Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Atmos. Chem. Phys., 15, 7003-7015, 2015
http://www.atmos-chem-phys.net/15/7003/2015/
doi:10.5194/acp-15-7003-2015
© Author(s) 2015. This work is distributed
under the Creative Commons Attribution 3.0 License.
Research article
29 Jun 2015
Simulation of the isotopic composition of stratospheric water vapour – Part 2: Investigation of HDO / H2O variations
R. Eichinger1, P. Jöckel1, and S. Lossow2 1Deutsches Zentrum für Luft- und Raumfahrt e.V. (DLR), Institut für Physik der Atmosphäre, Münchner Straße 20, Oberpfaffenhofen, 82234 Weßling, Germany
2Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, Hermann-von Helmholtz-Platz 1, 76344 Leopoldshafen, Germany
Abstract. Studying the isotopic composition of water vapour in the lower stratosphere can reveal the driving mechanisms of changes in the stratospheric water vapour budget and therefore help to explain the trends and variations of stratospheric water vapour during recent decades. We equipped a global chemistry climate model with a description of the water isotopologue HDO, comprising its physical and chemical fractionation effects throughout the hydrological cycle. We use this model to improve our understanding of the processes which determine the patterns in the stratospheric water isotope composition and in the water vapour budget itself. The link between the water vapour budget and its isotopic composition in the tropical stratosphere is presented through their correlation in a simulated 21-year time series. The two quantities depend on the same processes; however, they are influenced with different strengths. A sensitivity experiment shows that fractionation effects during the oxidation of methane have a damping effect on the stratospheric tape recorder signal in the water isotope ratio. Moreover, the chemically produced high water isotope ratios overshadow the tape recorder in the upper stratosphere. Investigating the origin of the boreal-summer signal of isotopically enriched water vapour reveals that in-mixing of old stratospheric air from the extratropics and the intrusion of tropospheric water vapour into the stratosphere complement each other in order to create the stratospheric isotope ratio tape recorder signal. For this, the effect of ice lofting in monsoon systems is shown to play a crucial role. Furthermore, we describe a possible pathway of isotopically enriched water vapour through the tropopause into the tropical stratosphere.

Citation: Eichinger, R., Jöckel, P., and Lossow, S.: Simulation of the isotopic composition of stratospheric water vapour – Part 2: Investigation of HDO / H2O variations, Atmos. Chem. Phys., 15, 7003-7015, doi:10.5194/acp-15-7003-2015, 2015.
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