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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-989-2005</article-id>
<title-group>
<article-title>Temperature and light dependence of the VOC emissions of Scots pine</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tarvainen</surname>
<given-names>V.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hakola</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hellén</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bäck</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hari</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kulmala</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Finnish Meteorological Institute, Sahaajankatu 20 E, FI-00880 Helsinki, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Forest Ecology, University of Helsinki, Helsinki, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Physical Sciences, University of Helsinki, Helsinki, Finland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>22</day>
<month>03</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>4</issue>
<fpage>989</fpage>
<lpage>998</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/989/2005/acp-5-989-2005.html">This article is available from http://www.atmos-chem-phys.net/5/989/2005/acp-5-989-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/989/2005/acp-5-989-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/989/2005/acp-5-989-2005.pdf</self-uri>
<abstract>
<p>The volatile organic compound (VOC) emission rates of Scots pine

(&lt;I&gt;Pinus sylvestris&lt;/I&gt;&amp;nbsp;L.) were measured from trees growing in a

natural forest environment at two locations in Finland. The observed

total VOC emission rates varied between 21 and

874 ngg&lt;sup&gt;-1&lt;/sup&gt; h&lt;sup&gt;-1&lt;/sup&gt; and 268 and

1670 ngg&lt;sup&gt;-1&lt;/sup&gt; h&lt;sup&gt;-1&lt;/sup&gt; in southern and northern Finland,

respectively. A clear seasonal cycle was detected with high emission

rates in early spring, a decrease of the emissions in late spring

and early summer, high emissions again in late summer, and a gradual

decrease in autumn.



&lt;P  style=&quot;line-height: 20px;&quot;&gt;

The main emitted compounds were &amp;Delta;&lt;sup&gt;3&lt;/sup&gt;-carene (southern Finland)

and &amp;alpha;- and &amp;beta;-pinene (northern Finland), with approximate

relative contributions of 60&amp;ndash;70% and 60&amp;ndash;85% of the total observed

monoterpene emission rates, respectively. Sesquiterpene (&amp;beta;-caryophyllene) and 2-methyl-3-buten-2-ol (MBO) emissions were initiated in

early summer at both sites. The observed MBO emission rates were between 1

and 3.5% of the total monoterpene emission rates. The sesquiterpene

emission rates varied between 2 and 5% of the total monoterpene emission

rates in southern Finland, but were high (40%) in northern Finland in

spring.



&lt;P  style=&quot;line-height: 20px;&quot;&gt;

Most of the measured emission rates were found to be well described

by the temperature dependent emission algorithm. The calculated

standard emission potentials were high in spring and early summer,

decreased somewhat in late summer, and were high again towards

autumn. The experimental coefficient &amp;beta; ranged from 0.025 to

0.19 (average 0.10) in southern Finland, with strongest temperature

dependence in spring and weakest in late summer. Only the emission

rates of 1,8-cineole were found to be both light and temperature

dependent.</p>
</abstract>
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