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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-1489-2005</article-id>
<title-group>
<article-title>Nanoparticle formation by ozonolysis of inducible plant volatiles</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Joutsensaari</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Loivamäki</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vuorinen</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Miettinen</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Nerg</surname>
<given-names>A.-M.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Holopainen</surname>
<given-names>J. K.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Laaksonen</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Department of Environmental Sciences, University of Kuopio, P.O. Box 1627, FIN-70211 Kuopio, Finland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Ecology and Environmental Science, University of Kuopio, P.O. Box 1627, Kuopio FIN-70211, Finland</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institute for Meteorology and Climate Research – Atmospheric Environmental Research (IMK-IFU), Kreuzeckbahnstrasse 19, 82467 Garmisch-Partenkirchen, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Applied Physics, University of Kuopio, P.O. Box 1627, FIN-70211 Kuopio, Finland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>16</day>
<month>06</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>6</issue>
<fpage>1489</fpage>
<lpage>1495</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/1489/2005/acp-5-1489-2005.html">This article is available from http://www.atmos-chem-phys.net/5/1489/2005/acp-5-1489-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/1489/2005/acp-5-1489-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/1489/2005/acp-5-1489-2005.pdf</self-uri>
<abstract>
<p>We present the first laboratory experiments of aerosol formation
from oxidation of volatile organic species emitted by living
plants, a process which for half a century has been known to take
place in the atmosphere. We have treated white cabbage plants with
methyl jasmonate in order to induce the production of monoterpenes
and certain less-volatile sesqui- and homoterpenes. Ozone was
introduced into the growth chamber in which the plants were
placed, and the subsequent aerosol formation and growth of
aerosols were monitored by measuring the particle size
distributions continuously during the experiments. Our
observations show similar particle formation rates as in the
atmosphere but much higher growth rates. The results indicate that
the concentrations of nonvolatile oxidation products of plant
released precursors needed to induce the nucleation are roughly an
order-of-magnitude higher than their concentrations during
atmospheric nucleation events. Our results therefore suggest that
if oxidized organics are involved
in atmospheric nucleation events, their role is to participate
in the growth of pre-existing molecular clusters rather than to form
such clusters through homogeneous or ion-induced nucleation.</p>
</abstract>
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