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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-4-1291-2004</article-id>
<title-group>
<article-title>Uptake study of ClONO&lt;sub&gt;2&lt;/sub&gt; and BrONO&lt;sub&gt;2&lt;/sub&gt; by Halide containing droplets</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Deiber</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>George</surname>
<given-names>Ch.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Le Calvé</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schweitzer</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Mirabel</surname>
<given-names>Ph.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Centre de Gochimie de la Surface / UMR 7517 CNRS and Univ. Louis Pasteur, 1 rue Blessig, F-67084 Strasbourg, France</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Laboratoire d’Application de la Chimie à l’Environnement (LACE), 43 boulevard du 11 novembre 1918, F-69622 Villeurbanne, France</addr-line>
</aff>
<pub-date pub-type="epub">
<day>20</day>
<month>08</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>5</issue>
<fpage>1291</fpage>
<lpage>1299</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/4/1291/2004/acp-4-1291-2004.html">This article is available from http://www.atmos-chem-phys.net/4/1291/2004/acp-4-1291-2004.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/4/1291/2004/acp-4-1291-2004.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/4/1291/2004/acp-4-1291-2004.pdf</self-uri>
<abstract>
<p>The uptake kinetics of gaseous ClONO&lt;sub&gt;2&lt;/sub&gt; and BrONO&lt;sub&gt;2&lt;/sub&gt; on aqueous
surfaces were measured, as a function of temperature and liquid composition
(pure water and NaCl or NaBr containing solutions) using the droplet train
technique coupled to a mass spectrometer. The uptake kinetics are driven by
the reactivity of these gases and, for both compounds, the uptake rates on
pure water or on NaCl solutions (0.1M) are comparable. The uptake
coefficient &amp;gamma; of ClONO&lt;sub&gt;2&lt;/sub&gt; does not depend on the temperature
while that of BrONO&lt;sub&gt;2&lt;/sub&gt; increases slightly when the temperature is raised
from 272 to 280K. For ClONO&lt;sub&gt;2&lt;/sub&gt; and BrONO&lt;sub&gt;2&lt;/sub&gt;, the uptake rates
increase on NaBr-doped droplets, enabling the estimation of the mass
accommodation coefficient &amp;alpha;. The corresponding values for &amp;alpha;
are 0.108&amp;plusmn;0.033 for ClONO&lt;sub&gt;2&lt;/sub&gt; and 0.063&amp;plusmn;0.021 for
BrONO&lt;sub&gt;2&lt;/sub&gt; where the statistical errors correspond to &amp;plusmn;2&amp;sigma;.

&lt;P  style=&quot;line-height: 20px;&quot;&gt;
The reactions of ClONO&lt;sub&gt;2&lt;/sub&gt; and BrONO&lt;sub&gt;2&lt;/sub&gt; on NaCl solutions lead
respectively to the formation of Cl&lt;sub&gt;2&lt;/sub&gt; and BrCl. The uptake of
ClONO&lt;sub&gt;2&lt;/sub&gt; on NaBr solutions generates BrCl as primary product, which in
turn can react with NaBr to produce Br&lt;sub&gt;2&lt;/sub&gt;. As expected, the only product
of BrONO&lt;sub&gt;2&lt;/sub&gt; reaction on NaBr solution is Br&lt;sub&gt;2&lt;/sub&gt;.</p>
</abstract>
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