Atmos. Chem. Phys., 13, 7321-7341, 2013
www.atmos-chem-phys.net/13/7321/2013/
doi:10.5194/acp-13-7321-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
Ozone photochemistry in boreal biomass burning plumes
M. Parrington1, P. I. Palmer1, A. C. Lewis2, J. D. Lee2, A. R. Rickard3,4, P. Di Carlo5,6, J. W. Taylor7, J. R. Hopkins2, S. Punjabi8, D. E. Oram9, G. Forster9, E. Aruffo5,6, S. J. Moller2, S. J.-B. Bauguitte10, J. D. Allan7,11, H. Coe7, and R. J. Leigh12
1School of GeoSciences, The University of Edinburgh, Edinburgh, UK
2National Centre for Atmospheric Science, Department of Chemistry, University of York, York, UK
3National Centre for Atmospheric Science, School of Chemistry, University of Leeds, Leeds, UK
4now at the National Centre for Atmospheric Science, Department of Chemistry, University of York, York, UK
5Center of Excellence CETEMPS, University of L'Aquila, L'Aquila, Italy
6Department of Physical and Chemical Sciences, University of L'Aquila, L'Aquila, Italy
7School of Earth, Atmospheric and Environmental Sciences, University of Manchester, Manchester, UK
8Department of Chemistry, University of York, York, UK
9National Centre for Atmospheric Science, School of Environmental Sciences, University of East Anglia, Norwich, UK
10Facility for Airborne Atmospheric Measurements, Bedford, UK
11National Centre for Atmospheric Science, University of Manchester, Manchester, UK
12Department of Physics and Astronomy, University of Leicester, Leicester, UK

Abstract. We present an analysis of ozone (O3) photochemistry observed by aircraft measurements of boreal biomass burning plumes over eastern Canada in the summer of 2011. Measurements of O3 and a number of key chemical species associated with O3 photochemistry, including non-methane hydrocarbons (NMHCs), nitrogen oxides (NOx) and total nitrogen containing species (NOy), were made from the UK FAAM BAe-146 research aircraft as part of the "quantifying the impact of BOReal forest fires on Tropospheric oxidants over the Atlantic using Aircraft and Satellites" (BORTAS) experiment between 12 July and 3 August 2011. The location and timing of the aircraft measurements put BORTAS into a unique position to sample biomass burning plumes from the same source region in Northwestern Ontario with a range of ages. We found that O3 mixing ratios measured in biomass burning plumes were indistinguishable from non-plume measurements, but evaluating them in relationship to measurements of carbon monoxide (CO), total alkyl nitrates (ΣAN) and the surrogate species NOz (= NOy-NOx) revealed that the potential for O3 production increased with plume age. We used NMHC ratios to estimate photochemical ages of the observed biomass burning plumes between 0 and 10 days. The BORTAS measurements provided a wide dynamic range of O3 production in the sampled biomass burning plumes with ΔO3/ΔCO enhancement ratios increasing from 0.020 ± 0.008 ppbv ppbv−1 in plumes with photochemical ages less than 2 days to 0.55 ± 0.29 ppbv ppbv−1 in plumes with photochemical ages greater than 5 days. We found that the main contributing factor to the variability in the ΔO3/ΔCO enhancement ratio was ΔCO in plumes with photochemical ages less than 4 days, and that was a transition to ΔO3 becoming the main contributing factor in plumes with ages greater than 4 days. In comparing O3 mixing ratios with components of the NOy budget, we observed that plumes with ages between 2 and 4 days were characterised by high aerosol loading, relative humidity greater than 40%, and low ozone production efficiency (OPE) of 7.7 ± 3.5 ppbv ppbv−1 relative to ΣAN and 1.6 ± 0.9 ppbv ppbv−1 relative to NOz. In plumes with ages greater than 4 days, OPE increased to 472 ± 28 ppbv ppbv−1 relative to ΣAN and 155 ± 5 ppbv ppbv−1 relative to NOz. From the BORTAS measurements we estimated that aged plumes with low aerosol loading were close to being in photostationary steady state and O3 production in younger plumes was inhibited by high aerosol loading and greater production of ΣAN relative to O3. The BORTAS measurements of O3 photochemistry in boreal biomass burning plumes were found to be consistent with previous summertime aircraft measurements made over the same region during the Arctic Research of the Composition of the Troposphere (ARCTAS-B) in 2008 and Atmospheric Boundary Layer Experiment (ABLE 3B) in 1990.

Citation: Parrington, M., Palmer, P. I., Lewis, A. C., Lee, J. D., Rickard, A. R., Di Carlo, P., Taylor, J. W., Hopkins, J. R., Punjabi, S., Oram, D. E., Forster, G., Aruffo, E., Moller, S. J., Bauguitte, S. J.-B., Allan, J. D., Coe, H., and Leigh, R. J.: Ozone photochemistry in boreal biomass burning plumes, Atmos. Chem. Phys., 13, 7321-7341, doi:10.5194/acp-13-7321-2013, 2013.
 
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