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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-13-1457-2013</article-id>
<title-group>
<article-title>The spatial scale of ozone depletion events derived from an autonomous surface ozone network in coastal Antarctica</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Jones</surname>
<given-names>A. E.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wolff</surname>
<given-names>E. W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Brough</surname>
<given-names>N.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bauguitte</surname>
<given-names>S. J.-B.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Weller</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Yela</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Navarro-Comas</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ochoa</surname>
<given-names>H. A.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Theys</surname>
<given-names>N.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>British Antarctic Survey, Natural Environment Research Council, Cambridge, UK</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Alfred Wegener Institute, Bremerhaven, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>INTA, Área de Investigación e Instrumentación Atmosférica,Torrejón de Ardoz, Spain</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Dirección Nacional del Antártico/Instituto Antártico Argentino (DNA/IAA), Buenos Aires, Argentina</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Belgian Institute of Spatial Aeronomy (IASB-BIRA), Bruxelles, Belgium</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>now at: Facility for Airborne Atmospheric Measurements, Natural Environment Research Council, Cranfield, UK</addr-line>
</aff>
<pub-date pub-type="epub">
<day>06</day>
<month>02</month>
<year>2013</year>
</pub-date>
<volume>13</volume>
<issue>3</issue>
<fpage>1457</fpage>
<lpage>1467</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/13/1457/2013/acp-13-1457-2013.html">This article is available from http://www.atmos-chem-phys.net/13/1457/2013/acp-13-1457-2013.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/13/1457/2013/acp-13-1457-2013.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/13/1457/2013/acp-13-1457-2013.pdf</self-uri>
<abstract>
<p>To probe the spatial extent of tropospheric ozone depletion events during
Antarctic spring, a network of 10 autonomous ozone monitors was established
around the Dronning Maud Land sector of Antarctica for a full calendar year.
Together with manned stations in the area, the network covered a
~1200 km stretch of coast, as well as a transect
~300 km inland and to ~2000 m above sea level
(a.s.l.). Here we present results from the spring period (August to October
2008). While some ozone depletion events were evident at only a single site,
implying localised ozone destruction, others were evident across the
network. The fact that, on occasions, ozone depletion events were observed
at all coastal sites simultaneously, suggests the depleted air mass had a
scale of at least 1200 km. As the ozone-poor air was advected from the
Weddell Sea sea ice zone, the data imply that large areas over the Weddell
Sea sea ice zone are significantly depleted in ozone on occasions during
Antarctic spring.</p>
</abstract>
<counts><page-count count="11"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Bauguitte, S. J.-B., Brough, N., Frey, M. M., Jones, A. E., Maxfield, D. J., Roscoe, H. K., Rose, M. C., and Wolff, E. W.: A network of autonomous surface ozone monitors in Antarctica: technical description and first results, Atmos. Meas. Tech., 4, 645–658, http://dx.doi.org/10.5194/amt-4-645-2011doi:10.5194/amt-4-645-2011, 2011. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Bottenheim, J. W., Netcheva, S., Morin, S., and Nghiem, S. V.: Ozone in the boundary layer air over the Arctic Ocean: measurements during the TARA transpolar drift 2006–2008, Atmos. Chem. Phys., 9, 4545–4557, http://dx.doi.org/10.5194/acp-9-4545-2009doi:10.5194/acp-9-4545-2009, 2009. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Buys, Z., Brough, N., Huey, L. G., Tanner, D. J., von Glasow, R., and Jones, A. E.: High temporal resolution Br&lt;sub&gt;2&lt;/sub&gt;, BrCl and BrO observations in coastal Antarctica, Atmos. Chem. Phys., 13, 1329–1343, http://dx.doi.org/10.5194/acp-13-1329-2013doi:10.5194/acp-13-1329-2013, 2013. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Choi, S., Wang, Y., Salawitch, R. J., Canty, T., Joiner, J., Zeng, T., Kurosu, T. P., Chance, K., Richter, A., Huey, L. G., Liao, J., Neuman, J. A., Nowak, J. B., Dibb, J. E., Weinheimer, A. J., Diskin, G., Ryerson, T. B., da Silva, A., Curry, J., Kinnison, D., Tilmes, S., and Levelt, P. F.: Analysis of satellite-derived Arctic tropospheric BrO columns in conjunction with aircraft measurements during ARCTAS and ARCPAC, Atmos. Chem. Phys., 12, 1255–1285, http://dx.doi.org/10.5194/acp-12-1255-2012doi:10.5194/acp-12-1255-2012, 2012. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Frieß, U., Hollwedel, J., Konig-Langlo, G., Wagner, T., and Platt U.: Dynamics and chemistry of tropospheric bromine explosion events in the Antarctic coastal region, J. Geophys. Res., 109, D06305, http://dx.doi.org/10.1029/2003JD004133doi:10.1029/2003JD004133, 2004. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Helmig, D., Oltmans, S., Carlson, D., Lamarque, J.-F., Jones, A.E., Labuschagne, C., Anlauf, K., and Hayden, K.: A review of surface ozone in the polar regions, Atmos. Environ., 41, 5138–5161, http://dx.doi.org/10.1016/j.atmosenv.2006.09.053doi:10.1016/j.atmosenv.2006.09.053, 2007. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Hopper, J. F., Peters, B., Yokouchi, Y., Niki, H., Jobson, B. T., Shelson, P. B., and Muthuramu, K.: Chemical and meteorological observations at ice camp SWAN during Polar Sunrise Experiment 1992, J. Geophys. Res., 99, 25489–25498, 1994. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Hopper, J. F., Barrie, L. A., Silis, A., Hart, W., Gallant, A. J., and Dryfhout, H.: Ozone and meteorology during the 1994 Polar Sunrise Experiment, J. Geophys. Res., 103, 1481–1492, 1998. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Jacobi, H.-W., Morin, S., and Bottenheim, J. W.: Observation of widespread depletion of ozone in the springtime boundary layer of the central Arctic linked to mesoscale synoptic conditions, J. Geophys. Res., 115, D17302, http://dx.doi.org/10.1029/2010JD013940doi:10.1029/2010JD013940, 2010. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Jones, A. E., Anderson, P. S., Begoin, M., Brough, N., Hutterli, M. A., Marshall, G. J., Richter, A., Roscoe, H. K., and Wolff, E. W.: BrO, blizzards, and drivers of polar tropospheric ozone depletion events, Atmos. Chem. Phys., 9, 4639–4652, http://dx.doi.org/10.5194/acp-9-4639-2009doi:10.5194/acp-9-4639-2009, 2009. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Kaleschke, L., Richter, A., Burrows, J. P., Afe, O., Heygster, G., Notholt, J., Rankin, A. M., Roscoe, H. K., Hollwedel, J., Wagner, T., and Jacobi, H.-W.: Frost flowers on sea ice as a source of sea salt and their influence on tropospheric halogen chemistry, Geophys. Res. Lett., 31, L16114, http://dx.doi.org/10.1029/2004GL020655doi:10.1029/2004GL020655, 2004. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> King, J. C.: Control of near-surface winds over an Antarctic ice shelf, J. Geophys. Res., 98, 12949–12953, 1993. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Knepp, T. N., Bottenheim, J., Carlsen, M., Carlson, D., Donohoue, D., Friederich, G., Matrai, P. A., Netcheva, S., Perovich, D. K., Santini, R., Shepson, P. B., Simpson, W., Valentic, T., Williams, C., and Wyss, P. J.: Development of an autonomous sea ice tethered buoy for the study of ocean-atmosphere-sea ice-snow pack interactions: the O-buoy, Atmos. Meas. Tech., 3, 249–261, http://dx.doi.org/10.5194/amt-3-249-2010doi:10.5194/amt-3-249-2010, 2010. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Lacis, A. A., Weubbles, D. J., and Logan, J. A.: Radiative forcing of climate by changes in the vertical distribution of ozone, J. Geophys. Res., 95, 9971–9981, 1990. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> McConnell, J. C., Henderson, G. S., Barrie, L., Bottenheim, J., Niki, H., Langford, C. H., and Templeton, E. M. J.: Photochemical bromine production implicated in Arctic boundary-layer ozone depletion, Nature, 355, 150–152, 1992. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Munro, R., Eisinger, M., Anderson, C., Callies, J., Corpaccioli, E., Lang, R., Lefebvre, A., Livschitz, Y., and Pérez Albiñana, A.: GOME-2 on Metop: From in-orbit verification to routine operations, in: The 2006 EUMETSAT Meteorological Satellite Conference, 12–16 June 2006, Helsinki, Finland, p. 48, 2006. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Rankin, A. M., Wolff, E. W., and Martin, S.: Frost flowers - implications for tropospheric chemistry and ice core interpretation, J. Geophys. Res., 107, 4683, http://dx.doi.org/10.1029/2002JD002492doi:10.1029/2002JD002492, 2002. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Read, K. A., Lewis, A. C., Bauguitte, S., Rankin, A. M., Salmon, R. A., Wolff, E. W., Saiz-Lopez, A., Bloss, W. J., Heard, D. E., Lee, J. D., and Plane, J. M. C.: DMS and MSA measurements in the Antarctic Boundary Layer: impact of BrO on MSA production, Atmos. Chem. Phys., 8, 2985–2997, http://dx.doi.org/10.5194/acp-8-2985-2008doi:10.5194/acp-8-2985-2008, 2008. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> Richter, A., Wittrock, F., Eisinger, M., and Burrows, J. P.: GOME observations of tropospheric BrO in Northern Hemispheric spring and summer 1997, Geophys. Res. Lett., 25, 2683–2686, 1998. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Ridley, B. A., Atlas, E. L., Montzka, D. D., Browell, E. V., Cantrell, C. A., Blake, D. R., Blake, N. J., Cinquini, L., Coffey, M. T., Emmons, L. K., Cohen, R. C., DeYoung, R. J., Dibb, J. E., Eisele, F. L., Flocke, F. M., Fried, A., Grahek, F. E., Grant, W. B., Hair, J. W., Hannigan, J. W., Heikes, B. J., Lefer, B. L., Mauldin, R. L., Moody, J. L., Shetter, R. E., Snow, J. A., Talbot, R. W., Thornton, J. A., Walega, J. G., Weinheimer, A. J., Wert, B. P., and Wimmers, A. J.: Ozone depletion events observed in the high latitude surface layer during the TOPSE aircraft program, J. Geophys. Res., 108, 8356, http://dx.doi.org/10.1029/2001JD001507doi:10.1029/2001JD001507, 2003. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Ridley, B. A., Zeng, T., Wang, Y, Atlas, E. L., Browell, E. V., Hess, P. G., Orlando, J. J., Chance, K., and Richter, A.: An ozone depletion event in the sub-arctic surface layer over Hudson Bay, Canada, J. Atmos. Chem., 57, 255–280, http://dx.doi.org/10.1007/s10874-007-9072-zdoi:10.1007/s10874-007-9072-z, 2007. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Roscoe, H. K., Kreher, K., and Friess, U.: Ozone loss episodes in the free Antarctic troposphere, suggesting a possible climate feedback, Geophys. Res. Lett., 28, 2911–2914, 2001. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Roscoe, H. K., Brough, N., Jones, A. E., Wittrock, F., Richter, A., Van Roozendael, M., and Hendrick, F.: Resolution of an important discrepancy between remote and in-situ measurements of tropospheric BrO during Antarctic enhancements, Atmos. Meas. Tech. Discuss., 5, 5419–5448, http://dx.doi.org/10.5194/amtd-5-5419-2012doi:10.5194/amtd-5-5419-2012, 2012. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Salawitch, R. J., Canty, T., Kurosu, T., Chance, K., Liang, Q., da Silva, A., Pawson, S., Nielsen, J. E., Rodriguez, J. M., Bhartia, P. K., Liu, X., Huey, L. G., Liao, J., Stickel, R. E., Tanner, D. J., Dibb, J. E., Simpson, W. R., Donohoue, D., Weinheimer, A., Flocke, F., Knapp, D., Montzka, D., Neuman, J. A., Nowak, J. B., Ryerson, T. B., Oltmans, S., Blake, D. R., Atlas, E. L., Kinnison, D. E., Tilmes, S., Pan, L. L., Hendrick, F., Van Roozendael, M., Kreher, K., Johnston, P. V., Gao, R. S., Johnson, B., Bui, T. P., Chen, G., Pierce, R. B., Crawford, J. H., and Jacob, D. J.: A new interpretation of total column BrO during Arctic spring, Geophys. Res. Lett., 37, L21805, http://dx.doi.org/10.1029/2010GL043798doi:10.1029/2010GL043798, 2010. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Simpson, W. R., Carlson, D., Hönninger, G., Douglas, T. A., Sturm, M., Perovich, D., and Platt, U.: First-year sea-ice contact predicts bromine monoxide (BrO) levels at Barrow, Alaska better than potential frost flower contact, Atmos. Chem. Phys., 7, 621–627, http://dx.doi.org/10.5194/acp-7-621-2007doi:10.5194/acp-7-621-2007, 2007a. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Simpson, W. R., von Glasow, R., Riedel, K., Anderson, P., Ariya, P., Bottenheim, J., Burrows, J., Carpenter, L. J., Frieß, U., Goodsite, M. E., Heard, D., Hutterli, M., Jacobi, H.-W., Kaleschke, L., Neff, B., Plane, J., Platt, U., Richter, A., Roscoe, H., Sander, R., Shepson, P., Sodeau, J., Steffen, A., Wagner, T., and Wolff, E.: Halogens and their role in polar boundary-layer ozone depletion, Atmos. Chem. Phys., 7, 4375–4418, http://dx.doi.org/10.5194/acp-7-4375-2007doi:10.5194/acp-7-4375-2007, 2007b. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Spreen, G., Kaleschke, L., and Heygster, G.: Sea ice remote sensing using AMSR-E 89 GHz channels J. Geophys. Res.,vol 113, C02S03, http://dx.doi.org/10.1029/2005JC003384doi:10.1029/2005JC003384, 2008. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> Theys, N., Van Roozendael, M., Errera, Q., Hendrick, F., Daerden, F., Chabrillat, S., Dorf, M., Pfeilsticker, K., Rozanov, A., Lotz, W., Burrows, J. P., Lambert, J.-C., Goutail, F., Roscoe, H. K., and De Mazière, M.: A global stratospheric bromine monoxide climatology based on the BASCOE chemical transport model, Atmos. Chem. Phys., 9, 831–848, http://dx.doi.org/10.5194/acp-9-831-2009doi:10.5194/acp-9-831-2009, 2009. </mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple"> Theys, N., Van Roozendael, M., Hendrick, F., Yang, X., De Smedt, I., Richter, A., Begoin, M., Errera, Q., Johnston, P. V., Kreher, K., and De Mazière, M.: Global observations of tropospheric BrO columns using GOME-2 satellite data, Atmos. Chem. Phys., 11, 1791–1811, http://dx.doi.org/10.5194/acp-11-1791-2011doi:10.5194/acp-11-1791-2011, 2011. </mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple"> Vogt, R., Crutzen, P. J., and Sander, R.: A mechanism for halogen release from sea-salt aerosol in the remote marine boundary layer, Nature, 383, 327–330, 1996. </mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple"> Wagner, T. and Platt, U.: Satellite mapping of enhanced BrO concentrations in the troposphere, Nature, 395, 486–490, http://dx.doi.org/10.1038/26723doi:10.1038/26723, 1998. </mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple"> Wilson, K. L. and Birks, J. W.: Mechanism and elimination of a water vapor interference in the measurements of ozone by UV absorbance, Environ. Sci. Technol., 40, 6361–6367, http://dx.doi.org/10.1021/es052590cdoi:10.1021/es052590c, 2006. </mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple"> Yang, X., Pyle, J. A., and Cox, R. A.: Sea salt aerosol production and bromine release: Role of snow on sea ice, Geophys. Res. Lett., 35, L16815, http://dx.doi.org/10.1029/2008GL034536doi:10.1029/2008GL034536, 2008. </mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple"> Yang, X., Pyle, J. A., Cox, R. A., Theys, N., and Van Roozendael, M.: Snow-sourced bromine and its implications for polar tropospheric ozone, Atmos. Chem. Phys., 10, 7763–7773, http://dx.doi.org/10.5194/acp-10-7763-2010doi:10.5194/acp-10-7763-2010, 2010. </mixed-citation>
</ref>
</ref-list>
</back>
</article>