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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-3-1849-2003</article-id>
<title-group>
<article-title>Global modelling of secondary organic aerosol in the troposphere: a sensitivity analysis</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Tsigaridis</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kanakidou</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Environmental Chemical Processes Laboratory, Department of Chemistry, University of Crete, POBox 1470, 71409, Heraklion, Crete, Greece</addr-line>
</aff>
<pub-date pub-type="epub">
<day>31</day>
<month>10</month>
<year>2003</year>
</pub-date>
<volume>3</volume>
<issue>5</issue>
<fpage>1849</fpage>
<lpage>1869</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
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<abstract>
<p>A global 3-dimensional chemistry/transport model able to describe
      O&lt;sub&gt;3&lt;/sub&gt;, NO&lt;sub&gt;x&lt;/sub&gt;, Volatile Organic Compounds (VOC), sulphur and
      NH&lt;sub&gt;3&lt;/sub&gt; chemistry has been extended to simulate the temporal and spatial distribution of primary and secondary carbonaceous aerosols in the troposphere
      focusing on Secondary Organic Aerosol (SOA) formation. A number of global simulations
      have been performed to determine a possible range of annual global SOA production and
      investigate uncertainties associated with the model results. The studied uncertainties in the
      SOA budget have been evaluated to be in decreasing importance: the potentially irreversible
      sticking of the semi-volatile compounds on aerosols, the enthalpy of vaporization of these
      compounds, the partitioning of SOA on non-carbonaceous aerosols, the conversion of
      aerosols from hydrophobic to hydrophilic, the emissions of primary carbonaceous aerosols,
      the chemical fate of the first generation products and finally the activity coefficient of the
      condensable species. The large uncertainties associated with the emissions of VOC and the
      adopted simplification of chemistry have not been investigated in this study. Although not all
      sources of uncertainties have been investigated, according to our calculations, the above
      factors within the experimental range of variations could result to an overall uncertainty of
      about a factor of 20 in the global SOA budget. The global annual SOA production from
      biogenic VOC might range from 2.5 to 44.5 Tg of organic matter per year, whereas that from
      anthropogenic VOC ranges from 0.05 to 2.62 Tg of organic matter per year. These estimates
      can be considered as a lower limit, since partitioning on coarse particles like nitrate, dust or
      sea-salt, together with the partitioning and the dissociation of the semi-volatile products in
      aerosol water has been neglected. Comparison of model results to observations, where
      available, shows a better agreement for the upper budget estimates than for the lower ones.</p>
</abstract>
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</article-meta>
</front>
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