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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-6-447-2006</article-id>
<title-group>
<article-title>Dry and wet deposition of inorganic nitrogen compounds to a tropical pasture site (Rondônia, Brazil)</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Trebs</surname>
<given-names>I.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lara</surname>
<given-names>L. L.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zeri</surname>
<given-names>L. M. M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gatti</surname>
<given-names>L. V.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Artaxo</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dlugi</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Slanina</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Andreae</surname>
<given-names>M. O.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Meixner</surname>
<given-names>F. X.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Max Planck Institute for Chemistry, Biogeochemistry Department, P.O. Box 3060, 55020, Mainz, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Centro de Energia Nuclear na Agricultura (CENA), Laboratorio de Ecologia Isotópica, Universidade de São Paulo (USP), Av. Centenario, 303 13400-970, Piracicaba, São Paulo, SP, Brazil</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Max Planck Institute for Biogeochemistry, Department Biogeochemical Processes, Hans-Knöll-Straße 10, 07745 Jena, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Instituto de Pesquisas Energéticas e Nucleares, CQMA, Atmospheric Chemistry Laboratory, Av. Prof. Lineu Prestes, 2242, Cidade Universitaria, CEP 055508-900, São Paulo, SP, Brazil</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Instituto de Física, Universidade de São Paulo (USP), Rua do Matão, Travessa R, 187, CEP 05508-900, São Paulo, SP, Brazil</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>Working Group Atmospheric Processes (WAP), Gernotstrasse 11, 80804 Munich, Germany</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>Peking University, College of Environmental Sciences, Beijing 100871, China</addr-line>
</aff>
<pub-date pub-type="epub">
<day>08</day>
<month>02</month>
<year>2006</year>
</pub-date>
<volume>6</volume>
<issue>2</issue>
<fpage>447</fpage>
<lpage>469</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/6/447/2006/acp-6-447-2006.html">This article is available from http://www.atmos-chem-phys.net/6/447/2006/acp-6-447-2006.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/6/447/2006/acp-6-447-2006.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/6/447/2006/acp-6-447-2006.pdf</self-uri>
<abstract>
<p>The input of nitrogen (N) to ecosystems has increased dramatically over the
past decades. While total (wet&amp;nbsp;+&amp;nbsp;dry) N deposition has been extensively
determined in temperate regions, only very few data sets of N wet deposition
exist for tropical ecosystems, and moreover, reliable experimental
information about N dry deposition in tropical environments is lacking. In
this study we estimate dry and wet deposition of inorganic N for a remote
pasture site in the Amazon Basin based on in-situ measurements. The
measurements covered the late dry (biomass burning) season, a transition
period and the onset of the wet season (clean conditions) (12 September to 14
November 2002) and were a part of the LBA-SMOCC (Large-Scale
Biosphere-Atmosphere Experiment in Amazonia &amp;ndash; Smoke, Aerosols, Clouds,
Rainfall, and Climate) 2002 campaign. Ammonia (NH&lt;sub&gt;3&lt;/sub&gt;), nitric acid
(HNO&lt;sub&gt;3&lt;/sub&gt;), nitrous acid (HONO), nitrogen dioxide (NO&lt;sub&gt;2&lt;/sub&gt;), nitric oxide
(NO), ozone (O&lt;sub&gt;3&lt;/sub&gt;), aerosol ammonium (NH&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;) and aerosol nitrate
(NO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;-&lt;/sup&gt;) were measured in real-time, accompanied by simultaneous
meteorological measurements. Dry deposition fluxes of NO&lt;sub&gt;2&lt;/sub&gt; and HNO&lt;sub&gt;3&lt;/sub&gt;
are inferred using the &apos;&apos;big leaf multiple resistance approach&apos;&apos; and
particle deposition fluxes are derived using an established empirical
parameterization. Bi-directional surface-atmosphere exchange fluxes of
NH&lt;sub&gt;3&lt;/sub&gt; and HONO are estimated by applying a &apos;&apos;canopy compensation point
model&apos;&apos;. N dry and wet deposition is dominated by NH&lt;sub&gt;3&lt;/sub&gt; and
NH&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;, which is largely the consequence of biomass burning during
the dry season. The grass surface appeared to have a strong potential for
daytime NH&lt;sub&gt;3&lt;/sub&gt; emission, owing to high canopy compensation points, which
are related to high surface temperatures and to direct NH&lt;sub&gt;3&lt;/sub&gt; emissions
from cattle excreta. NO&lt;sub&gt;2&lt;/sub&gt; also significantly accounted for N dry
deposition, whereas HNO&lt;sub&gt;3&lt;/sub&gt;, HONO and N-containing aerosol species were
only minor contributors. Ignoring NH&lt;sub&gt;3&lt;/sub&gt; emission from the vegetation
surface, the annual net N deposition rate is estimated to be about &amp;minus;11 kgN
ha&lt;sup&gt;-1&lt;/sup&gt; yr&lt;sup&gt;-1&lt;/sup&gt;. If on the other hand, surface-atmosphere exchange of
NH&lt;sub&gt;3&lt;/sub&gt; is considered to be bi-directional, the annual net N budget at the
pasture site is estimated to range from &amp;minus;2.15 to &amp;minus;4.25 kgN ha&lt;sup&gt;-1&lt;/sup&gt; yr&lt;sup&gt;-1&lt;/sup&gt;.</p>
</abstract>
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