Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 17, 2613-2629, 2017
http://www.atmos-chem-phys.net/17/2613/2017/
doi:10.5194/acp-17-2613-2017
© Author(s) 2017. This work is distributed
under the Creative Commons Attribution 3.0 License.
Research article
21 Feb 2017
Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland)
Carla Frege1, Federico Bianchi1,2, Ugo Molteni1, Jasmin Tröstl1, Heikki Junninen2, Stephan Henne3, Mikko Sipilä2, Erik Herrmann1, Michel J. Rossi1, Markku Kulmala2, Christopher R. Hoyle1,4, Urs Baltensperger1, and Josef Dommen1 1Laboratory of Atmospheric Chemistry, Paul Scherrer Institute, 5232 Villigen, Switzerland
2Department of Physics, University of Helsinki, 00014 Helsinki, Finland
3Laboratory for Air Pollution/Environmental Technology, Swiss Federal Laboratories for Materials Science and Technology, Empa, 8600 Dübendorf, Switzerland
4WSL (Swiss Federal Institute for Forest, Snow and Landscape Research) Institute for Snow and Avalanche Research SLF, 7260 Davos, Switzerland
Abstract. The ion composition at high altitude (3454 m a.s.l.) was measured with an atmospheric pressure interface time-of-flight mass spectrometer (APi-TOF) during a period of 9 months, from August 2013 to April 2014. The negative mass spectra were dominated by the ions of sulfuric, nitric, malonic, and methanesulfonic acid (MSA) as well as SO5. The most prominent positive ion peaks were from amines. The other cations were mainly organic compounds clustered with a nitrogen-containing ion, which could be either NH4+ or an aminium. Occasionally the positive spectra were characterized by groups of compounds each differing by a methylene group. In the negative spectrum, sulfuric acid was always observed during clear sky conditions following the diurnal cycle of solar irradiation. On many occasions we also saw a high signal of sulfuric acid during nighttime when clusters up to the tetramer were observed. A plausible reason for these events could be evaporation from particles at low relative humidity. A remarkably strong correlation between the signals of SO5 and CH3SO3 was observed for the full measurement period. The presence of these two ions during both the day and the night suggests a non-photochemical channel of formation which is possibly linked to halogen chemistry. Halogenated species, especially Br and IO3, were frequently observed in air masses that originated mainly from the Atlantic Ocean and occasionally from continental areas based on back trajectory analyses. We found I2O5 clustered with an ion, a species that was proposed from laboratory and modeling studies. All halogenated ions exhibited an unexpected diurnal behavior with low values during daytime. New particle formation (NPF) events were observed and characterized by (1) highly oxygenated molecules (HOMs) and low sulfuric acid or (2) ammonia–sulfuric acid clusters. We present characteristic spectra for each of these two event types based on 26 nucleation episodes. The mass spectrum of the ammonia–sulfuric acid nucleation event compares very well with laboratory measurements reported from the CLOUD chamber. A source receptor analysis indicates that NPF events at the Jungfraujoch take place within a restricted period of time of 24–48 h after air masses have had contact with the boundary layer. This time frame appears to be crucial to reach an optimal oxidation state and concentration of organic molecules necessary to facilitate nucleation.

Citation: Frege, C., Bianchi, F., Molteni, U., Tröstl, J., Junninen, H., Henne, S., Sipilä, M., Herrmann, E., Rossi, M. J., Kulmala, M., Hoyle, C. R., Baltensperger, U., and Dommen, J.: Chemical characterization of atmospheric ions at the high altitude research station Jungfraujoch (Switzerland), Atmos. Chem. Phys., 17, 2613-2629, doi:10.5194/acp-17-2613-2017, 2017.
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Short summary
We present measurements of the chemical composition of atmospheric ions at high altitude (3450 m a.s.l.) during a 9-month campaign. We detected remarkably high correlation between methanesulfonic acid (MSA) and SO5. Halogenated species were also detected frequently at this continental location. New-particle formation events occurred via the condensation of highly oxygenated molecules (HOMs) at very low sulfuric acid concentration or, less frequently, due to ammonia–sulfuric acid clusters.
We present measurements of the chemical composition of atmospheric ions at high altitude...
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