Atmos. Chem. Phys., 13, 2531-2539, 2013
www.atmos-chem-phys.net/13/2531/2013/
doi:10.5194/acp-13-2531-2013
© Author(s) 2013. This work is distributed
under the Creative Commons Attribution 3.0 License.
Lifetime and production rate of NOx in the upper stratosphere and lower mesosphere in the polar spring/summer after the solar proton event in October–November 2003
F. Friederich1, T. von Clarmann1, B. Funke2, H. Nieder1, J. Orphal1, M. Sinnhuber1, G. P. Stiller1, and J. M. Wissing3
1Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, Karlsruhe, Germany
2Instituto de Astrofísica de Andalucía, CSIC, Granada, Spain
3FB Physik, University of Osnabrück, Osnabrück, Germany

Abstract. We present altitude-dependent lifetimes of NOx, determined with MIPAS/ENVISAT (the Michelson Interferometer for Passive Atmospheric Sounding/the European Environment Satellite), for the Southern polar region after the solar proton event in October–November 2003. Between 50° S and 90° S and decreasing in altitude they range from about two days at 64 km to about 20 days at 44 km. The lifetimes are controlled by transport, mixing and photochemistry. We infer estimates of dynamical lifetimes by comparison of the observed decay to photochemical lifetimes calculated with the SLIMCAT 3-D Model. Photochemical loss contributes to the observed NOx depletion by 0.1% at 44 km, increasing with altitude to 45% at 64 km.

In addition, we show the correlation of modelled ionization rates and observed NOx densities under consideration of the determined lifetimes of NOx, and calculate altitude-dependent effective production rates of NOx due to ionization. For that we compare ionization rates of the AIMOS data base with the MIPAS measurements from 15 October–31 December 2003. We derive effective NOx-production rates to be applied to the AIMOS ionization rates which range from about 0.2 NOx-molecules per ion pair at 44 km to 0.7 NOx-molecules per ion pair at 62 km. These effective production rates are considerably lower than predicted by box model simulations which could hint at an overestimation of the modelled ionization rates.


Citation: Friederich, F., von Clarmann, T., Funke, B., Nieder, H., Orphal, J., Sinnhuber, M., Stiller, G. P., and Wissing, J. M.: Lifetime and production rate of NOx in the upper stratosphere and lower mesosphere in the polar spring/summer after the solar proton event in October–November 2003, Atmos. Chem. Phys., 13, 2531-2539, doi:10.5194/acp-13-2531-2013, 2013.
 
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