Atmospheric Chemistry and Physics www.atmos-chem-phys.net 1680-7316 1680-7324 5 4 2005 10.5194/acp-5-919-2005 http://www.atmos-chem-phys.net/5/919/2005/ http://www.atmos-chem-phys.net/5/919/2005/acp-5-919-2005.html http://www.atmos-chem-phys.net/5/919/2005/acp-5-919-2005.pdf 919 926 2005-03-21 4-D comparison method to study the NO_y partitioning in summer polar stratosphere – Influence of aerosol burden G. Dufour S. Payan F. Lefèvre M. Eremenko A. Butz P. Jeseck Y. Té K. Pfeilsticker C. Camy-Peyret Laboratoire de Physique Moléculaire et Applications, Université P. et M. Curie, Paris, France Service d’Aéronomie, Institut Pierre-Simon Laplace, Paris, France Institut für Umweltphysik, University of Heidelberg, Germany On 21–22 August 2001, NO, NO₂ and HNO₃ mixing ratio profiles were measured at high latitudes during sunset and sunrise using the Limb Profile Monitor of the Atmosphere (LPMA) and the DOAS experiments under stratospheric balloon. Photochemical simulations using the chemistry module of the Reprobus Chemistry Transport Model (CTM) that are constrained by ozone and total NO_y balloon observations reproduce well the partitioning of NO_x and NO_y when model results are calculated at the exact time and location of the measurement for each tangent altitude. Taking the recently recommended reaction rate coefficients for the NO_y partitioning (JPL-2003) and using realistic aerosol surface area in order to initialise the model leads to an agreement between calculations and measurements better than 10% all over the covered altitude range.