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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-583-2005</article-id>
<title-group>
<article-title>Measurements of total odd nitrogen (NO&lt;sub&gt;y&lt;/sub&gt;) aboard MOZAIC in-service aircraft: instrument design, operation and performance</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Volz-Thomas</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Berg</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Heil</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Houben</surname>
<given-names>N.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lerner</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Petrick</surname>
<given-names>W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Raak</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pätz</surname>
<given-names>H.-W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institut für Chemie und Dynamik der Geosphäre II: Troposphäre, Forschungszentrum Jülich, Jülich, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>25</day>
<month>02</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>3</issue>
<fpage>583</fpage>
<lpage>595</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/583/2005/acp-5-583-2005.html">This article is available from http://www.atmos-chem-phys.net/5/583/2005/acp-5-583-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/583/2005/acp-5-583-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/583/2005/acp-5-583-2005.pdf</self-uri>
<abstract>
<p>A small system for the unattended measurement of total odd
nitrogen (NO&lt;sub&gt;y&lt;/sub&gt;, i.e., the sum of NO and its atmospheric
oxidation products) aboard civil in-service aircraft in the
framework of MOZAIC is described. The instrument employs the
detection of NO by its chemiluminescence with O&lt;sub&gt;3&lt;/sub&gt; in
combination with catalytic conversion of the other NO&lt;sub&gt;y&lt;/sub&gt;
compounds to NO at 300&amp;deg;C on a gold surface in the presence
of H&lt;sub&gt;2&lt;/sub&gt;. The instrument has a sensitivity of 0.4-0.7cps/ppt
and is designed for unattended operation during 1-2 service
cycles of the aircraft (400-800 flight hours). The total weight
is 50kg, including calibration system, compressed gases,
mounting, and safety measures. The layout and inlet configuration
are governed by requirements due to the certification for
passenger aircraft. Laboratory tests are described regarding the
conversion efficiency for NO&lt;sub&gt;2&lt;/sub&gt; and HNO&lt;sub&gt;3&lt;/sub&gt; (both
&amp;gt;98%). Interference by non-NO&lt;sub&gt;y&lt;/sub&gt; species is
&amp;lt;1% for CH&lt;sub&gt;3&lt;/sub&gt;CN and NH&lt;sub&gt;3&lt;/sub&gt;, &amp;lt;5x10&lt;sup&gt;-5&lt;/sup&gt;% for
N&lt;sub&gt;2&lt;/sub&gt;O (corresponding to &amp;lt;0.2ppt fake NO&lt;sub&gt;y&lt;/sub&gt; from
ambient N&lt;sub&gt;2&lt;/sub&gt;O)  and 100% for HCN. The time response of the
instrument is &amp;lt;1s (90% change) for NO&lt;sub&gt;2&lt;/sub&gt;. The response
for HNO&lt;sub&gt;3&lt;/sub&gt; is nonlinear: 20s for 67%, 60s for 80%,
and 150s for 90% response, respectively.</p>
</abstract>
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