Articles | Volume 17, issue 5
https://doi.org/10.5194/acp-17-3453-2017
https://doi.org/10.5194/acp-17-3453-2017
Research article
 | 
10 Mar 2017
Research article |  | 10 Mar 2017

Formation of highly oxygenated low-volatility products from cresol oxidation

Rebecca H. Schwantes, Katherine A. Schilling, Renee C. McVay, Hanna Lignell, Matthew M. Coggon, Xuan Zhang, Paul O. Wennberg, and John H. Seinfeld

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Cited articles

Atkinson, R., Carter, W. P. L., Darnall, K. R., Winer, A. M., and Pitts Jr., J. N.: A smog chamber and modeling study of the gas phase NOx-air photooxidation of toluene and the cresols, Int. J. Chem. Kinet., 12, 779–836, 1980.
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Short summary
Toluene, one of the principle aromatic compounds present in the atmosphere, is oxidized by OH to produce cresol and other products. Here later-generation low-volatility oxygenated products from cresol oxidation by OH are detected in the gas and particle phases. This work identifies a simple and significant mechanism for toluene secondary organic aerosol formation through the cresol pathway. Likely the phenolic pathway of other aromatic compounds is also important for secondary organic aerosol.
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