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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-3-437-2003</article-id>
<title-group>
<article-title>On the transition between heterogeneous and homogeneous freezing</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gierens</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik der Atmosphäre, Oberpfaffenhofen, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>15</day>
<month>04</month>
<year>2003</year>
</pub-date>
<volume>3</volume>
<issue>2</issue>
<fpage>437</fpage>
<lpage>446</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<self-uri xlink:href="http://www.atmos-chem-phys.net/3/437/2003/acp-3-437-2003.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/3/437/2003/acp-3-437-2003.pdf</self-uri>
<abstract>
<p>Box model simulations of an uplifting and adiabatically cooling
      cloud of aerosol have been performed in order to study the transition between cirrus formation dominated by homogeneous
      nucleation of ice to that dominated by heterogeneous nucleation. The aerosol was assumed to consist of an internal mixture of
      sulfuric acid solution droplets with inclusions of soot. The parametrisation of
      De Mott et al. (1997) was used to simulate the heterogeneous nucleation of ice in such droplets with soot
      inclusions. The simulations show that the transition from heterogeneous to
      homogeneous nucleation occurs over a narrow range of soot concentration.  Thus it seems to be possible to fix critical
      concentrations of heterogeneous ice nuclei which must be exceeded if heterogeneous freezing dominates cirrus formation. A formula has been
      derived that allows to compute the critical concentrations of heterogeneous ice nuclei as a function of temperature, updraft speed,
      ambient pressure, and supersaturation at which heterogeneous freezing occurs.  Generally, homogeneous nucleation dominates in regions with
      updrafts stronger than 20 cm s &lt;sup&gt;-1&lt;/sup&gt;, with the exception of heavily
      polluted areas which could be common in the northern hemisphere due to air traffic, where updrafts of the order
      1 m s&lt;sup&gt;-1&lt;/sup&gt; may be necessary to render heterogeneous nucleation unimportant. According to the
      present results it cannot be excluded that heterogeneous nucleation plays a more important role for cirrus formation in the northern
      midlatitudes than anywhere else.  A possible consequence of these results is that air pollution may lead to a higher coverage of
      cirrus clouds, but then these clouds will be optically thinner than clouds formed by homogeneous freezing, with the exception of regions
      where condensation trails are frequent.</p>
</abstract>
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</front>
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