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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-4-423-2004</article-id>
<title-group>
<article-title>Effects of various meteorological conditions and spatial emissionresolutions on the ozone concentration and ROG/NO&lt;sub&gt;x&lt;/sub&gt; limitationin the Milan area (I)</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Baertsch-Ritter</surname>
<given-names>N.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Keller</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dommen</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Prevot</surname>
<given-names>A. S. H.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, CH-5232 Villigen PSI, Switzerland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>17</day>
<month>03</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>2</issue>
<fpage>423</fpage>
<lpage>438</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/4/423/2004/acp-4-423-2004.html">This article is available from http://www.atmos-chem-phys.net/4/423/2004/acp-4-423-2004.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/4/423/2004/acp-4-423-2004.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/4/423/2004/acp-4-423-2004.pdf</self-uri>
<abstract>
<p>The three-dimensional photochemical model UAM-V is used to investigate the
effects of various meteorological conditions and of the coarseness of
emission inventories on the ozone concentration and ROG/NO&lt;sub&gt;x&lt;/sub&gt; limitation
of the ozone production in the Po Basin in the northern part of Italy. As a
base case, the high ozone episode with up to 200ppb on 13 May 1998 was
modelled and previously thoroughly evaluated with measurements gained during
a large field experiment. Systematic variations in meteorology are applied
to mixing height, air temperature, specific humidity and wind speed. Three
coarser emission inventories are obtained by resampling from 3x3km&lt;sup&gt;2&lt;/sup&gt; up
to 54x54km&lt;sup&gt;2&lt;/sup&gt; emission grids. The model results show that changes in
meteorological input files strongly influence ozone in this area. For
instance, temperature changes peak ozone by 10.1ppb/&amp;degC and the ozone
concentrations in Milan by 2.8ppb/&amp;degC. The net ozone formation in
northern Italy is more strongly temperature than humidity dependent, while
the humidity is very important for the ROG/NO&lt;sub&gt;x&lt;/sub&gt; limitation of the ozone
production. For all meteorological changes (e.g. doubling the mixing
height), the modelled peak ozone remains ROG limited. A strong change
towards NO&lt;sub&gt;x&lt;/sub&gt; sensitivity in the ROG limited areas is only found if much
coarser emission inventories were applied. Increasing ROG limited areas with
increasing wind speed are found, because the ROG limited ozone chemistry
induced by point sources is spread over a larger area. Simulations without
point sources tend to increase the NO&lt;sub&gt;x&lt;/sub&gt; limited areas.</p>
</abstract>
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