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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-2657-2005</article-id>
<title-group>
<article-title>Stratospheric and tropospheric NO&lt;sub&gt;2&lt;/sub&gt; variability on the diurnal and annual scale: a combined retrieval from ENVISAT/SCIAMACHY and solar FTIR at the Permanent Ground-Truthing Facility Zugspitze/Garmisch</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sussmann</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Stremme</surname>
<given-names>W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Burrows</surname>
<given-names>J. P.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Richter</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Seiler</surname>
<given-names>W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Rettinger</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>IMK-IFU, Forschungszentrum Karlsruhe, Garmisch-Partenkirchen, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institute of Environmental Physics, University of Bremen, Bremen, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>07</day>
<month>10</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>10</issue>
<fpage>2657</fpage>
<lpage>2677</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/2657/2005/acp-5-2657-2005.html">This article is available from http://www.atmos-chem-phys.net/5/2657/2005/acp-5-2657-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/2657/2005/acp-5-2657-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/2657/2005/acp-5-2657-2005.pdf</self-uri>
<abstract>
<p>Columnar NO&lt;sub&gt;2&lt;/sub&gt; retrievals from solar FTIR measurements at the Zugspitze
(47.42&amp;deg; N, 10.98&amp;deg; E, 2964 m&amp;nbsp;a.s.l.), Germany were investigated
synergistically with columnar NO&lt;sub&gt;2&lt;/sub&gt; retrieved from SCIAMACHY data by the
University of Bremen scientific algorithm UB1.5 for the time span July 2002-October
2004. A new concept to match FTIR data to the time of satellite
overpass makes use of the NO&lt;sub&gt;2&lt;/sub&gt; daytime increasing rate retrieved from
the FTIR data set itself [+1.02(6)E+14 cm&lt;sup&gt;-2&lt;/sup&gt;/h]. This measured increasing
rate shows no significant seasonal variation. SCIAMACHY data within a 200-km
radius around Zugspitze were considered, and a pollution-clearing
scheme was developed to select only pixels corresponding to clean background
(free) tropospheric conditions, and exclude local pollution hot spots. The resulting
difference between SCIAMACHY and FTIR columns (without correcting
for the different sensitivities of the instruments) varies between
0.60-1.24E+15 cm&lt;sup&gt;-2&lt;/sup&gt; with an average of 0.83E+15 cm&lt;sup&gt;-2&lt;/sup&gt;. A
day-to-day scatter of daily means of &amp;asymp;7-10% could be retrieved in mutual
agreement from FTIR and SCIAMACHY. Both data sets are showing sufficient
precisions to make this assessment. Analysis of the averaging kernels gives
proof that at high-mountain-site FTIR is a highly accurate measure for the pure
stratospheric column, while SCIAMACHY shows significant tropospheric
sensitivity. Based on this finding, we set up a combined a posteriori
FTIR-SCIAMACHY retrieval for tropospheric NO&lt;sub&gt;2&lt;/sub&gt;, based upon the averaging
kernels. It yields an annual cycle of the clean background (free)
tropospheric column (&amp;lt;10 km) with variations between 0.75-1.54E+15 cm&lt;sup&gt;-2&lt;/sup&gt;,
an average of 1.09E+15 cm&lt;sup&gt;-2&lt;/sup&gt;, and an intermediate phase
between that of the well known boundary layer and stratospheric annual
cycles. The outcome is a concept for an integrated global observing system
for tropospheric NO&lt;sub&gt;2&lt;/sub&gt; that comprises DOAS nadir satellite measurements
and a set of latitudinally distributed mountain-site or clean-air FTIR
stations.</p>
</abstract>
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