Department of Environmental Sciences and Engineering, Gillings School of Global Public Health, The University of North Carolina at Chapel Hill, NC, 27599-7431, USA
Received: 02 May 2012 – Published in Atmos. Chem. Phys. Discuss.: 07 Jun 2012
Abstract. Isoprene epoxydiol (IEPOX) isomers are key gas-phase intermediates of isoprene atmospheric oxidation. Secondary organic aerosols derived from such intermediates have important impacts on air quality and health. We report here convergent and unambiguous pathways developed for the synthesis of isomeric IEPOX species and the rearrangement products cis- and trans-3-methyl-3,4-dihydroxytetrahydrofuran in good yield. The availability of such compounds is necessary to expedite research on isoprene atmospheric oxidation mechanisms and subsequent aerosol formation as well as the toxicological properties of the aerosols.
Revised: 28 Aug 2012 – Accepted: 04 Sep 2012 – Published: 21 Sep 2012
Citation: Zhang, Z., Lin, Y.-H., Zhang, H., Surratt, J. D., Ball, L. M., and Gold, A.: Technical Note: Synthesis of isoprene atmospheric oxidation products: isomeric epoxydiols and the rearrangement products cis- and trans-3-methyl-3,4-dihydroxytetrahydrofuran, Atmos. Chem. Phys., 12, 8529-8535, doi:10.5194/acp-12-8529-2012, 2012.