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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-5-1437-2005</article-id>
<title-group>
<article-title>Simulation of denitrification and ozone loss for the Arctic winter 2002/2003</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Grooß</surname>
<given-names>J.-U.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Günther</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Müller</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Konopka</surname>
<given-names>P.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bausch</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schlager</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Voigt</surname>
<given-names>C.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Volk</surname>
<given-names>C.M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Toon</surname>
<given-names>G. C.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institut für Chemie und Dynamik der Geosphäre I: Stratosphäre (ICG I), Forschungszentrum Jülich, Jülich, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institut für Physik der Atmosphäre, DLR Oberpfaffenhofen, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institut für Meteorologie und Geophysik, Universität Frankfurt, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>15</day>
<month>06</month>
<year>2005</year>
</pub-date>
<volume>5</volume>
<issue>6</issue>
<fpage>1437</fpage>
<lpage>1448</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/1437/2005/acp-5-1437-2005.html">This article is available from http://www.atmos-chem-phys.net/5/1437/2005/acp-5-1437-2005.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/5/1437/2005/acp-5-1437-2005.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/5/1437/2005/acp-5-1437-2005.pdf</self-uri>
<abstract>
<p>We present simulations with the Chemical Lagrangian Model of the
Stratosphere (CLaMS) for the Arctic winter 2002/2003. We integrated a
Lagrangian denitrification scheme into the three-dimensional
version of CLaMS that calculates the growth and sedimentation of
nitric acid trihydrate (NAT) particles along individual particle
trajectories.  From those, we derive the HNO&lt;sub&gt;3&lt;/sub&gt; downward flux
resulting from different particle nucleation assumptions.
The simulation results show a clear vertical redistribution of total
inorganic nitrogen ( ), with a maximum vortex average permanent
 removal of over 5ppb in late December between 500 and 550K
and a corresponding increase of  of over 2ppb below about
450K.
The simulated vertical redistribution of  is compared with
balloon observations by MkIV and in-situ observations from the high
altitude aircraft Geophysica.  Assuming a globally uniform NAT
particle nucleation rate of 7.8x10&lt;sup&gt;-6&lt;/sup&gt;cm&lt;sup&gt;-3&lt;/sup&gt;h&lt;sup&gt;-1&lt;/sup&gt; in
the model, the observed denitrification is well reproduced.

&lt;P  style=&quot;line-height: 20px;&quot;&gt;
In the investigated winter 2002/2003, the denitrification has only
moderate impact (&amp;le;14%) on the simulated vortex average ozone loss of
about 1.1ppm near the 460K level.
At higher altitudes, above 600K potential temperature, the simulations
show significant ozone depletion through -catalytic cycles due to the
unusual early exposure of vortex air to sunlight.</p>
</abstract>
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