Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 6 12 2006 10.5194/acp-6-4287-2006 http://www.atmos-chem-phys.net/6/4287/2006/ http://www.atmos-chem-phys.net/6/4287/2006/acp-6-4287-2006.html http://www.atmos-chem-phys.net/6/4287/2006/acp-6-4287-2006.pdf 4287 4309 2006-09-25 The sensitivity of aerosol in Europe to two different emission inventories and temporal distribution of emissions A. de Meij alexander.de-meij@jrc.it M. Krol F. Dentener E. Vignati C. Cuvelier P. Thunis Institute for Environment and Sustainability, Joint Research Centre, European Commission, Ispra, Italy now at: SRON, Utrecht, the Netherlands, and Wageningen University, The Netherlands The sensitivity to two different emission inventories, injection altitude and temporal variations of anthropogenic emissions in aerosol modelling is studied, using the two way nested global transport chemistry model TM5 focussing on Europe in June and December 2000. The simulations of gas and aerosol concentrations and aerosol optical depth (AOD) with the EMEP and AEROCOM emission inventories are compared with EMEP gas and aerosol surface based measurements, AERONET sun photometers retrievals and MODIS satellite data. For the aerosol precursor gases SO2 and NOx in both months the model results calculated with the EMEP inventory agree better (overestimated by a factor 1.3 for both SO2 and NOx) with the EMEP measurements than the simulation with the AEROCOM inventory (overestimated by a factor 2.4 and 1.9, respectively). Besides the differences in total emissions between the two inventories, an important role is also played by the vertical distribution of SO2 and NOx emissions in understanding the differences between the EMEP and AEROCOM inventories. In December NOx and SO2 from both simulations agree within 50% with observations. In June SO4= evaluated with the EMEP emission inventory agrees slightly better with surface observations than the AEROCOM simulation, whereas in December the use of both inventories results in an underestimate of SO4 with a factor 2. Nitrate aerosol measured in summer is not reliable, however in December nitrate aerosol calculations with the EMEP and AEROCOM emissions agree with 30%, and 60%, respectively with the filter measurements. Differences are caused by the total emissions and the temporal distribution of the aerosol precursor gases NOx and NH3. Despite these differences, we show that the column integrated AOD is less sensitive to the underlying emission inventories. Calculated AOD values with both emission inventories underestimate the observed AERONET AOD values by 20–30%, whereas a case study using MODIS data shows a high spatial agreement. 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