Articles | Volume 13, issue 4
https://doi.org/10.5194/acp-13-1809-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-1809-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
19 Feb 2013
Research article |
| 19 Feb 2013
Chemical ozone losses in Arctic and Antarctic polar winter/spring season derived from SCIAMACHY limb measurements 2002–2009
T. Sonkaew
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
Science Faculty, Lampang Rajabhat University, 119 Lampang-Maeta Rd., Lampang, 52100, Thailand
C. von Savigny
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
now at: Institute of Physics, Ernst-Moritz-Arndt-University of Greifswald, Felix-Hausdorff-Str. 6, 17489 Greifswald, Germany
K.-U. Eichmann
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
M. Weber
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
A. Rozanov
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
H. Bovensmann
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
J. P. Burrows
Institute of Environmental Physics, University of Bremen, Otto-Hahn-Allee 1, 28359 Bremen, Germany
J.-U. Grooß
Institute for Energy and Climate Research – Stratosphere (IEK-7), Forschungszentrum Jülich, Jülich, Germany
Related subject area
Subject: Gases | Research Activity: Remote Sensing | Altitude Range: Stratosphere | Science Focus: Physics (physical properties and processes)
Total ozone trends at three northern high-latitude stations
Case study on the influence of synoptic-scale processes on the paired H2O–O3 distribution in the UTLS across a North Atlantic jet stream
Dynamical linear modeling estimates of long-term ozone trends from homogenized Dobson Umkehr profiles at Arosa/Davos, Switzerland
Zonally asymmetric influences of the quasi-biennial oscillation on stratospheric ozone
Stratospheric ozone trends for 1984–2021 in the SAGE II–OSIRIS–SAGE III/ISS composite dataset
Analyzing ozone variations and uncertainties at high latitudes during sudden stratospheric warming events using MERRA-2
Impacts of tropical cyclones on the thermodynamic conditions in the tropical tropopause layer observed by A-Train satellites
Investigation and amelioration of long-term instrumental drifts in water vapor and nitrous oxide measurements from the Aura Microwave Limb Sounder (MLS) and their implications for studies of variability and trends
3-D tomographic observations of Rossby wave breaking over the North Atlantic during the WISE aircraft campaign in 2017
Is there a direct solar proton impact on lower-stratospheric ozone?
Small-scale variability of stratospheric ozone during the sudden stratospheric warming 2018/2019 observed at Ny-Ålesund, Svalbard
Seasonal stratospheric ozone trends over 2000–2018 derived from several merged data sets
Evidence for energetic particle precipitation and quasi-biennial oscillation modulations of the Antarctic NO2 springtime stratospheric column from OMI observations
Stratospheric ozone trends for 1985–2018: sensitivity to recent large variability
Interannual variations of water vapor in the tropical upper troposphere and the lower and middle stratosphere and their connections to ENSO and QBO
Ground-based ozone profiles over central Europe: incorporating anomalous observations into the analysis of stratospheric ozone trends
Response of stratospheric water vapor and ozone to the unusual timing of El Niño and the QBO disruption in 2015–2016
Assessing stratospheric transport in the CMAM30 simulations using ACE-FTS measurements
Water vapour and methane coupling in the stratosphere observed using SCIAMACHY solar occultation measurements
Evidence for a continuous decline in lower stratospheric ozone offsetting ozone layer recovery
MLS measurements of stratospheric hydrogen cyanide during the 2015–2016 El Niño event
What controls the seasonal cycle of columnar methane observed by GOSAT over different regions in India?
An “island” in the stratosphere – on the enhanced annual variation of water vapour in the middle and upper stratosphere in the southern tropics and subtropics
CCl4 distribution derived from MIPAS ESA v7 data: intercomparisons, trend, and lifetime estimation
Results from the validation campaign of the ozone radiometer GROMOS-C at the NDACC station of Réunion island
Trend analysis of the 20-year time series of stratospheric ozone profiles observed by the GROMOS microwave radiometer at Bern
Is there a solar signal in lower stratospheric water vapour?
Trajectory mapping of middle atmospheric water vapor by a mini network of NDACC instruments
Sunset–sunrise difference in solar occultation ozone measurements (SAGE II, HALOE, and ACE–FTS) and its relationship to tidal vertical winds
Tracing the second stage of ozone recovery in the Antarctic ozone-hole with a "big data" approach to multivariate regressions
Total ozone trends and variability during 1979–2012 from merged data sets of various satellites
Trends in stratospheric ozone derived from merged SAGE II and Odin-OSIRIS satellite observations
Evaluation of the use of five laboratory-determined ozone absorption cross sections in Brewer and Dobson retrieval algorithms
Decadal-scale responses in middle and upper stratospheric ozone from SAGE II version 7 data
Validation of ozone monthly zonal mean profiles obtained from the version 8.6 Solar Backscatter Ultraviolet algorithm
Stratospheric lifetimes of CFC-12, CCl4, CH4, CH3Cl and N2O from measurements made by the Atmospheric Chemistry Experiment-Fourier Transform Spectrometer (ACE-FTS)
Volcanic SO2 fluxes derived from satellite data: a survey using OMI, GOME-2, IASI and MODIS
Stratospheric ozone interannual variability (1995–2011) as observed by lidar and satellite at Mauna Loa Observatory, HI and Table Mountain Facility, CA
Development of a climate record of tropospheric and stratospheric column ozone from satellite remote sensing: evidence of an early recovery of global stratospheric ozone
A-train CALIOP and MLS observations of early winter Antarctic polar stratospheric clouds and nitric acid in 2008
Ozone zonal asymmetry and planetary wave characterization during Antarctic spring
A global climatology of tropospheric and stratospheric ozone derived from Aura OMI and MLS measurements
Sulphur dioxide as a volcanic ash proxy during the April–May 2010 eruption of Eyjafjallajökull Volcano, Iceland
Analysis of HCl and ClO time series in the upper stratosphere using satellite data sets
Retrieval of atmospheric parameters from GOMOS data
Multi sensor reanalysis of total ozone
GOMOS data characterisation and error estimation
Technical Note: Time-dependent limb-darkening calibration for solar occultation instruments
Simultaneous measurements of OClO, NO2 and O3 in the Arctic polar vortex by the GOMOS instrument
Leonie Bernet, Tove Svendby, Georg Hansen, Yvan Orsolini, Arne Dahlback, Florence Goutail, Andrea Pazmiño, Boyan Petkov, and Arve Kylling
Atmos. Chem. Phys., 23, 4165–4184, https://doi.org/10.5194/acp-23-4165-2023, https://doi.org/10.5194/acp-23-4165-2023, 2023
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After the severe destruction of the ozone layer, the amount of ozone in the stratosphere is expected to increase again. At northern high latitudes, however, such a recovery has not been detected yet. To assess ozone changes in that region, we analyse the amount of ozone above specific locations (total ozone) measured at three stations in Norway. We found that total ozone increases significantly at two Arctic stations, which may be an indication of ozone recovery at northern high latitudes.
Andreas Schäfler, Michael Sprenger, Heini Wernli, Andreas Fix, and Martin Wirth
Atmos. Chem. Phys., 23, 999–1018, https://doi.org/10.5194/acp-23-999-2023, https://doi.org/10.5194/acp-23-999-2023, 2023
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In this study, airborne lidar profile measurements of H2O and O3 across a midlatitude jet stream are combined with analyses in tracer–trace space and backward trajectories. We highlight that transport and mixing processes in the history of the observed air masses are governed by interacting tropospheric weather systems on synoptic timescales. We show that these weather systems play a key role in the high variability of the paired H2O and O3 distributions near the tropopause.
Eliane Maillard Barras, Alexander Haefele, René Stübi, Achille Jouberton, Herbert Schill, Irina Petropavlovskikh, Koji Miyagawa, Martin Stanek, and Lucien Froidevaux
Atmos. Chem. Phys., 22, 14283–14302, https://doi.org/10.5194/acp-22-14283-2022, https://doi.org/10.5194/acp-22-14283-2022, 2022
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Intercomparisons of three Dobson and three Brewer spectrophotometers at Arosa/Davos, Switzerland, are used for the homogenization of the longest Umkehr ozone profiles time series worldwide. Dynamic linear modeling (DLM) reveals a significant positive trend after 2004 in the upper stratosphere, a persistent negative trend between 25 and 30 km in the middle stratosphere, and a negative trend at 20 km in the lower stratosphere, with different levels of significance depending on the dataset.
Wuke Wang, Jin Hong, Ming Shangguan, Hongyue Wang, Wei Jiang, and Shuyun Zhao
Atmos. Chem. Phys., 22, 13695–13711, https://doi.org/10.5194/acp-22-13695-2022, https://doi.org/10.5194/acp-22-13695-2022, 2022
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The ozone layer protects the life on the Earth by absorbing the ultraviolet (UV) radiation. Beside the long-term trend, there are strong interannual fluctuations in stratospheric ozone. The quasi-biennial oscillation (QBO) is an important interannual mode in the stratosphere. We show some new zonally asymmetric features of its impacts on stratospheric ozone using satellite data, ERA5 reanalysis, and model simulations, which is helpful for predicting the regional UV radiation at the surface.
Kristof Bognar, Susann Tegtmeier, Adam Bourassa, Chris Roth, Taran Warnock, Daniel Zawada, and Doug Degenstein
Atmos. Chem. Phys., 22, 9553–9569, https://doi.org/10.5194/acp-22-9553-2022, https://doi.org/10.5194/acp-22-9553-2022, 2022
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We quantify recent changes in stratospheric ozone (outside the polar regions) using a combination of three satellite datasets. We find that upper stratospheric ozone have increased significantly since 2000, although the recovery shows an unexpected pause in the Northern Hemisphere. Combined with the likely decrease in ozone in the lower stratosphere, this presents an interesting challenge for predicting the future of the ozone layer.
Shima Bahramvash Shams, Von P. Walden, James W. Hannigan, William J. Randel, Irina V. Petropavlovskikh, Amy H. Butler, and Alvaro de la Cámara
Atmos. Chem. Phys., 22, 5435–5458, https://doi.org/10.5194/acp-22-5435-2022, https://doi.org/10.5194/acp-22-5435-2022, 2022
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Large-scale atmospheric circulation has a strong influence on ozone in the Arctic, and certain anomalous dynamical events, such as sudden stratospheric warmings, cause dramatic alterations of the large-scale circulation. A reanalysis model is evaluated and then used to investigate the impact of sudden stratospheric warmings on mid-atmospheric ozone. Results show that the position of the cold jet stream over the Arctic before these events influences the variability of ozone.
Jing Feng and Yi Huang
Atmos. Chem. Phys., 21, 15493–15518, https://doi.org/10.5194/acp-21-15493-2021, https://doi.org/10.5194/acp-21-15493-2021, 2021
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This study conducts a comprehensive analysis of thermodynamic fields above tropical cyclones. Using a synergistic retrieval method, we develop the first infrared hyperspectra-based dataset of collocated temperature and water vapor profiles above deep convective clouds. It discloses the unique impacts of convective overshoots on the tropical tropopause layer (TTL). Challenging conventional views, our study suggests that convective hydration may be limited by the radiative balance above cyclones.
Nathaniel J. Livesey, William G. Read, Lucien Froidevaux, Alyn Lambert, Michelle L. Santee, Michael J. Schwartz, Luis F. Millán, Robert F. Jarnot, Paul A. Wagner, Dale F. Hurst, Kaley A. Walker, Patrick E. Sheese, and Gerald E. Nedoluha
Atmos. Chem. Phys., 21, 15409–15430, https://doi.org/10.5194/acp-21-15409-2021, https://doi.org/10.5194/acp-21-15409-2021, 2021
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The Microwave Limb Sounder (MLS), an instrument on NASA's Aura mission launched in 2004, measures vertical profiles of the temperature and composition of Earth's "middle atmosphere" (the region from ~12 to ~100 km altitude). We describe how, among the 16 trace gases measured by MLS, the measurements of water vapor (H2O) and nitrous oxide (N2O) have started to drift since ~2010. The paper also discusses the origins of this drift and work to ameliorate it in a new version of the MLS dataset.
Lukas Krasauskas, Jörn Ungermann, Peter Preusse, Felix Friedl-Vallon, Andreas Zahn, Helmut Ziereis, Christian Rolf, Felix Plöger, Paul Konopka, Bärbel Vogel, and Martin Riese
Atmos. Chem. Phys., 21, 10249–10272, https://doi.org/10.5194/acp-21-10249-2021, https://doi.org/10.5194/acp-21-10249-2021, 2021
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A Rossby wave (RW) breaking event was observed over the North Atlantic during the WISE measurement campaign in October 2017. Infrared limb sounding measurements of trace gases in the lower stratosphere, including high-resolution 3-D tomographic reconstruction, revealed complex spatial structures in stratospheric tracers near the polar jet related to previous RW breaking events. Backward-trajectory analysis and tracer correlations were used to study mixing and stratosphere–troposphere exchange.
Jia Jia, Antti Kero, Niilo Kalakoski, Monika E. Szeląg, and Pekka T. Verronen
Atmos. Chem. Phys., 20, 14969–14982, https://doi.org/10.5194/acp-20-14969-2020, https://doi.org/10.5194/acp-20-14969-2020, 2020
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Recent studies have reported up to a 10 % average decrease of lower stratospheric ozone at 20 km altitude following solar proton events (SPEs). Our study uses 49 events that occurred after the launch of Aura MLS (July 2004–now) and 177 events that occurred in the WACCM-D simulation period (Jan 1989–Dec 2012) to evaluate ozone changes following SPEs. The statistical and case-by-case studies show no solid evidence of SPE's direct impact on the lower stratospheric ozone.
Franziska Schranz, Jonas Hagen, Gunter Stober, Klemens Hocke, Axel Murk, and Niklaus Kämpfer
Atmos. Chem. Phys., 20, 10791–10806, https://doi.org/10.5194/acp-20-10791-2020, https://doi.org/10.5194/acp-20-10791-2020, 2020
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We measured middle-atmospheric ozone, water vapour and zonal and meridional wind with two ground-based microwave radiometers which are located at Ny-Alesund, Svalbard, in the Arctic. In this article we present measurements of the small-scale horizontal ozone gradients during winter 2018/2019. We found a distinct seasonal variation of the ozone gradients which is linked to the planetary wave activity. We further present the signatures of the SSW in the ozone, water vapour and wind measurements.
Monika E. Szeląg, Viktoria F. Sofieva, Doug Degenstein, Chris Roth, Sean Davis, and Lucien Froidevaux
Atmos. Chem. Phys., 20, 7035–7047, https://doi.org/10.5194/acp-20-7035-2020, https://doi.org/10.5194/acp-20-7035-2020, 2020
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We analyze seasonal dependence of stratospheric ozone trends over 2000–2018. We demonstrate that the mid-latitude upper stratospheric ozone recovery maximizes during local winters and equinoxes. In the tropics, a very strong seasonal dependence of ozone trends is observed at all altitudes. We found hemispheric asymmetry of summertime ozone trend patterns below 35 km. The seasonal dependence of ozone trends and stratospheric temperature trends shows a clear inter-relation of the trend patterns.
Emily M. Gordon, Annika Seppälä, and Johanna Tamminen
Atmos. Chem. Phys., 20, 6259–6271, https://doi.org/10.5194/acp-20-6259-2020, https://doi.org/10.5194/acp-20-6259-2020, 2020
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The Sun constantly emits high-energy charged particles that produce the ozone destroying chemical NOx in the polar atmosphere. NOx is transported to the stratosphere, where the ozone layer is. Satellite observations show that the NOx gases remain in the atmosphere longer than previously reported. This is influenced by the strength of atmospheric large-scale dynamics, suggesting that there are specific times when this type of solar influence on the Antarctic atmosphere becomes more pronounced.
William T. Ball, Justin Alsing, Johannes Staehelin, Sean M. Davis, Lucien Froidevaux, and Thomas Peter
Atmos. Chem. Phys., 19, 12731–12748, https://doi.org/10.5194/acp-19-12731-2019, https://doi.org/10.5194/acp-19-12731-2019, 2019
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We analyse long-term stratospheric ozone (60° S–60° N) trends over the 1985–2018 period. Previous work has suggested that lower stratosphere ozone declined over 1998–2016. We demonstrate that a large ozone upsurge in 2017 is likely related to QBO variability, but that lower stratospheric ozone trends likely remain lower in 2018 than in 1998. Tropical stratospheric ozone (30° S–30° N) shows highly probable decreases in both the lower stratosphere and in the integrated stratospheric ozone layer.
Edward W. Tian, Hui Su, Baijun Tian, and Jonathan H. Jiang
Atmos. Chem. Phys., 19, 9913–9926, https://doi.org/10.5194/acp-19-9913-2019, https://doi.org/10.5194/acp-19-9913-2019, 2019
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We study the interannual (2–7-year) water vapor variations in the tropical upper troposphere and the lower and middle stratosphere and their connections to El Nino–Southern Oscillation (ENSO) and quasi-biennial oscillation (QBO) using the Aura Microwave Limb Sounder (MLS) data and time-lag regression analysis and composite analysis. We found that ENSO is more important in the upper troposphere and near the tropopause, while QBO is more important in the lower and middle stratosphere.
Leonie Bernet, Thomas von Clarmann, Sophie Godin-Beekmann, Gérard Ancellet, Eliane Maillard Barras, René Stübi, Wolfgang Steinbrecht, Niklaus Kämpfer, and Klemens Hocke
Atmos. Chem. Phys., 19, 4289–4309, https://doi.org/10.5194/acp-19-4289-2019, https://doi.org/10.5194/acp-19-4289-2019, 2019
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After severe ozone depletion, upper stratospheric ozone has started to recover in recent years. However, stratospheric ozone trends from various data sets still show differences. To partly explain such differences, we investigate how the trends are affected by different factors, for example, anomalies in the data. We show how trend estimates can be improved by considering such anomalies and present updated stratospheric ozone trends from ground data measured in central Europe.
Mohamadou Diallo, Martin Riese, Thomas Birner, Paul Konopka, Rolf Müller, Michaela I. Hegglin, Michelle L. Santee, Mark Baldwin, Bernard Legras, and Felix Ploeger
Atmos. Chem. Phys., 18, 13055–13073, https://doi.org/10.5194/acp-18-13055-2018, https://doi.org/10.5194/acp-18-13055-2018, 2018
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The unprecedented timing of an El Niño event aligned with the disrupted QBO in 2015–2016 caused a perturbation to the stratospheric circulation, affecting trace gases. This paper resolves the puzzling response of the lower stratospheric water vapor by showing that the QBO disruption reversed the lower stratosphere moistening triggered by the alignment of the El Niño event with a westerly QBO in early boreal winter.
Felicia Kolonjari, David A. Plummer, Kaley A. Walker, Chris D. Boone, James W. Elkins, Michaela I. Hegglin, Gloria L. Manney, Fred L. Moore, Diane Pendlebury, Eric A. Ray, Karen H. Rosenlof, and Gabriele P. Stiller
Atmos. Chem. Phys., 18, 6801–6828, https://doi.org/10.5194/acp-18-6801-2018, https://doi.org/10.5194/acp-18-6801-2018, 2018
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We used satellite observations and model simulations of CFC-11, CFC-12, and N2O to investigate stratospheric transport, which is important for predicting the recovery of the ozone layer and future climate. We found that sampling can impact results and that the model consistently overestimates concentrations of these gases in the lower stratosphere, consistent with a too rapid Brewer–Dobson circulation. An issue with mixing in the tropical lower stratosphere in June–July–August was also found.
Stefan Noël, Katja Weigel, Klaus Bramstedt, Alexei Rozanov, Mark Weber, Heinrich Bovensmann, and John P. Burrows
Atmos. Chem. Phys., 18, 4463–4476, https://doi.org/10.5194/acp-18-4463-2018, https://doi.org/10.5194/acp-18-4463-2018, 2018
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The combined analysis of stratospheric methane and water vapour data derived from SCIAMACHY solar occultation measurements shows the expected anti-correlation and a clear temporal variation related to waves in equatorial zonal winds. Above about 20 km most of the additional water vapour is attributed to the oxidation of methane. The SCIAMACHY data confirm that at lower altitudes water vapour and methane are transported from the tropics to higher latitudes.
William T. Ball, Justin Alsing, Daniel J. Mortlock, Johannes Staehelin, Joanna D. Haigh, Thomas Peter, Fiona Tummon, Rene Stübi, Andrea Stenke, John Anderson, Adam Bourassa, Sean M. Davis, Doug Degenstein, Stacey Frith, Lucien Froidevaux, Chris Roth, Viktoria Sofieva, Ray Wang, Jeannette Wild, Pengfei Yu, Jerald R. Ziemke, and Eugene V. Rozanov
Atmos. Chem. Phys., 18, 1379–1394, https://doi.org/10.5194/acp-18-1379-2018, https://doi.org/10.5194/acp-18-1379-2018, 2018
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Using a robust analysis, with artefact-corrected ozone data, we confirm upper stratospheric ozone is recovering following the Montreal Protocol, but that lower stratospheric ozone (50° S–50° N) has continued to decrease since 1998, and the ozone layer as a whole (60° S–60° N) may be lower today than in 1998. No change in total column ozone may be due to increasing tropospheric ozone. State-of-the-art models do not reproduce lower stratospheric ozone decreases.
Hugh C. Pumphrey, Norbert Glatthor, Peter F. Bernath, Christopher D. Boone, James W. Hannigan, Ivan Ortega, Nathaniel J. Livesey, and William G. Read
Atmos. Chem. Phys., 18, 691–703, https://doi.org/10.5194/acp-18-691-2018, https://doi.org/10.5194/acp-18-691-2018, 2018
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The Microwave Limb Sounder (MLS) is a satellite instrument that has been measuring the amount of various gases in the atmosphere since 2004. In late 2015 and 2016 it observed unusual amounts of hydrogen cyanide (HCN), a gas produced when vegetation is burned. We compare the MLS observations to similar observations from other instruments. The excess HCN is shown to come from fires in Indonesia. There are more fires than usual in 2015–16 due to a drought caused by an El Niño event.
Naveen Chandra, Sachiko Hayashida, Tazu Saeki, and Prabir K. Patra
Atmos. Chem. Phys., 17, 12633–12643, https://doi.org/10.5194/acp-17-12633-2017, https://doi.org/10.5194/acp-17-12633-2017, 2017
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This study shows difficulties in interpreting columnar dry-air mole fractions of methane (XCH4) for surface emissions of CH4 over the South Asia region, without separating the role of chemistry and transport. Using a chemistry-transport model, we suggest that a link between surface emissions and higher levels of XCH4 is not always valid in this region of complex monsoonal meteorology, although there is often a fair correlation between the seasonal variations in surface emissions and XCH4.
Stefan Lossow, Hella Garny, and Patrick Jöckel
Atmos. Chem. Phys., 17, 11521–11539, https://doi.org/10.5194/acp-17-11521-2017, https://doi.org/10.5194/acp-17-11521-2017, 2017
Massimo Valeri, Flavio Barbara, Chris Boone, Simone Ceccherini, Marco Gai, Guido Maucher, Piera Raspollini, Marco Ridolfi, Luca Sgheri, Gerald Wetzel, and Nicola Zoppetti
Atmos. Chem. Phys., 17, 10143–10162, https://doi.org/10.5194/acp-17-10143-2017, https://doi.org/10.5194/acp-17-10143-2017, 2017
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Atmospheric emissions of CCl4 are regulated by the Montreal Protocol due to its role as a strong ozone-depleting substance. The molecule is the subject of recent increased interest as a consequence of the discrepancy between atmospheric observations and reported production and consumption. We use MIPAS/ENVISAT data (2002–2012) to estimate CCl4 trends and lifetime. At 50 hPa we find a decline of about 30–35 % per decade. In the lower stratosphere our lifetime estimate is 47 (39–61) years.
Susana Fernandez, Rolf Rüfenacht, Niklaus Kämpfer, Thierry Portafaix, Françoise Posny, and Guillaume Payen
Atmos. Chem. Phys., 16, 7531–7543, https://doi.org/10.5194/acp-16-7531-2016, https://doi.org/10.5194/acp-16-7531-2016, 2016
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We present a new ground based microwave radiometer for campaigns, GROMOS-C. It measures the vertical distribution of ozone in the middle atmosphere by observing spectra at 110.836 GHz. The paper presents a validation campaign that took place on La Réunion Island. The ozone retrieved profiles are validated against ozone profiles from the Microwave Limb Sounder, the ozone lidar located in the observatory, ozone profiles from weekly radiosondes and with ECMWF model data.
L. Moreira, K. Hocke, E. Eckert, T. von Clarmann, and N. Kämpfer
Atmos. Chem. Phys., 15, 10999–11009, https://doi.org/10.5194/acp-15-10999-2015, https://doi.org/10.5194/acp-15-10999-2015, 2015
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GROMOS (GROund-based Millimeter-wave Ozone Spectrometer) has provided ozone profiles for the NDACC (Network for the Detection of Atmospheric Composition Change) at Bern since 1994. We performed a trend analysis of our 20-year time series of stratospheric ozone profiles with a multilinear parametric trend estimation method. With our estimated ozone trends we are able to support the stratospheric ozone turnaround, besides a statistically significant negative trend in the lower mesosphere.
T. Schieferdecker, S. Lossow, G. P. Stiller, and T. von Clarmann
Atmos. Chem. Phys., 15, 9851–9863, https://doi.org/10.5194/acp-15-9851-2015, https://doi.org/10.5194/acp-15-9851-2015, 2015
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A merged data set of HALOE and MIPAS lower stratospheric water vapour has been constructed. Multivariate linear regression shows that the merged time series can best be explained if a proxy for the 11-year solar cycle is considered. The amplitude of the solar cycle signal in water vapour is slightly higher than that which can be explained by the known solar cycle variation of cold-point temperatures.
M. Lainer, N. Kämpfer, B. Tschanz, G. E. Nedoluha, S. Ka, and J. J. Oh
Atmos. Chem. Phys., 15, 9711–9730, https://doi.org/10.5194/acp-15-9711-2015, https://doi.org/10.5194/acp-15-9711-2015, 2015
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We use water vapor profiles from ground-based microwave radiometers at five locations distributed over the Northern Hemisphere and operated in the frame of NDACC (Network for the Detection of Atmospheric Composition Change) to generate hemispheric water vapor maps based on the so-called trajectory mapping technique. The novelty is to show that a mini network of instruments is capable of providing information about the hemispheric distribution of water vapor under most conditions.
T. Sakazaki, M. Shiotani, M. Suzuki, D. Kinnison, J. M. Zawodny, M. McHugh, and K. A. Walker
Atmos. Chem. Phys., 15, 829–843, https://doi.org/10.5194/acp-15-829-2015, https://doi.org/10.5194/acp-15-829-2015, 2015
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The solar occultation measurements measure the atmosphere at sunrise (SR) and sunset (SS). It has been reported that there is a significant difference in the observed amount of stratospheric ozone between SR and SS. This study first revealed that this difference can be largely explained by diurnal variations in ozone, particularly those caused by vertical transport by the atmospheric tidal winds. Our results would be helpful for the construction of combined data sets from SR and SS profiles.
A. T. J. de Laat, R. J. van der A, and M. van Weele
Atmos. Chem. Phys., 15, 79–97, https://doi.org/10.5194/acp-15-79-2015, https://doi.org/10.5194/acp-15-79-2015, 2015
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Recent research suggests the Antarctic ozone hole has started to shrink due to decreasing ozone-depleting substances. Because it could be questioned how robust these results are, we provide an assessment of uncertainties in both the underlying ozone observational records and the detection-attribution method. Although Antarctic ozone concentrations are definitely increasing slowly, the formal identification of recovery is not yet justified, although this will likely become possible this decade.
W. Chehade, M. Weber, and J. P. Burrows
Atmos. Chem. Phys., 14, 7059–7074, https://doi.org/10.5194/acp-14-7059-2014, https://doi.org/10.5194/acp-14-7059-2014, 2014
A. E. Bourassa, D. A. Degenstein, W. J. Randel, J. M. Zawodny, E. Kyrölä, C. A. McLinden, C. E. Sioris, and C. Z. Roth
Atmos. Chem. Phys., 14, 6983–6994, https://doi.org/10.5194/acp-14-6983-2014, https://doi.org/10.5194/acp-14-6983-2014, 2014
A. Redondas, R. Evans, R. Stuebi, U. Köhler, and M. Weber
Atmos. Chem. Phys., 14, 1635–1648, https://doi.org/10.5194/acp-14-1635-2014, https://doi.org/10.5194/acp-14-1635-2014, 2014
E. E. Remsberg
Atmos. Chem. Phys., 14, 1039–1053, https://doi.org/10.5194/acp-14-1039-2014, https://doi.org/10.5194/acp-14-1039-2014, 2014
N. A. Kramarova, S. M. Frith, P. K. Bhartia, R. D. McPeters, S. L. Taylor, B. L. Fisher, G. J. Labow, and M. T. DeLand
Atmos. Chem. Phys., 13, 6887–6905, https://doi.org/10.5194/acp-13-6887-2013, https://doi.org/10.5194/acp-13-6887-2013, 2013
A. T. Brown, C. M. Volk, M. R. Schoeberl, C. D. Boone, and P. F. Bernath
Atmos. Chem. Phys., 13, 6921–6950, https://doi.org/10.5194/acp-13-6921-2013, https://doi.org/10.5194/acp-13-6921-2013, 2013
N. Theys, R. Campion, L. Clarisse, H. Brenot, J. van Gent, B. Dils, S. Corradini, L. Merucci, P.-F. Coheur, M. Van Roozendael, D. Hurtmans, C. Clerbaux, S. Tait, and F. Ferrucci
Atmos. Chem. Phys., 13, 5945–5968, https://doi.org/10.5194/acp-13-5945-2013, https://doi.org/10.5194/acp-13-5945-2013, 2013
G. Kirgis, T. Leblanc, I. S. McDermid, and T. D. Walsh
Atmos. Chem. Phys., 13, 5033–5047, https://doi.org/10.5194/acp-13-5033-2013, https://doi.org/10.5194/acp-13-5033-2013, 2013
J. R. Ziemke and S. Chandra
Atmos. Chem. Phys., 12, 5737–5753, https://doi.org/10.5194/acp-12-5737-2012, https://doi.org/10.5194/acp-12-5737-2012, 2012
A. Lambert, M. L. Santee, D. L. Wu, and J. H. Chae
Atmos. Chem. Phys., 12, 2899–2931, https://doi.org/10.5194/acp-12-2899-2012, https://doi.org/10.5194/acp-12-2899-2012, 2012
I. Ialongo, V. Sofieva, N. Kalakoski, J. Tamminen, and E. Kyrölä
Atmos. Chem. Phys., 12, 2603–2614, https://doi.org/10.5194/acp-12-2603-2012, https://doi.org/10.5194/acp-12-2603-2012, 2012
J. R. Ziemke, S. Chandra, G. J. Labow, P. K. Bhartia, L. Froidevaux, and J. C. Witte
Atmos. Chem. Phys., 11, 9237–9251, https://doi.org/10.5194/acp-11-9237-2011, https://doi.org/10.5194/acp-11-9237-2011, 2011
H. E. Thomas and A. J. Prata
Atmos. Chem. Phys., 11, 6871–6880, https://doi.org/10.5194/acp-11-6871-2011, https://doi.org/10.5194/acp-11-6871-2011, 2011
A. Jones, J. Urban, D. P. Murtagh, C. Sanchez, K. A. Walker, N. J. Livesey, L. Froidevaux, and M. L. Santee
Atmos. Chem. Phys., 11, 5321–5333, https://doi.org/10.5194/acp-11-5321-2011, https://doi.org/10.5194/acp-11-5321-2011, 2011
E. Kyrölä, J. Tamminen, V. Sofieva, J. L. Bertaux, A. Hauchecorne, F. Dalaudier, D. Fussen, F. Vanhellemont, O. Fanton d'Andon, G. Barrot, M. Guirlet, A. Mangin, L. Blanot, T. Fehr, L. Saavedra de Miguel, and R. Fraisse
Atmos. Chem. Phys., 10, 11881–11903, https://doi.org/10.5194/acp-10-11881-2010, https://doi.org/10.5194/acp-10-11881-2010, 2010
R. J. van der A, M. A. F. Allaart, and H. J. Eskes
Atmos. Chem. Phys., 10, 11277–11294, https://doi.org/10.5194/acp-10-11277-2010, https://doi.org/10.5194/acp-10-11277-2010, 2010
J. Tamminen, E. Kyrölä, V. F. Sofieva, M. Laine, J.-L. Bertaux, A. Hauchecorne, F. Dalaudier, D. Fussen, F. Vanhellemont, O. Fanton-d'Andon, G. Barrot, A. Mangin, M. Guirlet, L. Blanot, T. Fehr, L. Saavedra de Miguel, and R. Fraisse
Atmos. Chem. Phys., 10, 9505–9519, https://doi.org/10.5194/acp-10-9505-2010, https://doi.org/10.5194/acp-10-9505-2010, 2010
S. P. Burton, L. W. Thomason, and J. M. Zawodny
Atmos. Chem. Phys., 10, 1–8, https://doi.org/10.5194/acp-10-1-2010, https://doi.org/10.5194/acp-10-1-2010, 2010
C. Tétard, D. Fussen, C. Bingen, N. Capouillez, E. Dekemper, N. Loodts, N. Mateshvili, F. Vanhellemont, E. Kyrölä, J. Tamminen, V. Sofieva, A. Hauchecorne, F. Dalaudier, J.-L. Bertaux, O. Fanton d'Andon, G. Barrot, M. Guirlet, T. Fehr, and L. Saavedra
Atmos. Chem. Phys., 9, 7857–7866, https://doi.org/10.5194/acp-9-7857-2009, https://doi.org/10.5194/acp-9-7857-2009, 2009
Cited articles
Baldwin, M. P., Gray, L. J., Dunkerton, T. J., Hamilton, K., Haynes, P. H., Randel, W. J., Holton, J. R., Alexander, M. J., Hirota, I., Horinouchi, T., Jones, D. B. A., Kinnersley, J. S., Marquardt, C., Sato, K., and Takahashi, M.: The quasibiennial oscillation, Rev. Geophys., 39, 179–229, 2001.
Baldwin, M., P., Hirooka, T., O'Neill, A., and Yoden, S.: Major stratospheric warming in the southern hemisphere in 2002: Dynamical aspects of the ozone hole split, SPARC newsletter, No. 20, SPARC Office, Toronto, ON, Canada, 24–26, 2003.
Becker, G., Müller, R., McKenna, D. S., Rex, M., Carslaw, K., and Oelhaf, H.: Ozone loss rates in the Arctic stratosphere in the winter 1994/1995: Model simulations underestimate results of the Match analysis, J. Geophys. Res., 105, 15175–15184, 2000.
Bodeker, G. E., Shiona, H., and Eskes, H.: Indicators of Antarctic ozone depletion, Atmos. Chem. Phys., 5, 2603–2615, https://doi.org/10.5194/acp-5-2603-2005, 2005.
Bovensmann, H., Burrows, J. P., Buchwitz, M., Frerick, J., Noël, S., Rozanov, V. V., Chance, K. V., and Goede, A. P. H.: SCIAMACHY: Mission objectives and measurement modes, J. Atmos. Sci., 56, 127–150, 1999.
Braathen, G. O., Rummkainen, M., Kyrö, E., Schmidt, U., Dahlback, A., Jorgensen, T. S., Fabian, R., Rudagov, V. V., Gil, M., and Borchers, R.: Temporal development of ozone within the Arctic vortex during the winter of 1991/1992, Geophys. Res. Lett., 21, 1407–1410, 1994.
Brewer, A. W.: Evidence for a world circulation provided by the measurements of helium and water vapour distribution in the stratosphere, Q. J. Roy. Meteor. Soc., 75, 351–363, https://doi.org/10.1002/qj.49707532603, 1949.
Burrows, J. P., Hölzle, E., Goede, A. P. H., Visser, H., and Fricke, W.: SCIAMACHY – Scanning Imaging Absorption Spectrometer for Atmospheric Chartography, Acta Astronautica, 35, 7, 445–451, 1995.
Camp, C. D. and Tung, K.-K.: The influence of the solar cycle and QBO on the late-winter stratospheric polar vortex, J. Atmos. Sci, 64, 1267–1283, 2007.
Chen, H. Y., Lien, C. Y., Lin, W. Y., Lee, Y. T., and Lin, J. J.: UV absorption cross sections of ClOOCl are consistent with ozone degradation models, Science, 324, 781–784, https://doi.org/10.1126/science.1171305, 2009.
Chipperfield, M. P., Lee, A. M., and Pyle, J. A.: Model calculations of ozone depletion in the Arctic polar vortex for 1991/92 to 1994/95, Geophys. Res. Lett., 23, 559–562, 1996.
Christensen, T., Knudsen, B. M., Streibel, M., Andersen, S. B., Benesova, A., Braathen, G., Claude, H., Davies, J., De Backer, H., Dier, H., Dorokhov, V., Gerding, M., Gil, M., Henchoz, B., Kelder, H., Kivi, R., Kyrö, E., Litynska, Z., Moore, D., Peters, G., Skrivankova, P., Stübi, R., Turunen, T., Vaughan, G., Viatte, P., Vik, A. F., von der Gathen, P., and Zaitcev, I.: Vortex-averaged Arctic ozone depletion in the winter 2002/2003, Atmos. Chem. Phys., 5, 131–138, https://doi.org/10.5194/acp-5-131-2005, 2005.
National Weather Service, Climate Prediction Center: Stratosphere: Global temperature time series, available at: http://www.cpc.noaa.gov/products/stratosphere/temperature/, (last access: 2 February 2013), 2009.
Deniel, C., Bevilaqua, R. M., Pommereau, J. P., and Lefèvre, F.: Arctic chemical ozone depletion during the 1994/1995 winter deduced from POAM II satellite observations and the REPROBUS three-dimensional model, J. Geophys. Res., 103, 19231–19244, 1998.
Dobson, G. M. B., Kimball, H. H., and Kidson, E.: Observations of the amount of ozone in the Earth's atmosphere, and its relation to other geophysical conditions. Part IV, Proc. R. Soc. Lond. A, 129, 411–433, 1930.
Dufour, G., Nassar, R., Boone, C. D., Skelton, R., Walker, K. A., Bernath, P. F., Rinsland, C. P., Semeniuk, K., Jin, J. J., McConnell, J. C., and Manney, G. L.: Partitioning between the inorganic chlorine reservoirs HCl and ClONO2 during the Arctic winter 2005 from the ACE-FTS, Atmos. Chem. Phys., 6, 2355–2366, https://doi.org/10.5194/acp-6-2355-2006, 2006.
Eichmann, K.-U., Weber, M., Bramstedt, K., and Burrows, J. P.: Ozone depletion in the NH winter/spring 1999/2000 as measured by GOME on ERS-2, J. Geophys. Res., 107, 8280, https://doi.org/10.1029/2001JD001148, 2002.
El Amraoui, L., Semane, N., Peuch, V.-H., and Santee M. L.: Investigation of dynamical processes in the polar stratospheric vortex during the unusually cold winter 2004/2005, Geophys. Res. Lett., 35, L03803, https://doi.org/10.1029/2007GL031251, 2008.
EU: European research in the stratosphere 1996-2000, chap. 3.5, 112–117, EUR 19867, Brussels, 2001.
Farman, J. C., Gardiner, B. G., and Shanklin, J. D.: Large losses of total ozone in Antarctica reveal seasonal ClOx/NOx interaction, Nature, 315, 207–210, 1985.
Feng, W., Chipperfield, M. P., Davies, S., von der Gathen, P., Kyrö, E., Volk, C. M., Ulanovsky, A., and Belyaev, G.: Large chemical ozone loss in 2004/2005 Arctic winter/spring, Geophys. Res. Lett., 34, L09803, https://doi.org/10.1029/2006GL029098, 2007
Feng, W., Chipperfield, M. P., Davies, S., Sen, B., Toon, G., Blavier, J. F., Webster, C. R., Volk, C. M., Ulanovsky, A., Ravegnani, F., von der Gathen, P., Jost, H., Richard, E. C., and Claude, H.: Three-dimensional model study of the Arctic ozone loss in 2002/2003 and comparison with 1999/2000 and 2003/2004, Atmos. Chem. Phys., 5, 139–152, https://doi.org/10.5194/acp-5-139-2005, 2005.
Feng, W., Chipperfield, M. P., Davies, S., Mann, G. W., Carslaw, K. S., Dhomse, S., Harvey, L., Randall, C., and Santee, M. L.: Modelling the effect of denitrification on polar ozone depletion for Arctic winter 2004/2005, Atmos. Chem. Phys., 11, 6559–6573, https://doi.org/10.5194/acp-11-6559-2011, 2011.
Frie{ß}, U., Kreher, K., Johnston, P. V., and Platt, U.: Ground-Based DOAS Measurements of Stratospheric Trace Gases at Two Antarctic Stations during the 2002 Ozone Hole Period, J. Atmos. Sci., 62, 765–777, 2005.
Fussen, D. and López-Puertas, M: Summary on upper atmosphere, Atmospheric Science Conference, Barcelona, Spain, 7–11 September, 2009.
Geer, A. J., Lahoz, W. A., Jackson, D. R., Cariolle, D., and McCormack, J. P.: Evaluation of linear ozone photochemistry parametrizations in a stratosphere-troposphere data assimilation system, Atmos. Chem. Phys., 7, 939–959, https://doi.org/10.5194/acp-7-939-2007, 2007.
Goutail, F., Harris, N. R. P., Kilbane-Dawe, I., and Amanatidis, G. T.: Ozone loss: the global picture, Proc. European Ozone Meeting, Schliersee, Germany, 1997.
Goutail, F., Pommereau, J.-P., Lefèvre, F., van Roozendael, M., Andersen, S. B., Kåstad Høiskar, B.-A., Dorokhov, V., Kyrö, E., Chipperfield, M. P., and Feng, W.: Early unusual ozone loss during the Arctic winter 2002/2003 compared to other winters, Atmos. Chem. Phys., 5, 665–677, https://doi.org/10.5194/acp-5-665-2005, 2005.
Grooß, J.-U. and Müller, R.: The impact of mid-latitude intrusions into the polar vortex on ozone loss estimates, Atmos. Chem. Phys., 3, 395–402, https://doi.org/10.5194/acp-3-395-2003, 2003.
Grooß, J.-U., Günther, G., Müller, R., Konopka, P., Bausch, S., Schlager, H., Voigt, C., Volk, C. M., and Toon, G. C.: Simulation of denitrification and ozone loss for the Arctic winter 2002/2003, Atmos. Chem. Phys., 5, 1437–1448, https://doi.org/10.5194/acp-5-1437-2005, 2005.
Groo{ß}, J.-U. and M{ü}ller, R.: Simulation of ozone loss in Arctic winter 2004/2005, Geophys. Res. Lett., 34, L05804, https://doi.org/10.1029/2006GL028901, 2007.
Grooß, J.-U., Müller, R., Konopka, P., Steinhorst, H.-M., Engel, A., Möbius, T., and Volk, C. M.: The impact of transport across the polar vortex edge on Match ozone loss estimates, Atmos. Chem. Phys., 8, 565–578, https://doi.org/10.5194/acp-8-565-2008, 2008.
Guirlet, M., Chipperfield, M. P., Pyle, J. A., Goutail, F., Pommereau, J. P., and Kyrö, E.: Modeled Arctic ozone depletion in winter 1997/1998 and comparison with previous winters, J. Geophys. Res., 105, 22185–22200, 2000.
Harris, N. R. P., Rex, M., Goutail, F., Knudsen, B. M., Manney, G. L., Müller, R., and von der Gathen, P.: Comparison of empirically derived ozone losses in the Arctic vortex, J. Geophys. Res., 107, 8264, https://doi.org/10.1029/2001JD000482, 2002.
Haynes, P. H., Marks, C. J., McIntyre, M. E., Shepherd, T. G., and Shine, K. P.: On the "downward control" of extratropical diabatic circulations by eddy-induced mean zonal forces, J. Atmos. Sci., 48, 651–678, 1991.
Holton, J. R. and Tan, H. C.: The influence of the equatorial QBO in the global circulation at 50mb, J. Atmos. Sci., 37, 2200–2208, 1980.
Holton J. R., Haynes, P. H., McIntyre, M. E., Douglass, A. R., Rood, R. B., and Pfister, L.: Stratosphere-troposphere exchange, Rev. Geophys., 33, 403–439, 1995.
Holton, J. R. and Alexander, M. J.: The role of waves in the transport circulation of the middle atmosphere, in: Atmospheric Sciences Across the Stratopause, edited by: Siskind, D. E., Eckermann, S. D., and Summers, M. E., Geophysical Monograph Series No. 123, AGU, 21–35, 2000.
Hoogen, R., Rozanov, V. V., and Burrows, J. P.: Ozone profiles from GOME satellite data: Algorithm description and first validation, J. Geophys. Res., 104, 8263–8280, 1999.
Hoppel, K., Bevilacqua, R., Allen, D., Nedoluha, G., and Randall C.: POAM III observations of the anomalous 2002 Antarctic ozone hole, Geophys. Res. Lett., 30, 1394, https://doi.org/10.1029/2003GL016899, 2003.
Hoppel, K. W., Baker, N. L., Coy, L., Eckermann, S. D., McCormack, J. P., Nedoluha, G. E., and Siskind, D. E.: Assimilation of stratospheric and mesospheric temperatures from MLS and SABER into a global NWP model, Atmos. Chem. Phys., 8, 6103-6116, https://doi.org/10.5194/acp-8-6103-2008, 2008.
IPCC/TEAP: Special report on safeguarding the ozone layer and the global climate system, Cambridge University Press, Cambridge, United Kingdom, New York, USA, 2005.
Jackson, D. R. and Orsolini, Y. J.: Estimation of Arctic ozone loss in winter 2004/05 based on assimilation of EOS MLS and SBUV/2 observations, Q. J. Roy. Meteor. Soc., 134, 1833–1841, 2008.
Jin, J. J., Semeniuk, K., Manney, G.L., Jonsson, A. I., Beagley, S. R., McConnell, J. C., Dufour, G., Nassar, R., Walker, K. A., Boone, C. D., Bernath, P. F, Rinsland, C. P., Urban, J., Murtagh, D., and Petelina, S. V.: Severe Arctic ozone loss in the winter 2004/2005: observations from ACE-FTS, Geophys. Res. Lett., 33, L15801, https://doi.org/10.1029/2006GL026752, 2006.
Jones, A., Urban, J., Murtagh, D. P., Eriksson, P., Brohede, S., Haley, C., Degenstein, D., Bourassa, A., von Savigny, C., Sonkaew, T., Rozanov, A., Bovensmann, H., and Burrows, J.: Evolution of stratospheric ozone and water vapour time series studied with satellite measurements, Atmos. Chem. Phys., 9, 6055–6075, https://doi.org/10.5194/acp-9-6055-2009, 2009.
Jucks, K. W. and Salawitch, R. J.: Future changes in upper stratospheric ozone, in: atmospheric science across the stratopause, edited by: Siskind, D. E., Eckermann, S. D., and Summers, M. E., Geophys. Mono., 123, AGU, 241–255, 2000.
Knudsen, B. M., Larsen, N., Mikkelsen, I. S., Morcrette, J.-J., Braathen, G. O., Kyrö, E., Fast, H., Gernandt, H., Kanzawa, H., Nakane, H., Dorokhov, V., Yushkov, V., Hansen, G., Gil, M., and Shearman, R. J.: Ozone depletion in and below the Arctic vortex for 1997, Geophys. Res. Lett., 25, 627–630, 1998.
Konopka, P., Groo{ß}, J.-U., Hoppel, K. W., Steinhorst, H.-M., and M{ü}ller, R.: Mixing and chemical ozone loss during and after the Antarctic polar vortex major warming in September 2002, J. Atmos. Sci., 62, 848–859, https://doi.org/10.1175/JAS-3329.1, 2005.
Konopka, P., Engel, A., Funke, B., M{ü}ller, R., Groo{ß}, J.-U., G{ü}nther, G., Wetter, T., Stiller, G., von Clarmann, T., Glatthor, N., Oelhaf, H., Wetzel, G., L{ó}pez-Puertas, M., Pirre, M., Huret, N., and Riese, M.: Ozone loss driven by nitrogen oxides and triggered by stratospheric warmings can outweigh the effect of halogens, J. Geophys. Res., 112, D5105, https://doi.org/10.1029/2006JD007064, 2007.
Kushner, P. L. and Polvani, L. M.: A very large, spontaneous stratospheric sudden warming in a simple AGCM: A prototype for the southern hemisphere warming of 2002?, J. Atmos. Sci., 62, 890–897, 2004.
Kuttippurath, J., Godin-Beekmann, S., Lefévre, F., and Goutail, F.: Spatial, temporal, and vertical variability of polar stratospheric ozone loss in the Arctic winters 2004/2005–2009/2010, Atmos. Chem. Phys., 10, 9915–9930, https://doi.org/10.5194/acp-10-9915-2010, 2010a.
Kuttippurath, J., Goutail, F., Pommereau, J.-P., Lef{é}vre, F., Roscoe, H. K., Pazmino, A., Feng, W., Chipperfield, M. P., and Godin-Beekmann, S.: Estimation of Antarctic ozone loss from ground-based total column measurements, Atmos. Chem. Phys., 10, 6569–6581, https://doi.org/10.5194/acp-10-6569-2010, 2010b.
Labitzke, K.: Sunspots, the QBO, and the stratospheric temperature in the north polar-region, Geophys. Res. Lett., 14, 535–537, 1987.
Labitzke, K. and van Loon, H.: Associations between the 11-year solar-cycle, the QBO and the atmosphere. Part I: The troposphere and stratosphere in the northern hemisphere in winter, J. Atmos. Terr. Phys., 50, 197–206, 1988.
Labitzke, K. and Kunze, M.: On the remarkable Arctic winter in 2008/2009, J. Geophys. Res., 114, D00I02, https://doi.org/10.1029/2009JD012273, 2009.
Lait, L. R.: An alternative form for potential vorticity, J. Atmos. Sci., 51, 1754–1759, 1994.
Manney, G. L., Krüger, K., Sabutis, J. L., Sena, S. A., and Pawson, S.: The remarkable 2003–2004 winter and other recent warm winters in the Arctic stratosphere since the late 1990s, J. Geophys. Res., 110, D04107, https://doi.org/10.1029/2004JD005367, 2005a.
Manney, G. L., Sabutis, J. L., Allen, D. R., Lahoz, W. A., Scaife, A. A., Randall, C. E., Pawson, S., Naujokat, B., and Swinbank, R.: Simulations of dynamics and transport during the September 2002 Antarctic major warming, J. Geophys. Res., 62, 690–707, https://doi.org/10.1175/JAS-3313.1, 2005b.
Manney,G. L., Santee, M. L., Froidevaux, L., Hoppel, K., Livesey, N. J., and Waters, J. W.: EOS MLS observations of ozone loss in the 2004–2005 Arctic winter, Geophys. Res. Lett., 33, L04802, https://doi.org/10.1029/2005GL024494, 2006.
Manney, G. L., Schwartz, M. J., Krüger, K., Santee, M. L., Pawson, S., Lee, J. N., Daffer, W. H., Fuller, R. A., and Livesey, J.: Aura Microwave Limb Sounder Observations of dynamics and transport during the record-breaking 2009 Arctic stratospheric major warming, Geophys. Res. Lett., 36, L12815, https://doi.org/10.1029/2009GL038586, 2009.
Müller, R., and Günther, G.: A generalized form of Lait's modified potential vorticity, J. Atmos. Sci., 60, 2229–2237, 2003.
Nash, E. R., Newman, P. A., Rosenfield, J. E., and Schoeberl, M. R.: An objective determination of the polar vortex using Ertel's potential vorticity, J. Geophys. Res., 101, 9471–9478, 1996.
Newchurch, M. J., Yang, E.-S., Cunnold, D. M., Reinsel, G. C., Zawodny, J. M., and Russell III, J. M.: Evidence for slowdown in stratospheric ozone loss: First stage of ozone recovery, J. Geophys. Res., 108, 4507, https://doi.org/10.1029/2003JD003471, 2003.
Newman, P. A. and Nash, E. R.: The unusual southern hemisphere stratosphere winter of 2002, J. Atmos. Sci., 62, 614–628, 2005.
Randel, W. J., Wu, F., Russell III, J. M., Roche, A., and Waters, J. W.: Seasonal cycles and QBO variations in stratospheric CH4 and H2O observed in UARS HALOE data, J. Atmos. Sci., 55, 163–185, 1998.
Remsberg, E. E., Marshall, B. T., Garcia-Comas, M., Krueger, D., Lingenfelser, G. S., Martin-Torres, J., Mlynczak, M. G., Russell, J. M., Smith, A. K., Zhao, Y., Brown, C., Gordley, L. L., Lopez-Gonzalez, M. J., Lopez-Puertas, M., She, C.-Y., Taylor, M. J., and Thompson, R. E.: Assessment of the quality of the Version 1.07 temperature-versus-pressure profiles of the middle atmosphere from TIMED/SABER, J. Geophys. Res.-Atmos., 113, D17101, https://doi.org/10.1029/2008JD010013, 2008.
Rex, M., von der Gathen, P., Braathen, G. O., Harris, N. R. P., Reimer, E., Beck, A., Alfier, R., Krüger-Carstensen, R., Chipperfield, M., De Backer, H., Balis, D., O'Connor, F., Dier, H., Dorokhov, V., Fast, H., Gamma, A., Gil, M., Kyrö, E., Litynska, Z., Mikkelsen, I. S., Molyneux, M., Murphy, G., Reid, S. J., Rummukainen, M., and Zerefos, D.: Chemical ozone loss in the Arctic winter 1994/1995 as determined by the Match technique, J. Atmos. Chem., 32, 35–59, 1999.
Rex, M., Salawitch, R. J., Harris, N. R. P., von der Gathen, P., Braathen, G. O., Schulz, A., Deckelmann, H., Chipperfield, M., Sinnhuber, B.-M., Reimer, E., Alfier, R., Bevilacqua, R., Hoppel, K., Fromm, M., Lumpe, J., Küllmann, H., Kleinböhl, A., Bremer, H., von König, M., Künzi, K., Toohey, D., Vömel, H., Richard, E., Aikin, K., Jost, H., Greenblatt, J. B., Loewenstein, M., Podolske, J. R., Webster, C. R., Flesch, G. J., Scott, D. C., Herman, R. L., Elkins, J. W., Ray, E. A., Moore, F. L., Hurst, D. F., Romashkin, P., Toon, G. C., Sen, B., Margitan, J. J., Wennberg, P., Neuber, R., Allart, M., Bojkov, B. R., Claude, H., Davies, J., Davies, W., De Backer, H., Dier, H., Dorokhov, V., Fast, H., Kondo, Y., Kyrö, E., Litynska, Z., Mikkelsen, I. S., Molyneux, M. J., Moran, E., Nagai, T., Nakane, H., Parrondo, C., Ravegnani, F., Skrivankova, P., Viatte, P., and Yushkov, V.: Chemical depletion of Arctic ozone in winter 1999/2000, J. Geophys. Res., 107, 8276, https://doi.org/10.1029/2001JD000533, 2002.
Rex, M., Salawitch, R. J., Santee, M. L., Waters, J. W., Hoppel, K., and Bevilaqua, R.: On the unexplained stratospheric ozone losses during cold Arctic Januaries, Geophys. Res. Lett., 30, 1008, https://doi.org/10.1029/2002GL016008, 2003.
Rex, M., Salawitch, R. J., von der Gathen, P., Harris, N. R. P., Chipperfield, M. P., and Naujokat, B.: Arctic ozone loss and climate change, Geophys. Res. Lett., 31, L04116, https://doi.org/10.1029/2003GL018844, 2004.
Rex, M., Salawitch, R. J., Deckelmann, H., von der Gathen, P., Harris, N. R. P., Chipperfield, M. P., Naujokat, B., Reimer, E., Allaart, M., Andersen, S. B., Bevilacqua, R., Braathen, G. O., Claude, H., Davies, J., De Backer, H., Dier, H., Dorokhov, V., Fast, H., Gerding, M., Godin-Beekmann, S., Hoppel, K., Johnson, B., Kyr{ö}, E., Litynska, Z., Moore, D., Nakane, H., Parrondo, M. C., Risley, A. D., Skrivankova, P., St{ü}bi, R., Viatte, P., Yushkov, V., and Zerefos, C.: Arctic winter 2005: Implications for stratospheric ozone loss and climate change, Geophys. Res. Lett., 33, L23808, https://doi.org/10.1029/2006GL026731, 2006.
Ricaud, P., Lef{è}vre, F., Berthet, G., Murtagh, D., Llewellyn, E. J., M{é}gie, G., Kyr{ö}l{ä}, E., Leppelmeier, G. W., Auvinen, H., Boone, C., Brohede, S., Degenstein, D. A., de La No{ë}, J., Dupuy, E., El Amraoui, L., Eriksson, P., Evans, W. F. J., Frisk, U., Gattinger, R. L., Girod, F., Haley, C. S., Hassinen, S., Hauchecorne, A., Jimenez, C., Kyr{ö}, E., Lauti{é}, N., Le Flochmo{ë}n, E., Lloyd, N. D., McConnell, J. C., McDade, I. C., Nordh, L., Olberg, M., Pazmino, A., Petelina, S. V., Sandqvist, A., Sepp{ä}l{ä}, A., Sioris, C. E., Solheim, B. H., Stegman, J., Strong, K., Taalas, P. Urban, J., von Savigny, C., von Scheele, F., and Witt, G.: Polar vortex evolution during the 2002 Antarctic major warming as observed by the Odin satellite, J. Geophys. Res., 110, D05302, https://doi.org/10.1029/2004JD005018, 2005.
Richter, A., Wittrock, F., Weber, M., Beirle, S., K{ü}hl, S., Platt, U., Wagner, T., Wilms-Grabe, W., and Burrows, J. P.: GOME Observations of Stratospheric Trace Gas Distributions during the Splitting Vortex Event in the Antarctic Winter of 2002. Part I: Measurements, J. Atmos. Sci., 62, 778–785, https://doi.org/10.1175/JAS-3325.1, 2005.
Rosenlof, K. H. and Holton, J. R.: Estimates of the stratospheric residual circulation using the downward control principle, J. Geophys. Res., 98, 10465–10479, 1993.
Rosenlof, K. H.: Seasonal cycle of the residual mean meridional circulation in the stratosphere, J. Geophys. Res., 100, 5173–5191, 1995.
Rösevall, J. D., Murtagh, D. P., and Urban, J.: Ozone depletion in the 2006/2007 Arctic winter, Geophys. Res. Lett., 34, L21809, https://doi.org/10.1029/2007GL030620, 2007a.
Rösevall, J. D., Murtagh, D. P., Urban, J., and Jones, A. K.: A study of polar ozone depletion based on sequential assimilation of satellite data from the ENVISAT/MIPAS and Odin/SMR instruments, Atmos. Chem. Phys., 7, 899–911, https://doi.org/10.5194/acp-7-899-2007, 2007b.
R{ö}sevall, J. D., Murtagh, D. P., Urban, J., Feng, W., Eriksson, P., and Brohede, S.: A study of ozone depletion in the 2004/2005 Arctic winter based on data from Odin/SMR and Aura/MLS, J. Geophys. Res., 113, D13301, https://doi.org/10.1029/2007JD009560, 2008.
Rozanov, A., Rozanov, V., Buchwitz, M., Kokhanovsky, A., and Burrows, J. P.: SCIATRAN 2.0 – A new radiative transfer model for geophysical applications in the 175–2400 nm spectral region, Adv. Space Res., 36, 1015–1019, 2005.
Rozanov, A.: {SCIATRAN 2.X}: {R}adiative transfer model and retrieval software package, available at: http://www.iup.physik.uni-bremen.de/sciatran, (last access: 2 February 2013), 2008.
Sathishkumar, S., Sridharan, S., and Jocobi, Ch.: Dynamical response of low-latitude middle atmosphere to major sudden stratospheric warming events, J. Atmos. Sol.-Terr. Phys., 71, 857–865, 2009.
Shi, Q., Jayne, J. T., Kolb, C. E., Worsnop, D. R., and Davidovits, P:, Kinetic model for reaction of ClONO2 with H2O and HCl and HOCl with HCl in sulfuric acid solutions, J. Geophys. Res., 106, 4259–24274, 2001.
Shine, K. P.: On the cause of the relative greenhouse strength of gases such as the halocarbons, J. Atmos. Sci., 48, 1513–1518, 1991.
Singleton, C. S., Randall, C. E., Chipperfield, M. P., Davies, S., Feng, W., Bevilacqua, R. M., Hoppel, K. W., Fromm, M. D., Manney, G. L., and Harvey, V. L.: 2002–2003 Arctic ozone loss deduced from POAM III satellite observations and the SLIMCAT chemical transport model, Atmos. Chem. Phys., 5, 597–609, https://doi.org/10.5194/acp-5-597-2005, 2005.
Singleton, C. S., Randall, C. E., Harvey, V. L., Chipperfield, M. P., Feng, W., Manney, G. L., Froidevaux, L., Boone, C. D., Bernath, P. F., Walker, K. A., McElroy, C. T. and Hoppel, K. W.: Quantifying Arctic ozone loss during the 2004-2005 winter using satellite observations and a chemical transport model, J. Geophys. Res.-Atmos., 112, D7304, https://doi.org/10.1029/2006JD007463, 2007.
Sinnhuber, B.-M., Langer, J., Klein, U., Raffalski, U., K{ü}nzi, K., and Schrems, O.:, Ground based millimeter-wave observations of Arctic ozone depletion during winter and spring of 1996/97, Geophys. Res. Lett., 25, 3327–3330, 1998.
Siskind, D. E., Froidevaux, L., Russell, J. M., and Lean, J.: Implications of upper stratospheric trace constituent changes observed by HALOE for O3 and ClO from 1992 to 1995, Geophys. Res. Lett., 25, 3513–3516, 1998.
Solomon, S.: Stratospheric ozone depletion: A review of concepts and history, Rev. Geophys., 37, 275–316, 1999.
Solomon S., Portmann, R. W., Sasaki, T., Hofmann, D. J., and Thompson, D. W. J.: Four decades of ozonesonde measurements over Antarctica, J. Geophys. Res., 110, D21311, https://doi.org/10.1029/2005JD005917, 2005.
Solomon, S., Portmann, R. W., and Thompson, D. W. J.: Contrasts between Antarctic and Arctic ozone depletion, P. Natl. Acad. Sci., 104, 445–449, 2007.
Sonkaew, T., Rozanov, V. V., von Savigny, C., Rozanov, A., Bovensmann, H., and Burrows, J. P.: Cloud sensitivity studies for stratospheric and lower mesospheric ozone profile retrievals from measurements of limb-scattered solar radiation, Atmos. Meas. Tech., 2, 653–678, https://doi.org/10.5194/amt-2-653-2009, 2009.
Steinbrecht, W., Claude, H., Schönenborn, F., McDermid, I. S., Leblanc, T., Godin, S., Keckhut, P., van Gijsel, A., Swart, D. P. J., Bodeker, G., Parrish, A., Boyd, I., Kämpfer, N., Hocke, C., Stolarski, R. S., Frith, S. M., Thomason, L. W., Remsberg, E. E., von Savigny, C., Rozanov, A., and Burrows, J. P.: Ozone and temperature trends in the upper stratosphere at five stations of the Network for the Detection of Atmospheric Composition Change, Int. J. Remote Sens., 30, 3875–3886, 2009.
Stolarski, R. S., McPeters, R. D., and Newman, P. A.: The ozone hole of 2002 as measured by TOMS, J. Atmos. Sci., 62(3), 716–720, 2005.
Streibel, M., Rex, M., von der Gathen, P., Lehmann, R., Harris, N. R. P., Braathen, G. O., Reimer, E., Deckelmann, H., Chipperfield, M., Millard, G., Allaart, M., Andersen, S. B., Claude, H., Davies, J., De Backer, H., Dier, H., Dorokov, V., Fast, H., Gerding, M., Kyrö, E., Litynska, Z., Moore, D., Moran, E., Nagai, T., Nakane, H., Parrondo, C., Skrivankova, P., Stübi, R., Vaughan, G., Viatte, P., and Yushkov, V.: Chemical ozone loss in the Arctic winter 2002/2003 determined with Match, Atmos. Chem. Phys., 6, 2783–2792, https://doi.org/10.5194/acp-6-2783-2006, 2006.
Swinbank, R. and O'Neill, A.: A stratosphere-troposphere data assimilation system, Mon. Weather Rev., 122, 686–702, 1994.
Tsvetkova, N. D., Yushkov, V. A., Luk'yanov, A. N., Dorokhov, V. M., and Nakane, H.: Record-breaking chemical destruction of ozone in the arctic during the winter of 2004/2005, Izvestiya Atmos. Ocean. Phys., 43, 592–598, 2007.
Tilmes, S., Müller, R, Groo{ß}, J.-U., and Russell, J. M.: Ozone loss and chlorine activation in the Arctic winters 1991–2003 derived with the tracer-tracer correlations, Atmos. Chem. Phys., 4, 2181–2213, https://doi.org/10.5194/acp-4-2181-2004, 2004.
Tilmes, S., Müller, R., Groo{ß}, J.-U., Spang, R., Sugita, T., Nakajima, H., and Sasano, Y.: Chemical ozone loss and related processes in the Antarctic winter 2003 based on Improved Limb Atmospheric Spectrometer (ILAS)–II observations, J. Geophys. Res., 111, D11S12, https://doi.org/10.1029/2005JD006260, 2006.
Tilmes, S., Kinnison, D. E., Garcia, R. R., M{ü}ller, R., Sassi, F., Marsh, D. R., and Boville, B. A.: Evaluation of heterogeneous processes in the polar lower stratosphere in the Whole Atmosphere Community Climate Model, J. Geophys. Res., 112, D24301, https://doi.org/10.1029/2006JD008334, 2007.
von Clarmann, T., Glatthor, N., Ruhnke, R., Stiller, G. P., Kirner, O., Reddmann, T., Höpfner, M., Kellmann, S., Kouker, W., Linden, A., and Funke, B.: HOCl chemistry in the Antarctic Stratospheric Vortex 2002, as observed with the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS), Atmos. Chem. Phys., 9, 1817–1829, https://doi.org/10.5194/acp-9-1817-2009, 2009.
von Hobe, M., Ulanovsky, A., Volk, C. M., Groo{ß}, J.-U., Tilmes, S., Konopka, P., Günther, G., Werner, A., Spelten, N., Shur, G., Yushkov, V., Ravegnani, F., Schiller, C., Müller, R., and Stroh F.: Severe ozone depletion in the cold Arctic winter 2004–05, Geophys. Res. Lett., 33, L17815, https://doi.org/10.1029/2006GL026945, 2006.
von Hobe, M., Stroh, F., Beckers, H., Benter, T., and Willner, H.: The UV/Vis absorption spectrum of matrix-isolated dichlorine peroxide, ClOOCl, Phys. Chem. Chem. Phys., 11, 1571–1580, https://doi.org/10.1039/B814373K, 2009.
von Savigny, C., Rozanov, A., Bovensmann, H., Eichmann, K.-U., Noël, S., Rozanov, V., Sinnhuber, B.-M., Weber, M., Burrows, J. P., and Kaiser, J. W.: The ozone hole breakup in September 2002 as seen by SCIAMACHY on ENVISAT, J. Atmos. Sci., 62, 721–734, 2005a.
von Savigny, C., Ulasi, E. P., Eichmann, K.-U., Bovensmann, H., and Burrows, J. P.: Detection and mapping of polar stratospheric clouds using limb scattering observations, Atmos. Chem. Phys., 5, 3071–3079, https://doi.org/10.5194/acp-5-3071-2005, 2005b.
Varotsos, C.: The southern hemisphere ozone hole split in 2002, Environ. Sci. Pollut. Res., 9, 375–376, 2002.
Weber, M., Dhomse, S., Wittrock, F., Richter, A., Sinnhuber, B.-M., and Burrows, J. P.: Dynamical control of NH and SH winter/spring total ozone from GOME observations in 1995–2002, Geophys. Res. Lett., 30, 1583, https://doi.org/10.1029/2002GL016799, 2003.
WMO (World Meteorological Organization), Scientific Assessment of Ozone Depletion: 2002, Global Ozone Research and Monitoring Project-Report 47, Geneva, Switzerland, 2003.
WMO (World Meteorological Organization), Scientific Assessment of Ozone Depletion: 2006, Global Ozone Research and Monitoring Project-Report 50, Geneva, Switzerland, 2007.
WMO (World Meteorological Organization), Scientific Assessment of Ozone Depletion: 2010, Global Ozone Research and Monitoring Project-Report 52, Geneva, Switzerland, 2011.
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