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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-77-2005</article-id>
<title-group>
<article-title>Heterogeneous conversion of NO&lt;sub&gt;2&lt;/sub&gt; and NO on HNO&lt;sub&gt;3&lt;/sub&gt; treated soot surfaces: atmospheric implications</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kleffmann</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wiesen</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Physikalische Chemie/FB C, Bergische Universität Wuppertal, D-42097 Wuppertal, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>20</day>
<month>01</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>1</issue>
<fpage>77</fpage>
<lpage>83</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/77/2005/acp-5-77-2005.html">This article is available from http://www.atmos-chem-phys.net/5/77/2005/acp-5-77-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/77/2005/acp-5-77-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/77/2005/acp-5-77-2005.pdf</self-uri>
<abstract>
<p>In the present study, the heterogeneous conversion of nitrogen oxide (NO)
and nitrogen dioxide (NO&lt;sub&gt;2&lt;/sub&gt;) was studied at atmospheric humidity levels
on flame soot surfaces treated with gaseous nitric acid (HNO&lt;sub&gt;3&lt;/sub&gt;).
In addition, the heterogeneous reaction of HNO&lt;sub&gt;3&lt;/sub&gt; on soot
was investigated at atmospheric humidity.

&lt;P  style=&quot;line-height: 20px;&quot;&gt;
For the treatment of soot by pure HNO&lt;sub&gt;3&lt;/sub&gt; only reversible uptake with a
surface coverage of ~1-2x10&lt;sup&gt;14&lt;/sup&gt; HNO&lt;sub&gt;3&lt;/sub&gt; cm&lt;sup&gt;-2&lt;/sup&gt; was
observed for HNO&lt;sub&gt;3&lt;/sub&gt; mixing ratios in the range 250-800ppbv. Only
for higher HNO&lt;sub&gt;3&lt;/sub&gt; mixing ratios of &amp;gt;800ppbv the formation of NO and
NO&lt;sub&gt;2&lt;/sub&gt; was observed. The results were not affected by the addition of NO.
In none of the experiments with HNO&lt;sub&gt;3&lt;/sub&gt; the formation of nitrous acid
(HONO) was observed. For HNO&lt;sub&gt;3&lt;/sub&gt; mixing ratios &amp;lt;600ppbv the upper limit
yields for HONO, NO&lt;sub&gt;2&lt;/sub&gt; and NO were found to be &amp;lt;0.2%, &amp;lt;0.5%
and &amp;lt;1%, respectively. Compared to untreated soot, the product
formation of the reaction of NO&lt;sub&gt;2&lt;/sub&gt; with soot was not significantly
affected when the soot surface was treated with gaseous HNO&lt;sub&gt;3&lt;/sub&gt; prior to
the experiment. Only for high surface coverage of HNO&lt;sub&gt;3&lt;/sub&gt; the formation of
HONO was suppressed in the initial phase of the reaction, probably caused by
the blocking of active sites by adsorbed HNO&lt;sub&gt;3&lt;/sub&gt;.

&lt;P  style=&quot;line-height: 20px;&quot;&gt;
Under the assumption that the experimental findings for the used model flame
soot can be extrapolated to atmospheric soot particles, the results show
that the reactions of HNO&lt;sub&gt;3&lt;/sub&gt; and HNO&lt;sub&gt;3&lt;/sub&gt;+NO on soot surfaces are
unimportant for a &quot;renoxification&quot; of the atmosphere and do not represent
an atmospheric HONO source. In addition, the integrated HONO yield of ca.
10&lt;sup&gt;14&lt;/sup&gt;cm&lt;sup&gt;-2&lt;/sup&gt; in the reaction of NO&lt;sub&gt;2&lt;/sub&gt; with soot is not
significantly influenced by simulated atmospheric processing of the soot
surface by HNO&lt;sub&gt;3&lt;/sub&gt;, and is still too small to explain HONO formation in
the atmosphere.</p>
</abstract>
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