Articles | Volume 15, issue 6
https://doi.org/10.5194/acp-15-3429-2015
https://doi.org/10.5194/acp-15-3429-2015
Research article
 | 
28 Mar 2015
Research article |  | 28 Mar 2015

Total sulfate vs. sulfuric acid monomer concenterations in nucleation studies

K. Neitola, D. Brus, U. Makkonen, M. Sipilä, R. L. Mauldin III, N. Sarnela, T. Jokinen, H. Lihavainen, and M. Kulmala

Related authors

New particle formation, growth and apparent shrinkage at a rural background site in western Saudi Arabia
Simo Hakala, Mansour A. Alghamdi, Pauli Paasonen, Ville Vakkari, Mamdouh I. Khoder, Kimmo Neitola, Lubna Dada, Ahmad S. Abdelmaksoud, Hisham Al-Jeelani, Ibrahim I. Shabbaj, Fahd M. Almehmadi, Anu-Maija Sundström, Heikki Lihavainen, Veli-Matti Kerminen, Jenni Kontkanen, Markku Kulmala, Tareq Hussein, and Antti-Pekka Hyvärinen
Atmos. Chem. Phys., 19, 10537–10555, https://doi.org/10.5194/acp-19-10537-2019,https://doi.org/10.5194/acp-19-10537-2019, 2019
Short summary
Bipolar long-term high temporal resolution broadband measurement system for incoming and outgoing solar UV radiation, and snow UV albedo, at Sodankylä (67°N) and Marambio (64°S)
O. Meinander, A. Aarva, A. Poikonen, A. Kontu, H. Suokanerva, E. Asmi, K. Neitola, E. Rodriguez, R. Sanchez, M. Mei, G. de Leeuw, and E. Kyrö
Geosci. Instrum. Method. Data Syst. Discuss., https://doi.org/10.5194/gi-2015-31,https://doi.org/10.5194/gi-2015-31, 2016
Revised manuscript not accepted
Soot on snow experiments: light-absorbing impurities effect on the natural snowpack
J. Svensson, A. Virkkula, O. Meinander, N. Kivekäs, H.-R. Hannula, O. Järvinen, J. I. Peltoniemi, M. Gritsevich, A. Heikkilä, A. Kontu, A.-P. Hyvärinen, K. Neitola, D. Brus, P. Dagsson-Waldhauserova, K. Anttila, T. Hakala, H. Kaartinen, M. Vehkamäki, G. de Leeuw, and H. Lihavainen
The Cryosphere Discuss., https://doi.org/10.5194/tcd-9-1227-2015,https://doi.org/10.5194/tcd-9-1227-2015, 2015
Revised manuscript not accepted
Short summary
Total sulphate vs. sulphuric acid monomer in nucleation studies: which represents the "true" concentration?
K. Neitola, D. Brus, U. Makkonen, M. Sipilä, R. L. Mauldin III, K. Kyllönen, H. Lihavainen, and M. Kulmala
Atmos. Chem. Phys. Discuss., https://doi.org/10.5194/acpd-13-2313-2013,https://doi.org/10.5194/acpd-13-2313-2013, 2013
Revised manuscript not accepted

Related subject area

Subject: Aerosols | Research Activity: Laboratory Studies | Altitude Range: Troposphere | Science Focus: Physics (physical properties and processes)
Contribution of brown carbon to light absorption in emissions of European residential biomass combustion appliances
Satish Basnet, Anni Hartikainen, Aki Virkkula, Pasi Yli-Pirilä, Miika Kortelainen, Heikki Suhonen, Laura Kilpeläinen, Mika Ihalainen, Sampsa Väätäinen, Juho Louhisalmi, Markus Somero, Jarkko Tissari, Gert Jakobi, Ralf Zimmermann, Antti Kilpeläinen, and Olli Sippula
Atmos. Chem. Phys., 24, 3197–3215, https://doi.org/10.5194/acp-24-3197-2024,https://doi.org/10.5194/acp-24-3197-2024, 2024
Short summary
Measurement report: Water diffusion in single suspended phase-separated aerosols
Yu-Kai Tong, Zhijun Wu, Min Hu, and Anpei Ye
Atmos. Chem. Phys., 24, 2937–2950, https://doi.org/10.5194/acp-24-2937-2024,https://doi.org/10.5194/acp-24-2937-2024, 2024
Short summary
Water activity and surface tension of aqueous ammonium sulfate and D-glucose aerosol nanoparticles
Eugene F. Mikhailov, Sergey S. Vlasenko, and Alexei A. Kiselev
Atmos. Chem. Phys., 24, 2971–2984, https://doi.org/10.5194/acp-24-2971-2024,https://doi.org/10.5194/acp-24-2971-2024, 2024
Short summary
Jet aircraft lubrication oil droplets as contrail ice-forming particles
Joel Ponsonby, Leon King, Benjamin J. Murray, and Marc E. J. Stettler
Atmos. Chem. Phys., 24, 2045–2058, https://doi.org/10.5194/acp-24-2045-2024,https://doi.org/10.5194/acp-24-2045-2024, 2024
Short summary
A study on the influence of inorganic ions, organic carbon and microstructure on the hygroscopic property of soot
Zhanyu Su, Lanxiadi Chen, Yuan Liu, Peng Zhang, Tianzeng Chen, Biwu Chu, Mingjin Tang, Qingxin Ma, and Hong He
Atmos. Chem. Phys., 24, 993–1003, https://doi.org/10.5194/acp-24-993-2024,https://doi.org/10.5194/acp-24-993-2024, 2024
Short summary

Cited articles

Arnold, F.: Ion-induced nucleation of atmospheric water vapor at the mesopause, Planet. Space Sci., 28, 1003–1009, https://doi.org/10.1016/0032-0633(80)90061-6, 1980.
Ayers, G. P., Gillett, R. W., and Gras, J. L.: On the vapor pressure of sulphuric acid, Geophys. Res. Lett., 7, 433–436, 1980.
Ball, S. M., Hanson, D. R., and Eisele, F. L.: Laboratory studies of particle nucleation: Initial results for H2SO4, H2O, and NH3 vapors, J. Geophys. Res., 104, 23709–23718, https://doi.org/10.1029/1999JD900411, 1999.
Benson, D., Young, L.-H., Kameel, F., and Lee, S.-H.: Laboratory-measured nucleation rates of sulfuric acid and water binary homogeneous nucleation from the SO2 + OH reaction, Geophys. Res. Lett., 35, L11801, https://doi.org/10.1029/2008GL033387, 2008.
Benson, D. R., Erupe, M. E., and Lee, S.-H.: Laboratory-measured H2SO4-H2O-NH3 ternary homogeneous nucleation rates: Initial observations, Geophys. Res. Lett., 36, L15818, https://doi.org/10.1029/2009GL038728, 2009.
Download
Short summary
A discrepancy of 2 orders of magnitude was found between the measured sulfuric acid monomer concentration and total sulfate, when measured with independent methods (mass spectrometry and ion chromatography) with the same source of sulphuric acid vapor. The ion chromatography method produces the exact concentrations predicted by empirical equations, and the mass spectrometry method shows significantly lower values. The discrepancy is investigated thoroughly from different points of views.
Altmetrics
Final-revised paper
Preprint