Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 6 9 2006 10.5194/acp-6-2695-2006 http://www.atmos-chem-phys.net/6/2695/2006/ http://www.atmos-chem-phys.net/6/2695/2006/acp-6-2695-2006.html http://www.atmos-chem-phys.net/6/2695/2006/acp-6-2695-2006.pdf 2695 2709 2006-07-06 Ozone observations by the Gas and Aerosol Measurement Sensor during SOLVE II M. C. Pitts michael.c.pitts@nasa.gov L. W. Thomason J. M. Zawodny B. N. Wenny J. M. Livingston P. B. Russell J.-H. Yee W. H. Swartz R. E. Shetter NASA Langley Research Center, Hampton, Virginia, USA Science Applications International Corporation, Hampton, Virginia, USA SRI International, Menlo Park, California, USA NASA Ames Research Center, Moffett Field, California, USA The Johns Hopkins University Applied Physics Laboratory, Laurel, Maryland, USA National Center for Atmospheric Research, Boulder, Colorado, USA The Gas and Aerosol Measurement Sensor (GAMS) was deployed aboard the NASA DC-8 aircraft during the second SAGE III Ozone Loss and Validation Experiment (SOLVE II). GAMS acquired line-of-sight (LOS) direct solar irradiance spectra during the sunlit portions of ten science flights of the DC-8 between 12 January and 4 February 2003. Differential line-of-sight (DLOS) optical depth spectra are produced from the GAMS raw solar irradiance spectra. Then, DLOS ozone number densities are retrieved from the GAMS spectra using a multiple linear regression spectral fitting technique. Both the DLOS optical depth spectra and retrieved ozone data are compared with coincident measurements from two other solar instruments aboard the DC-8 platform to demonstrate the robustness and stability of the GAMS data. The GAMS ozone measurements are then utilized to evaluate the quality of the Wulf band ozone cross sections, a critical component of the SAGE III aerosol, water vapor, and temperature/pressure retrievals. Results suggest the ozone cross section compilation of Shettle and Anderson currently used operationally in SAGE III data processing may be in error by as much as 10–20% in the Wulf bands, and their lack of reported temperature dependence is a significant deficiency. A second, more recent, cross section database compiled for the SCIAMACHY satellite mission appears to be of much better quality in the Wulf bands, but still may have errors as large as 5% near the Wulf band absorption peaks, which is slightly larger than their stated uncertainty. 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