ACP Atmospheric Chemistry and Physics ACP 1680-7324 Copernicus GmbH Göttingen, Germany 10.5194/acp-6-93-2006 Intercomparison exercise between different radiative transfer models used for the interpretation of ground-based zenith-sky and multi-axis DOAS observations Hendrick F. 1 Van Roozendael M. 1 Kylling A. 2 7 Petritoli A. 3 Rozanov A. 4 Sanghavi S. 5 Schofield R. 6 8 von Friedeburg C. 5 Wagner T. 5 Wittrock F. 4 Fonteyn D. 1 De Mazière M. 1 Institut d’Aéronomie Spatiale de Belgique, Brussels, Belgium Norwegian Institute for Air Research, Kjeller, Norway Institute of Atmospheric Science and Climate, Bologna, Italy Institute of Environmental Physics, University of Bremen, Bremen, Germany Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany National Institute of Water and Atmospheric Research, Omakau, Central Otago, New Zealand now at: St. Olavs University Hospital, Trondheim, Norway now at: NOAA Aeronomy Laboratory, Boulder, Colorado, USA 20 01 2006 6 1 93 108 This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. This article is available from http://www.atmos-chem-phys.net/6/93/2006/acp-6-93-2006.html The full text article is available as a PDF file from http://www.atmos-chem-phys.net/6/93/2006/acp-6-93-2006.pdf

We present the results of an intercomparison exercise between six different radiative transfer (RT) models carried out in the framework of QUILT, an EU funded project based on the exploitation of the Network for the Detection of Stratospheric Change (NDSC). RT modelling is an important step in the interpretation of Differential Optical Absorption Spectroscopy (DOAS) observations. It allows the conversion of slant column densities (SCDs) into vertical column densities (VCDs) using calculated air mass factors (AMFs). The originality of our study resides in comparing SCD simulations in multi-axis (MAX) geometry (trace gases: NO<sub>2</sub> and HCHO) and in taking into account photochemical enhancement for calculating SCDs of rapidly photolysing species (BrO, NO<sub>2</sub>, and OClO) in zenith-sky geometry. Concerning the zenith-sky simulations, the different models agree generally well, especially below 90&deg; SZA. At higher SZA, larger discrepancies are obtained with relative differences ranging between 2% and 14% in some cases. In MAX geometry, good agreement is found between the models with the calculated NO<sub>2</sub> and HCHO SCDs differing by no more than 5% in the elevation and solar zenith angle (SZA) ranges investigated (5&deg;&ndash;20&deg; and 35&deg;&ndash;85&deg;, respectively). The impacts of aerosol scattering, ground albedo, and relative azimuth on MAX simulations have also been tested. Significant discrepancies appear for the aerosol effect, suggesting differences between models in the treatment of aerosol scattering. A better agreement is found in case of the ground albedo and relative azimuth effects. The complete set of initialization data and results have been made publicly available through the QUILT project web site (<TT><A NAME="tex2html1" HREF="http://nadir.nilu.no/quilt/">http://nadir.nilu.no/quilt/</A></TT>), enabling the testing of other RT codes designed for the calculation of SCDs/AMFs.