Articles | Volume 3, issue 2
https://doi.org/10.5194/acp-3-315-2003
© Author(s) 2003. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
https://doi.org/10.5194/acp-3-315-2003
© Author(s) 2003. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
21 Mar 2003
The isotopic fingerprint of the pre-industrial and the anthropogenic N2O source
T. Röckmann
Max Planck Institute for Nuclear Physics, Atmospheric Physics Division, Heidelberg, Germany
J. Kaiser
Max Planck Institute for Nuclear Physics, Atmospheric Physics Division, Heidelberg, Germany
now at: Department of Geosciences, Princeton University, Princeton, USA
C. A. M. Brenninkmeijer
Max Planck Institute for Chemistry, Air Chemistry Division, Mainz, Germany
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Cited
76 citations as recorded by crossref.
- Measurement of isotopomer signatures of N2O in groundwater R. Well et al. 10.1029/2005JG000044
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- DFT Study of N2O Adsorption onto the Surface of M-Decorated Graphene Oxide (M = Mg, Cu or Ag) Z. Liu et al. 10.3390/ma12162611
- An in-depth look into a tropical lowland forest soil: nitrogen-addition effects on the contents of N2O, CO2 and CH4 and N2O isotopic signatures down to 2-m depth B. Koehler et al. 10.1007/s10533-012-9711-6
- The 18O isotope exchange rate between firn air CO2 and the firn matrix at three Antarctic sites S. Assonov et al. 10.1029/2005JD005769
- Stable carbon isotope fractionation in the UV photolysis of CFC-11 and CFC-12 A. Zuiderweg et al. 10.5194/acp-12-4379-2012
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- Nitrogen isotopic signatures and fluxes of N2O in response to land-use change on naturally occurring saline–alkaline soil A. Timilsina et al. 10.1038/s41598-020-78149-w
- Global modeling of the isotopic analogues of N2O: Stratospheric distributions, budgets, and the 17O–18O mass‐independent anomaly C. McLinden et al. 10.1029/2002JD002560
- A liquid nitrogen-free preconcentration unit for measurements of ambient N<sub>2</sub>O isotopomers by QCLAS J. Mohn et al. 10.5194/amt-3-609-2010
- Development of automated preparation system for isotopocule analysis of N<sub>2</sub>O in various air samples S. Toyoda & N. Yoshida 10.5194/amt-9-2093-2016
- Temporal variations of the atmospheric nitrous oxide concentration and its δ15N and δ18O for the latter half of the 20th century reconstructed from firn air analyses K. Ishijima et al. 10.1029/2006JD007208
- Complete and accurate mass spectrometric isotope analysis of tropospheric nitrous oxide J. Kaiser et al. 10.1029/2003JD003613
- Measurements of N2O isotopologues in the stratosphere: Influence of transport on the apparent enrichment factors and the isotopologue fluxes to the troposphere S. Park et al. 10.1029/2003JD003731
- Trends and seasonal cycles in the isotopic composition of nitrous oxide since 1940 S. Park et al. 10.1038/ngeo1421
- Isotopomer fractionation in the UV photolysis of N2O: 2. Further comparison of theory and experiment W. Chen et al. 10.1029/2007JD009180
- How reliable is the intramolecular distribution of 15N in N2O to source partition N2O emitted from soil? C. Decock & J. Six 10.1016/j.soilbio.2013.05.012
- N<sub>2</sub>O changes from the Last Glacial Maximum to the preindustrial – Part 1: Quantitative reconstruction of terrestrial and marine emissions using N<sub>2</sub>O stable isotopes in ice cores H. Fischer et al. 10.5194/bg-16-3997-2019
- Tracking nitrous oxide emission processes at a suburban site with semicontinuous, in situ measurements of isotopic composition E. Harris et al. 10.1002/2016JD025906
- Catalytic reduction of N2O over Si-embedded MoS2 monolayer: A single-atom catalyst approach M. Esrafili 10.1016/j.inoche.2019.107504
- Comment on “Evidence for O‐atom exchange in the O(1D) + N2O reaction as the source of mass‐independent isotopic fractionation in atmospheric N2O” by Y. L. Yung et al. T. Röckmann & J. Kaiser 10.1029/2004GL022149
- Clumped isotope perturbation in tropospheric nitrous oxide from stratospheric photolysis J. Schmidt & M. Johnson 10.1002/2015GL063102
- N2O and NOy production by the comammox bacterium Nitrospira inopinata in comparison with canonical ammonia oxidizers P. Han et al. 10.1016/j.watres.2020.116728
- Gas transport in firn: multiple-tracer characterisation and model intercomparison for NEEM, Northern Greenland C. Buizert et al. 10.5194/acp-12-4259-2012
- Nitrous Oxide Formation by Corona Discharge: Isotopic Composition Measurements and Atmospheric Applications M. Smith et al. 10.1029/2020JD033927
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- Evidence for a CO increase in the SH during the 20th century based on firn air samples from Berkner Island, Antarctica S. Assonov et al. 10.5194/acp-7-295-2007
- Al- or Si-decorated graphene oxide: A favorable metal-free catalyst for the N2O reduction M. Esrafili et al. 10.1016/j.apsusc.2016.06.127
- Comparison of measured and EF5‐r‐derived N2O fluxes from a spring‐fed river T. CLOUGH et al. 10.1111/j.1365-2486.2005.01089.x
- Are dual isotope and isotopomer ratios of N2O useful indicators for N2O turnover during denitrification in nitrate-contaminated aquifers? R. Well et al. 10.1016/j.gca.2012.04.045
- Temporal and latitudinal distributions of stratospheric N2O isotopomers S. Toyoda et al. 10.1029/2003JD004316
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- Continuous‐flow isotope analysis of the deuterium/hydrogen ratio in atmospheric hydrogen T. Rhee et al. 10.1002/rcm.1309
- Absolute Calibration of the Intramolecular Site Preference of 15N Fractionation in Tropospheric N2O by FT-IR Spectroscopy D. Griffith et al. 10.1021/ac802371c
- High‐precision determination of the changing isotopic composition of atmospheric N2O from 1990 to 2002 T. Röckmann & I. Levin 10.1029/2005JD006066
- Recent research progress on the significance of aquatic systems for indirect agricultural N2O emissions R. Well et al. 10.1080/15693430500393334
- Lime and Soil Moisture Effects on Nitrous Oxide Emissions from a Urine Patch T. Clough et al. 10.2136/sssaj2004.1600
- Concentration and Isotopic Composition of Atmospheric N2O Over the Last Century S. Ghosh et al. 10.1029/2022JD038281
- Isotope fractionation factors of N2O diffusion R. Well & H. Flessa 10.1002/rcm.3656
- Do increasingly depleted δ15N values of atmospheric N2O indicate a decline in soil N2O reduction? F. Conen & A. Neftel 10.1007/s10533-006-9066-y
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- Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide E. Harris et al. 10.1021/ac403606u
- Effect of local and regional sources on the isotopic composition of nitrous oxide in the tropical free troposphere and tropopause layer P. Croteau et al. 10.1029/2009JD013117
- Vertical gradients of δ15N and δ18O in soil atmospheric N2O—temporal dynamics in a sandy soil J. Van Groenigen et al. 10.1002/rcm.1929
- Mid-infrared laser spectroscopic determination of isotope ratios of N2O at trace levels using wavelength modulation and balanced path length detection H. Waechter & M. Sigrist 10.1007/s00340-007-2576-z
- Isotopic constraints on marine and terrestrial N2O emissions during the last deglaciation A. Schilt et al. 10.1038/nature13971
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- Constraining N<sub>2</sub>O emissions since 1940 using firn air isotope measurements in both hemispheres M. Prokopiou et al. 10.5194/acp-17-4539-2017
- Stratospheric carbon isotope fractionation and tropospheric histories of CFC-11, CFC-12, and CFC-113 isotopologues M. Thomas et al. 10.5194/acp-21-6857-2021
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- Diffusion of 15N-labelled N2O into soil columns: a promising method to examine the fate of N2O in subsoils T. Clough et al. 10.1016/j.soilbio.2005.11.002
- Decadal time series of tropospheric abundance of N2O isotopomers and isotopologues in the Northern Hemisphere obtained by the long‐term observation at Hateruma Island, Japan S. Toyoda et al. 10.1002/jgrd.50221
- Isotopic signatures and concentration profiles of nitrous oxide in a rice‐based ecosystem during the drained crop‐growing season Z. Xiong et al. 10.1029/2008JG000827
- Chlorine isotope composition in chlorofluorocarbons CFC-11, CFC-12 and CFC-113 in firn, stratospheric and tropospheric air S. Allin et al. 10.5194/acp-15-6867-2015
- Changes in the Isotopic Signature of Atmospheric Nitrous Oxide and Its Global Average Source During the Last Three Millennia M. Prokopiou et al. 10.1029/2018JD029008
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- Determination of the triple oxygen and carbon isotopic composition of CO2 from atomic ion fragments formed in the ion source of the 253 Ultra high‐resolution isotope ratio mass spectrometer G. Adnew et al. 10.1002/rcm.8478
- Measurement of the 17O‐excess (Δ17O) of tropospheric ozone using a nitrite‐coated filter W. Vicars et al. 10.1002/rcm.6218
- Analytical techniques for measuring nitrous oxide T. Rapson & H. Dacres 10.1016/j.trac.2013.11.004
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- 3‐D Atmospheric Modeling of the Global Budget of N2O and Its Isotopologues for 1980–2019: The Impact of Anthropogenic Emissions Q. Liang et al. 10.1029/2021GB007202
- Contribution of mass‐dependent fractionation to the oxygen isotope anomaly of atmospheric nitrous oxide J. Kaiser et al. 10.1029/2003JD004088
- Probing stratospheric transport and chemistry with new balloon and aircraft observations of the meridional and vertical N<sub>2</sub>O isotope distribution J. Kaiser et al. 10.5194/acp-6-3535-2006
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- Isotope Effects in the Chemistry of Atmospheric Trace Compounds C. Brenninkmeijer et al. 10.1021/cr020644k
- Can N2O stable isotopes and isotopomers be useful tools to characterize sources and microbial pathways of N2O production and consumption in tropical soils? S. Park et al. 10.1029/2009GB003615
- An approach for calibrating laser‐based N2O isotopic analyzers for soil biogeochemistry research E. Stuchiner et al. 10.1002/rcm.8978
- N2O + CO reaction over Si- and Se-doped graphenes: An ab initio DFT study R. Gholizadeh & Y. Yu 10.1016/j.apsusc.2015.09.163
- Gas chromatography/isotope‐ratio mass spectrometry method for high‐precision position‐dependent15N and18O measurements of atmospheric nitrous oxide T. Röckmann et al. 10.1002/rcm.1132
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- Inverse modeling estimates of the global nitrous oxide surface flux from 1998–2001 A. Hirsch et al. 10.1029/2004GB002443
72 citations as recorded by crossref.
- Measurement of isotopomer signatures of N2O in groundwater R. Well et al. 10.1029/2005JG000044
- Isotopomer Analysis of Production and Consumption Mechanisms of N2O and CH4 in an Advanced Wastewater Treatment System S. Toyoda et al. 10.1021/es102985u
- DFT Study of N2O Adsorption onto the Surface of M-Decorated Graphene Oxide (M = Mg, Cu or Ag) Z. Liu et al. 10.3390/ma12162611
- An in-depth look into a tropical lowland forest soil: nitrogen-addition effects on the contents of N2O, CO2 and CH4 and N2O isotopic signatures down to 2-m depth B. Koehler et al. 10.1007/s10533-012-9711-6
- The 18O isotope exchange rate between firn air CO2 and the firn matrix at three Antarctic sites S. Assonov et al. 10.1029/2005JD005769
- Stable carbon isotope fractionation in the UV photolysis of CFC-11 and CFC-12 A. Zuiderweg et al. 10.5194/acp-12-4379-2012
- Characterization and production and consumption processes of N2O emitted from temperate agricultural soils determined via isotopomer ratio analysis S. Toyoda et al. 10.1029/2009GB003769
- Nitrogen isotopic signatures and fluxes of N2O in response to land-use change on naturally occurring saline–alkaline soil A. Timilsina et al. 10.1038/s41598-020-78149-w
- Global modeling of the isotopic analogues of N2O: Stratospheric distributions, budgets, and the 17O–18O mass‐independent anomaly C. McLinden et al. 10.1029/2002JD002560
- A liquid nitrogen-free preconcentration unit for measurements of ambient N<sub>2</sub>O isotopomers by QCLAS J. Mohn et al. 10.5194/amt-3-609-2010
- Development of automated preparation system for isotopocule analysis of N<sub>2</sub>O in various air samples S. Toyoda & N. Yoshida 10.5194/amt-9-2093-2016
- Temporal variations of the atmospheric nitrous oxide concentration and its δ15N and δ18O for the latter half of the 20th century reconstructed from firn air analyses K. Ishijima et al. 10.1029/2006JD007208
- Complete and accurate mass spectrometric isotope analysis of tropospheric nitrous oxide J. Kaiser et al. 10.1029/2003JD003613
- Measurements of N2O isotopologues in the stratosphere: Influence of transport on the apparent enrichment factors and the isotopologue fluxes to the troposphere S. Park et al. 10.1029/2003JD003731
- Trends and seasonal cycles in the isotopic composition of nitrous oxide since 1940 S. Park et al. 10.1038/ngeo1421
- Isotopomer fractionation in the UV photolysis of N2O: 2. Further comparison of theory and experiment W. Chen et al. 10.1029/2007JD009180
- How reliable is the intramolecular distribution of 15N in N2O to source partition N2O emitted from soil? C. Decock & J. Six 10.1016/j.soilbio.2013.05.012
- N<sub>2</sub>O changes from the Last Glacial Maximum to the preindustrial – Part 1: Quantitative reconstruction of terrestrial and marine emissions using N<sub>2</sub>O stable isotopes in ice cores H. Fischer et al. 10.5194/bg-16-3997-2019
- Tracking nitrous oxide emission processes at a suburban site with semicontinuous, in situ measurements of isotopic composition E. Harris et al. 10.1002/2016JD025906
- Catalytic reduction of N2O over Si-embedded MoS2 monolayer: A single-atom catalyst approach M. Esrafili 10.1016/j.inoche.2019.107504
- Comment on “Evidence for O‐atom exchange in the O(1D) + N2O reaction as the source of mass‐independent isotopic fractionation in atmospheric N2O” by Y. L. Yung et al. T. Röckmann & J. Kaiser 10.1029/2004GL022149
- Clumped isotope perturbation in tropospheric nitrous oxide from stratospheric photolysis J. Schmidt & M. Johnson 10.1002/2015GL063102
- N2O and NOy production by the comammox bacterium Nitrospira inopinata in comparison with canonical ammonia oxidizers P. Han et al. 10.1016/j.watres.2020.116728
- Gas transport in firn: multiple-tracer characterisation and model intercomparison for NEEM, Northern Greenland C. Buizert et al. 10.5194/acp-12-4259-2012
- Nitrous Oxide Formation by Corona Discharge: Isotopic Composition Measurements and Atmospheric Applications M. Smith et al. 10.1029/2020JD033927
- Isotopic fractionation of nitrous oxide in the stratosphere: Comparison between model and observations C. Morgan et al. 10.1029/2003JD003402
- Evidence for a CO increase in the SH during the 20th century based on firn air samples from Berkner Island, Antarctica S. Assonov et al. 10.5194/acp-7-295-2007
- Al- or Si-decorated graphene oxide: A favorable metal-free catalyst for the N2O reduction M. Esrafili et al. 10.1016/j.apsusc.2016.06.127
- Comparison of measured and EF5‐r‐derived N2O fluxes from a spring‐fed river T. CLOUGH et al. 10.1111/j.1365-2486.2005.01089.x
- Are dual isotope and isotopomer ratios of N2O useful indicators for N2O turnover during denitrification in nitrate-contaminated aquifers? R. Well et al. 10.1016/j.gca.2012.04.045
- Temporal and latitudinal distributions of stratospheric N2O isotopomers S. Toyoda et al. 10.1029/2003JD004316
- From the Ground Up: Global Nitrous Oxide Sources are Constrained by Stable Isotope Values D. Snider et al. 10.1371/journal.pone.0118954
- Continuous‐flow isotope analysis of the deuterium/hydrogen ratio in atmospheric hydrogen T. Rhee et al. 10.1002/rcm.1309
- Absolute Calibration of the Intramolecular Site Preference of 15N Fractionation in Tropospheric N2O by FT-IR Spectroscopy D. Griffith et al. 10.1021/ac802371c
- High‐precision determination of the changing isotopic composition of atmospheric N2O from 1990 to 2002 T. Röckmann & I. Levin 10.1029/2005JD006066
- Recent research progress on the significance of aquatic systems for indirect agricultural N2O emissions R. Well et al. 10.1080/15693430500393334
- Lime and Soil Moisture Effects on Nitrous Oxide Emissions from a Urine Patch T. Clough et al. 10.2136/sssaj2004.1600
- Concentration and Isotopic Composition of Atmospheric N2O Over the Last Century S. Ghosh et al. 10.1029/2022JD038281
- Isotope fractionation factors of N2O diffusion R. Well & H. Flessa 10.1002/rcm.3656
- Do increasingly depleted δ15N values of atmospheric N2O indicate a decline in soil N2O reduction? F. Conen & A. Neftel 10.1007/s10533-006-9066-y
- The isotopic composition of atmospheric nitrous oxide observed at the high-altitude research station Jungfraujoch, Switzerland L. Yu et al. 10.5194/acp-20-6495-2020
- Isotopologue ratios of N2O emitted from microcosms with NH4+ fertilized arable soils under conditions favoring nitrification R. Well et al. 10.1016/j.soilbio.2008.06.003
- Development of a Spectroscopic Technique for Continuous Online Monitoring of Oxygen and Site-Specific Nitrogen Isotopic Composition of Atmospheric Nitrous Oxide E. Harris et al. 10.1021/ac403606u
- Effect of local and regional sources on the isotopic composition of nitrous oxide in the tropical free troposphere and tropopause layer P. Croteau et al. 10.1029/2009JD013117
- Vertical gradients of δ15N and δ18O in soil atmospheric N2O—temporal dynamics in a sandy soil J. Van Groenigen et al. 10.1002/rcm.1929
- Mid-infrared laser spectroscopic determination of isotope ratios of N2O at trace levels using wavelength modulation and balanced path length detection H. Waechter & M. Sigrist 10.1007/s00340-007-2576-z
- Isotopic constraints on marine and terrestrial N2O emissions during the last deglaciation A. Schilt et al. 10.1038/nature13971
- Simultaneous stable isotope analysis of methane and nitrous oxide on ice core samples C. Sapart et al. 10.5194/amt-4-2607-2011
- Fractionation factors for stable isotopes of N and O during N2O reduction in soil depend on reaction rate constant B. Vieten et al. 10.1002/rcm.2915
- Exploring the Adsorption Mechanism of N2O on Graphene: A DFT Study on Circum-Coronene for Catalysis, Sensing, and Energy Storage Applications W. Gill & M. Janjua 10.1021/acs.jpca.3c03133
- Constraining N<sub>2</sub>O emissions since 1940 using firn air isotope measurements in both hemispheres M. Prokopiou et al. 10.5194/acp-17-4539-2017
- Stratospheric carbon isotope fractionation and tropospheric histories of CFC-11, CFC-12, and CFC-113 isotopologues M. Thomas et al. 10.5194/acp-21-6857-2021
- Nitrous oxide emissions and nitrogen cycling in managed grassland in Southern Hokkaido, Japan M. Shimizu et al. 10.1111/j.1747-0765.2010.00496.x
- Isotopomeric characterization of N2O produced, consumed, and emitted by automobiles S. Toyoda et al. 10.1002/rcm.3400
- Comparison of measured and EF5‐r‐derived N2O fluxes from a spring‐fed river T. CLOUGH et al. 10.1111/j.1365-2486.2005.01092.x
- Diffusion of 15N-labelled N2O into soil columns: a promising method to examine the fate of N2O in subsoils T. Clough et al. 10.1016/j.soilbio.2005.11.002
- Decadal time series of tropospheric abundance of N2O isotopomers and isotopologues in the Northern Hemisphere obtained by the long‐term observation at Hateruma Island, Japan S. Toyoda et al. 10.1002/jgrd.50221
- Isotopic signatures and concentration profiles of nitrous oxide in a rice‐based ecosystem during the drained crop‐growing season Z. Xiong et al. 10.1029/2008JG000827
- Chlorine isotope composition in chlorofluorocarbons CFC-11, CFC-12 and CFC-113 in firn, stratospheric and tropospheric air S. Allin et al. 10.5194/acp-15-6867-2015
- Changes in the Isotopic Signature of Atmospheric Nitrous Oxide and Its Global Average Source During the Last Three Millennia M. Prokopiou et al. 10.1029/2018JD029008
- Isotopologue signatures of N2O produced by denitrification in soils R. Well & H. Flessa 10.1029/2008JG000804
- Determination of the triple oxygen and carbon isotopic composition of CO2 from atomic ion fragments formed in the ion source of the 253 Ultra high‐resolution isotope ratio mass spectrometer G. Adnew et al. 10.1002/rcm.8478
- Measurement of the 17O‐excess (Δ17O) of tropospheric ozone using a nitrite‐coated filter W. Vicars et al. 10.1002/rcm.6218
- Analytical techniques for measuring nitrous oxide T. Rapson & H. Dacres 10.1016/j.trac.2013.11.004
- Contributions of denitrification and mixing on the distribution of nitrous oxide in the North Pacific H. Yamagishi et al. 10.1029/2004GL021458
- 3‐D Atmospheric Modeling of the Global Budget of N2O and Its Isotopologues for 1980–2019: The Impact of Anthropogenic Emissions Q. Liang et al. 10.1029/2021GB007202
- Contribution of mass‐dependent fractionation to the oxygen isotope anomaly of atmospheric nitrous oxide J. Kaiser et al. 10.1029/2003JD004088
- Probing stratospheric transport and chemistry with new balloon and aircraft observations of the meridional and vertical N<sub>2</sub>O isotope distribution J. Kaiser et al. 10.5194/acp-6-3535-2006
- Extreme <sup>13</sup>C depletion of CCl<sub>2</sub>F<sub>2</sub> in firn air samples from NEEM, Greenland A. Zuiderweg et al. 10.5194/acp-13-599-2013
- Isotope Effects in the Chemistry of Atmospheric Trace Compounds C. Brenninkmeijer et al. 10.1021/cr020644k
- Can N2O stable isotopes and isotopomers be useful tools to characterize sources and microbial pathways of N2O production and consumption in tropical soils? S. Park et al. 10.1029/2009GB003615
- An approach for calibrating laser‐based N2O isotopic analyzers for soil biogeochemistry research E. Stuchiner et al. 10.1002/rcm.8978
4 citations as recorded by crossref.
- N2O + CO reaction over Si- and Se-doped graphenes: An ab initio DFT study R. Gholizadeh & Y. Yu 10.1016/j.apsusc.2015.09.163
- Gas chromatography/isotope‐ratio mass spectrometry method for high‐precision position‐dependent15N and18O measurements of atmospheric nitrous oxide T. Röckmann et al. 10.1002/rcm.1132
- Can Si-embedded boron nitride nanotubes act as a favorable metal-free catalyst for CO oxidation by N2O? M. Esrafili et al. 10.1039/C5RA20180B
- Inverse modeling estimates of the global nitrous oxide surface flux from 1998–2001 A. Hirsch et al. 10.1029/2004GB002443
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