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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-3-1293-2003</article-id>
<title-group>
<article-title>Sensitivity studies of the recent new data on O(&lt;sup&gt;1&lt;/sup&gt;&lt;i&gt;D&lt;/i&gt;) quantum yields in O&lt;sub&gt;3&lt;/sub&gt; Hartley band photolysis in the stratosphere</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Taniguchi</surname>
<given-names>N.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hayashida</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Takahashi</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Matsumi</surname>
<given-names>Y.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Faculty of Science, Nara Women’s University, Kitauoya - Nishimachi, Nara, 630 - 8506, Japan</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Solar - Terrestrial Environment Laboratory, Nagoya University, Honohara 3 - 13, Toyokawa, 442 - 8507, Japan</addr-line>
</aff>
<pub-date pub-type="epub">
<day>04</day>
<month>09</month>
<year>2003</year>
</pub-date>
<volume>3</volume>
<issue>5</issue>
<fpage>1293</fpage>
<lpage>1300</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/3/1293/2003/acp-3-1293-2003.html">This article is available from http://www.atmos-chem-phys.net/3/1293/2003/acp-3-1293-2003.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/3/1293/2003/acp-3-1293-2003.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/3/1293/2003/acp-3-1293-2003.pdf</self-uri>
<abstract>
<p>The production yields of excited oxygen
      O(&lt;sup&gt;1&lt;/sup&gt;&lt;i&gt;D&lt;/i&gt;) atoms from the near ultraviolet O&lt;sub&gt;3&lt;/sub&gt; photolysis
      are essential quantities for atmospheric chemistry calculations because of its importance as
      major sources of hydroxyl (OH) radicals and nitric oxide (NO).  Recently, new
      O(&lt;sup&gt;1&lt;/sup&gt;&lt;i&gt;D&lt;/i&gt;) quantum yields from O&lt;sub&gt;3&lt;/sub&gt; photolysis between 230 and
      305 nm in the Hartley band region were reported, which are almost independent of the photolysis wavelength
      (0.88-0.93) and smaller than NASA/JPL-2000 recommendations (0.95 between 240 and
      300 nm).  In order to assess consequences of the new data of O(&lt;sup&gt;1&lt;/sup&gt;&lt;i&gt;D&lt;/i&gt;) quantum yields on the stratospheric chemistry, the
      changes in stratospheric chemical partitioning and O&lt;sub&gt;3&lt;/sub&gt; concentration are examined using a
      one-dimensional atmospheric model.  Our steady state model simulations for
      40° N in March indicate that the smaller O(&lt;sup&gt;1&lt;/sup&gt;&lt;i&gt;D&lt;/i&gt;) quantum yields result in increases of stratospheric
      O&lt;sub&gt;3&lt;/sub&gt; (up to ~2% in the upper stratosphere), which are attributed to the changes in
      HO&lt;sub&gt;x&lt;/sub&gt;, NO&lt;sub&gt;x&lt;/sub&gt;, and ClO&lt;sub&gt;x&lt;/sub&gt; abundance and their catalyzed
      O&lt;sub&gt;3&lt;/sub&gt; loss rates.</p>
</abstract>
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