1Jet Propulsion Laboratory, California Institute of Technology, CA, USA
2Abbott Lawrence Rotch Professor of Atmospheric and Environmental Chemistry School of Engineering and Applied Science and Department of Earth and Planetary Science Harvard University, Cambridge, MA, USA
3Lawrence Berkeley National Laboratory, Berkeley, CA, USA
4Environment Canada, Toronto, Ontario, Canada
5Department of Physics, University of Toronto, Tonronto, Canada
6Air Quality Research Group, Department of Chemical and Environmental Engineering, Universidad Nacional de Colombia, Bogota, DC 111321, Colombia
7Department of Oceanography, College of Ecology and Environmental Science, Kyungpook National University, Daegu, South Korea
8National Center for Atmospheric Research, Boulder, CO, USA
Received: 18 Jan 2012 – Discussion started: 29 Feb 2012
Abstract. Thermal infrared radiances from the Tropospheric Emission Spectrometer (TES) between 10 and 15 μm contain significant carbon dioxide (CO2) information, however the CO2 signal must be separated from radiative interference from temperature, surface and cloud parameters, water, and other trace gases. Validation requires data sources spanning the range of TES CO2 sensitivity, which is approximately 2.5 to 12 km with peak sensitivity at about 5 km and the range of TES observations in latitude (40° S to 40° N) and time (2005–2011). We therefore characterize Tropospheric Emission Spectrometer (TES) CO2 version 5 biases and errors through comparisons to ocean and land-based aircraft profiles and to the CarbonTracker assimilation system. We compare to ocean profiles from the first three Hiaper Pole-to-Pole Observations (HIPPO) campaigns between 40° S and 40° N with measurements between the surface and 14 km and find that TES CO2 estimates capture the seasonal and latitudinal gradients observed by HIPPO CO2 measurements. Actual errors range from 0.8–1.8 ppm, depending on the campaign and pressure level, and are approximately 1.6–2 times larger than the predicted errors. The bias of TES versus HIPPO is within 1 ppm for all pressures and datasets; however, several of the sub-tropical TES CO2 estimates are lower than expected based on the calculated errors. Comparisons to land aircraft profiles from the United States Southern Great Plains (SGP) Atmospheric Radiation Measurement (ARM) between 2005 and 2011 measured from the surface to 5 km to TES CO2 show good agreement with an overall bias of −0.3 ppm to 0.1 ppm and standard deviations of 0.8 to 1.0 ppm at different pressure levels. Extending the SGP aircraft profiles above 5 km using AIRS or CONTRAIL measurements improves comparisons with TES. Comparisons to CarbonTracker (version CT2011) show a persistent spatially dependent bias pattern and comparisons to SGP show a time-dependent bias of −0.2 ppm yr−1. We also find that the predicted sensitivity of the TES CO2 estimates is too high, which results from using a multi-step retrieval for CO2 and temperature. We find that the averaging kernel in the TES product corrected by a pressure-dependent factor accurately reflects the sensitivity of the TES CO2 product.
Revised: 23 Feb 2013 – Accepted: 25 Feb 2013 – Published: 18 Mar 2013
Kulawik, S. S., Worden, J. R., Wofsy, S. C., Biraud, S. C., Nassar, R., Jones, D. B. A., Olsen, E. T., Jimenez, R., Park, S., Santoni, G. W., Daube, B. C., Pittman, J. V., Stephens, B. B., Kort, E. A., Osterman, G. B., and TES team: Comparison of improved Aura Tropospheric Emission Spectrometer CO2 with HIPPO and SGP aircraft profile measurements, Atmos. Chem. Phys., 13, 3205-3225, doi:10.5194/acp-13-3205-2013, 2013.