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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-393-2005</article-id>
<title-group>
<article-title>Using a photochemical model for the validation of NO&lt;sub&gt;2&lt;/sub&gt; satellite measurements at different solar zenith angles</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bracher</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sinnhuber</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rozanov</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Burrows</surname>
<given-names>J. P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute of Environmental Physics and Remote Sensing (IUP/IFE), University of Bremen, Otto-Hahn-Allee 1, 28334 Bremen, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>10</day>
<month>02</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>2</issue>
<fpage>393</fpage>
<lpage>408</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/393/2005/acp-5-393-2005.html">This article is available from http://www.atmos-chem-phys.net/5/393/2005/acp-5-393-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/393/2005/acp-5-393-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/393/2005/acp-5-393-2005.pdf</self-uri>
<abstract>
<p>SCIAMACHY (Scanning Imaging Spectrometer for Atmospheric Chartography)
aboard the recently launched Environmental Satellite (ENVISAT) of ESA is
measuring solar radiance upwelling from the atmosphere and the
extraterrestrial irradiance. Appropriate inversion of the ultraviolet and
visible radiance measurements, observed from the atmospheric limb, yields
profiles of nitrogen dioxide, NO&lt;sub&gt;2&lt;/sub&gt;, in the stratosphere (SCIAMACHY-IUP
NO&lt;sub&gt;2&lt;/sub&gt; profiles V1). In order to assess their accuracy, the resulting
NO&lt;sub&gt;2&lt;/sub&gt; profiles have been compared with those retrieved from the space
borne occultation instruments Halogen Occultation Experiment (HALOE, data
version v19) and Stratospheric Aerosol and Gas Experiment II (SAGE II, data
version 6.2). As the HALOE and SAGE II measurements are performed during
local sunrise or sunset and because NO&lt;sub&gt;2&lt;/sub&gt; has a significant diurnal
variability, the NO&lt;sub&gt;2&lt;/sub&gt; profiles derived from HALOE and SAGE II have been
transformed to those predicted for the solar zenith angles of the SCIAMACHY
measurement by using a 1-dimensional photochemical model. The model used to
facilitate the comparison of the NO&lt;sub&gt;2&lt;/sub&gt; profiles from the different
satellite sensors is described and a sensitivity ananlysis provided.
Comparisons between NO&lt;sub&gt;2&lt;/sub&gt; profiles from SCIAMACHY and those from HALOE
NO&lt;sub&gt;2&lt;/sub&gt; but transformed to the SCIAMACHY solar zenith angle, for
collocations from July to October 2002, show good agreement (within +/-12%)
between the altitude range from 22 to 33km. The results from the
comparison of all collocated NO&lt;sub&gt;2&lt;/sub&gt; profiles from SCIAMACHY and those from
SAGE II transformed to the SCIAMACHY solar zenith angle show a systematic
negative bias of 10 to 35% between 20km to 38km with a small standard
deviation between 5 to 14%. These results agree with those of Newchurch
and Ayoub (2004), implying that above 20km NO&lt;sub&gt;2&lt;/sub&gt; profiles from SAGE II
sunset are probably somewhat high.</p>
</abstract>
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