and heat flux from any airplane. Bound.-Layer Meteorol., 59, 257&amp;ndash;278, 1992. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> De Wekker, S. F. J., Steyn, D. G., and Nyeki, S.: A comparison of aerosol layer- and convective boundary layer structure over a mountain range during STAAARTE &apos;97, Bound.-Layer Meteorol., 113, 249&amp;ndash;271, 2004. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Denning, A. S., Collatz, J. G., Zhang, C., Randall, D. A., Berry, J. A., Sellers, P. J., Colello, G. D., and Dazlich, D. A.: Simulations of terrestrial carbon metabolism and atmospheric CO&lt;sub&gt;2&lt;/sub&gt; in a general circulation model, Part 1: Surface carbon fluxes, Tellus, 48B, 521&amp;ndash;542, 1996. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Denning, S.: Investigations of the transport, sources and sinks of atmospheric CO&lt;sub&gt;2&lt;/sub&gt; using a general circulation model, PhD Thesis, Colorado State University, 1994. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Falge, E., Baldocchi, D. D., Olson, R. J., Anthoni, P., Aubinet, M., Bernhofer, C., Burba, G., Ceulemans, R., Dolman, H., Granier, A., Gross, P., Grünwald, T., Hollinger, D., Jensen, N. O., Katul, G., Keronen, P., Kowalski, A. S., Ta Lai, C., Law, B. E., Meyers, T., Moncrieff, J., Moors, E., Munger, J. W., Pilegaard, K., Rannik, U., Rebmann, C., Suyker, A., Tenhunen, J., Tu, K., Verma, S., Vesala, T., Wilson, K., and Wofsy, S.: Gap filling strategies for defensible annual sums of net ecosystem exchange, Agric. For. Meteorol., 107, 43&amp;ndash;69, 2001. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Fan, S., Gloor, M., Mahlman, J., Pacala, S., Sarmiento, J., Takahashi, T., and Tans, P.: A large terrestrial carbon sink in North America implied by atmospheric and oceanic carbon dioxide data and models, Science, 282, 442&amp;ndash;446, 1998. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> FAO: World reference base for soil resources, Food and Agriculture Organization of the United Nations, Rome, available online at http://www.itc.nl/~rossiter/Docs/WRB/wsrr84e.pdf, 1998. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Gangoiti, G., Alonso, L., Navazo, M., Albizuri, A., Pérez-Landa, G., Matabuena, M., Valdenebro, V., Maruri, M., García J. A., and Millán M. M.: Regional transport of pollutants over the Bay of Biscay: analysis of an ozone episode under a blocking anticyclone in west-central Europe, Atmos. Environ., 36(8) 1349&amp;ndash;1361, 2002. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Gangoiti, G., Millán, M. M., Salvador, R., and Mantilla E.: Long-range transport and re-circulation of pollutants in the western Mediterranean, during the project Regional Cycles of Air Pollution in the West-Central Mediterranean Area, Atmos. Environ., 35, 6267&amp;ndash;6276, 2001. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Gerbig, C., Lin, J. C., Wofsy, S. C., Daube, B. C., Andrews, A. E., Stephens, B. B., Bakwin, P. S.,and Grainger, C. A.: Towards constraining regional-scale fluxes of CO&lt;sub&gt;2&lt;/sub&gt; with atmospheric observations over a continent: 2. Analysis of COBRA data using a receptor-oriented framework, J. Geophys. Res., 108, 4757, doi:10.1029/2003JD003770, 2003. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Gioli B., Miglietta, F., De Martino, B., Hutjes, R. W. A., Dolman, H. A. J., Lindroth, A., Schumacher, M., Sanz, M. J., Manca, G., Peressotti, A., and Dumas, E. J.: Comparison between tower and aircraft-based eddy covariance fluxes in five European regions, Agric. For. Meteorol., 127, 1&amp;ndash;16, 2004. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Gurney, K. R., Law, R. M., Denning, A. S., Rayner, P. J., Baker, D., Bousquet, P., Bruhwiler, L., Chen, Y.-H., Ciais, P., Fan, S., Fung, I. Y., Gloor, M., Heimann, M., Higuchi, K., John, J., Maki, T., Maksyutov, S., Masarie, K., Peylin, P., Prather, M., Pak, B. C., Randerson, J., Sarmiento, J., Taguchi, S., Takahashi, T., and Yuen, C.-W: Towards robust regional estimates of CO&lt;sub&gt;2&lt;/sub&gt; sources and sinks using atmospheric transport models, Nature, 415, 626&amp;ndash;630, 2002. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> Hutjes, R., van den Bulk, W. C. M., Cosin, S., et al.: Regional Assessment and monitoring of the carbon balance within Europe (RECAB), Final Report. Alterra, PO Box 47, 6700 AC, Wageningen. Netherlands, 2003. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Kotroni, V., Kallos, G., Lagouvardos, K., Varinou M., and Walko, R.: Numerical Simulations of the Meteorological and Dispersion Conditions during an Air Pollution Episode over Athens, Greece, J. Appl. Meteorol., 38(4), 432&amp;ndash;447, 1999. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Lin, J. C., Gerbig, C., Daube, B. C., Wofsy, S. C., Andrews, A. E., Vay, S. A., and Anderson, B. E.: An Empirical Analysis of the Spatial Variability of Atmospheric CO&lt;sub&gt;2&lt;/sub&gt;: Implications for Inverse Analyses and Space-borne Sensors, Geophys. Res. Lett., 31, L23104, doi:10.1029/2004GL020957, 2004. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Lu, L., Denning, A. S., da Silva-Dias, M. A., da Silva-Dias, P., Longo, M., Freitas, S. R., and Saatchi, S.: Mesoscale circulations and atmospheric CO&lt;sub&gt;2&lt;/sub&gt; variations in the Tapajós Region, Pará, Brazil, J. Geophys. Res., 110, D21102, doi:10.1029/2004JD005757, 2005. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Marland, G., Boden, T. A., and Andres, R. J.: Global, regional, and national CO&lt;sub&gt;2&lt;/sub&gt; emissions in trends: A compendium of data on global change, Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory, U.S. Department of Energy, Oak Ridge, Tenn., USA, 2003. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Michaelis, L. and Menten, M. L.: Die Kinetik der Invertinwirkung, Biochemische Zeitschrift, 49, 333&amp;ndash;369, 1913. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Millán, M. M., Salvador, R., Mantilla, E., and Kallos, G.: Photooxidants dynamics in the Mediterranean basin in summer: Results from European research projects, J. Geophys. Res., 102(D7), 8811&amp;ndash;8823, 1997. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Millán, M. M., Arti&amp;ntilde;ano, B., Alonso, L., Castro, M., Fernandez-Patier, R., and Goberna, J.: Meso-Meteorological Cycles of Air Pollution in the Iberian Peninsula, (MECAPIP), Air Pollution Research Report 44, EUR No 14834, European Commission DG XII/E-1, Rue de la Loi, 200, B-1040, Brussels, 1992. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Nicholls, M. E., Denning, A. S., Prihodko, L., Vidale, P. L., Davis, K., and Bakwin, P.: A multiple-scale simulation of variations in atmospheric carbon dioxide using a coupled biosphere-atmospheric model,. J. Geophys. Res., 109, D18117, doi:10.1029/2003JD004482, 2004. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> Olivier, J. G. J. and Berdowski, J. J. M.: Global emissions sources and sinks, in: The Climate System, edited by: Berdowski, J., Guicherit, R., and Heij, B. J., A A Balkema Publishers/Swets &amp; Zeitlinger Publishers, Lisse, The Netherlands, ISBN~90-5809-255-0, 33&amp;ndash;78, 2001. </mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple"> Palau, J. L., Pérez-Landa, G., Diéguez, J. J., Monter, C., and Millán, M. M.: The importance of meteorological scales to forecast air pollution scenarios on coastal complex terrain, Atmos. Chem. Phys., 5, 2771&amp;ndash;2785, 2005. </mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple"> Pérez-Landa, G., Ciais, P., Sanz, M. J., Gioli, B., Miglietta, F., Palau, J. L., Gangoiti, G., and Millán, M. M.: Mesoscale circulations over complex terrain in the Valencia coastal region, Spain &amp;ndash; Part 1: Simulation of diurnal circulation regimes, Atmos. Chem. Phys., 7, 1835&amp;ndash;1849, 2007. </mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple"> Rayner, P. J., Enting, I. G., Francey, R. J., and Langenfelds, R.: Reconstructing the recent carbon cycle from atmospheric CO&lt;sub&gt;2&lt;/sub&gt;, $\delta ^13$C, and O&lt;sub&gt;2&lt;/sub&gt;/N&lt;sub&gt;2&lt;/sub&gt; observations, Tellus, 51B, 213&amp;ndash;232, 1999.  </mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple"> Schumacher, M.: Airborne and ground level flask sampling for regional carbon budgets the potential of multiple tracer and isotope analyses, PhD. thesis, University Hamburg, http://www.sub.uni-hamburg.de/opus/volltexte/2005/2576/, 2005. </mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple"> Seufert, G., Sanz, M., and Millán, M. M.: Report on the 3rd BEMA measuring campaign at Burriana (Valencia&amp;ndash;Spain) July 12&amp;ndash;23, 1995, Joint Research Centre Rep. EUR 17305 EN (Available from Office of Official Publications of the European Communities, L-2985, Luxemburg), 140, 1997. </mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple"> Tremback, C. J., Lyons, W. A., Thorson, W. P., and Walko, R. L.: An emergency response and local weather forecasting software system, Preprints, Eighth Joint Conf. on the Applications of Air Pollution, Nashville, TN, Amer. Meteorol. Soc., 219&amp;ndash;233, 1994. </mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple"> Walko, R. L., Tremback, C. J., and Bell, M. J.: HYPACT Hybrid Particle and Concentration Transport Model, Users Guide, Mission Research Corporation, Fort Collins, Colorado (USA), 2001. </mixed-citation>
</ref>
</ref-list>
</back>
</article>