1Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, MI 48105, USA
2Atmospheric and Oceanic Sciences Program, Princeton University/Geophysical Fluid Dynamics Laboratory, 201 Forrestal Road, Princeton, NJ 08540, USA
3D.V. Skobeltsyn Institute of Nuclear Physics, M.V. Lomonosov Moscow State University, Moscow 119234, Russia
Received: 08 Jul 2012 – Discussion started: 09 Aug 2012
Abstract. Fossil fuel black carbon and organic matter (ffBC/OM) are often emitted together with sulfate, which coats the surface of these particles and changes their hygroscopicity. Observational studies at cirrus temperatures (≈−40 °C) show that the hygroscopicity of soot particles can modulate their ice nucleation ability. Here, we implement a scheme for 3 categories of soot (hydrophobic, hydrophilic and hygroscopic) on the basis of laboratory data and specify their ability to act as ice nuclei at mixed-phase temperatures by extrapolating the observations using a published deposition/condensation/immersion freezing parameterization. The new scheme results in significant changes to anthropogenic forcing in mixed-phase clouds. The net forcing in our offline model studies varies from 0.111 to 1.059 W m−2 depending on the ice nucleation capability of hygroscopic soot particles. The total anthropogenic cloud forcing and whole-sky forcing with the new scheme are 0.06 W m−2 and −2.45 W m−2, respectively, but could be more positive (by about 1.17 W m−2) if hygroscopic soot particles are allowed to nucleate ice particles. The change in liquid water path dominates the anthropogenic forcing in mixed-phase clouds.
Revised: 15 Jan 2013 – Accepted: 18 Mar 2013 – Published: 26 Apr 2013
Yun, Y., Penner, J. E., and Popovicheva, O.: The effects of hygroscopicity on ice nucleation of fossil fuel combustion aerosols in mixed-phase clouds, Atmos. Chem. Phys., 13, 4339-4348, doi:10.5194/acp-13-4339-2013, 2013.