<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-12-7391-2012</article-id>
<title-group>
<article-title>Sources of atmospheric mercury in the tropics: continuous observations at a coastal site in Suriname</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Müller</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Wip</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Warneke</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Holmes</surname>
<given-names>C. D.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dastoor</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Notholt</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Institute of Environmental Physics, University of Bremen, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Anton de Kom Universiteit van Suriname, Paramaribo, Suriname</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>University of California, Irvine, USA</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Air Quality Research Division, Environment Canada, 2121 Trans Canada Highway, Dorval, QC, H9P 1J3, Canada</addr-line>
</aff>
<pub-date pub-type="epub">
<day>16</day>
<month>08</month>
<year>2012</year>
</pub-date>
<volume>12</volume>
<issue>16</issue>
<fpage>7391</fpage>
<lpage>7397</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/12/7391/2012/acp-12-7391-2012.html">This article is available from http://www.atmos-chem-phys.net/12/7391/2012/acp-12-7391-2012.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/12/7391/2012/acp-12-7391-2012.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/12/7391/2012/acp-12-7391-2012.pdf</self-uri>
<abstract>
<p>Mercury measurements at a coastal site in Nieuw Nickerie (5°56&apos; N,
56°59&apos; W), Suriname, provide the only continuous records of atmospheric
mercury in the tropics. Here we evaluate observations of total gaseous
mercury (TGM) during 2007. Nieuw Nickerie typically samples marine air from
the Atlantic Ocean, with occasional influence from continental South
America. Over the year, average concentrations are 1.40 ng m&lt;sup&gt;−3&lt;/sup&gt;. As the
intertropical convergence zone passes over Suriname twice each year, the
site samples both northern and southern hemispheric air masses. We use back
trajectories to classify each measurement by hemisphere, as well as
continental or ocean. For air passing over ocean before sampling, TGM
concentrations are 10% higher in air coming from the Northern Hemisphere
(1.45 ng m&lt;sup&gt;−3&lt;/sup&gt;) than from the Southern Hemisphere (1.32 ng m&lt;sup&gt;−3&lt;/sup&gt;). Air
from the South American continent also carries higher TGM (1.43 ng m&lt;sup&gt;−3&lt;/sup&gt;)
than air from the South Atlantic Ocean, with most of these trajectories
occurring in August and September. Biomass burning in Brazil peaks in the
same months and likely contributes significantly to elevated concentrations
seen in Nickerie. We also compare the observed seasonal cycle to two
atmospheric mercury chemistry and transport models (GRAHM and GEOS-Chem).
Both models simulate transition between northern and southern hemispheric
air, thus capturing the seasonal cycle; however the models overestimate the
TGM concentrations during months when Nickerie samples Northern Hemisphere
air. It is difficult to determine whether the models&apos; sources or sinks in
the Northern Hemisphere tropics are responsible.</p>
</abstract>
<counts><page-count count="7"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Brunke, E.-G., Labuschagne, C., Ebinghaus, R., Kock, H. H., and Slemr, F.: Gaseous elemental mercury depletion events observed at Cape Point during 2007–2008, Atmos. Chem. Phys., 10, 1121–1131, http://dx.doi.org/10.5194/acp-10-1121-2010doi:10.5194/acp-10-1121-2010, 2010. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Durnford, D., Dastoor, A., Ryzhkov, A., Poissant, L., Pilote, M., and Figueras-Nieto, D.: How relevant is the deposition of mercury onto snowpacks? – Part 2: A modeling study, Atmos. Chem. Phys. Discuss., 12, 2647–2706, http://dx.doi.org/10.5194/acpd-12-2647-2012doi:10.5194/acpd-12-2647-2012, 2012. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Draxler,~R. R. and Hess,~G. D.: Description of the HYSPLIT_4 modeling system. NOAA Tech. Memo. ERL ARL-224, NOAA Air Resources Laboratory, Silver Spring, MD, 24 pp., 1997. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Draxler,~R. R. and Hess,~G. D.: An overview of the HYSPLIT_4 modeling system of trajectories, dispersion, and deposition, Aust. Meteor. Mag., 47, 295–308, 1998. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Draxler,~R. R.: HYSPLIT4 user&apos;s guide, NOAA Tech. Memo. ERL ARL-230, NOAA Air Resources Laboratory, Silver Spring, MD, 1999. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Ebinghaus,~R., Tripathi,~R. M., Wallschläger,~D., and Lindberg,~S. E.: Natural and Anthropogenic Mercury Sources and Their Impact on the Air-Surface Exchange of Mercury on Regional and Global Scales, in: Mercury Contaminated Sites – Characterization, Risk Assessment and Remediation, edited by: Ebinghaus, R., Turner, R. R., de Lacerda, L. D., Vasiliev, O., and Salomons, W., Springer, Berlin/Heidelberg, 1999. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Ebinghaus,~R., Kock,~H. H., Coggins,~A. M., Spain,~T. G., Jennings,~S. G., and Temme,~C.: Long-term measurements of atmospheric mercury at Mace Head, Irish west coast, between 1995 and 2001, Atmos. Environ., 36, 5267–5276, 2002. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Ebinghaus,~R., Slemr,~F., Benninkmeijer,~C. A. M., van Velthoven,~P., Zahn,~A., Hermann,~M., O&apos;Sullivan,~D. A., and Oram,~D. E.: Emissions of gaseous mercury from biomass burning in South America in 2005 observed during CARIBIC flights, Geophys. Res. Lett., 34, L08813, http://dx.doi.org/10.1029/2006GL028866doi:10.1029/2006GL028866, 2007. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Holmes,~C. D., Jacob,~D. J., and Yang,~X.: Global lifetime of elemental mercury against oxidation by atomic bromine in the free troposphere, Geophys. Res. Lett., 33, L20808, http://dx.doi.org/10.1029/2006GL027176doi:10.1029/2006GL027176, 2006. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Holmes, C. D., Jacob, D. J., Corbitt, E. S., Mao, J., Yang, X., Talbot, R., and Slemr, F.: Global atmospheric model for mercury including oxidation by bromine atoms, Atmos. Chem. Phys., 10, 12037–12057, http://dx.doi.org/10.5194/acp-10-12037-2010doi:10.5194/acp-10-12037-2010, 2010. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Kock,~H. H., Bieber,~E., Ebinghaus,~R., Spain,~T. G., and Thees,~B.: Comparison of long-term trends and seasonal variations of atmospheric mercury concentrations at the two European coastal monitoring stations Mace Head, Ireland, and Zingst, Germany, Atmos. Environ., 39, 7549–7556, http://dx.doi.org/10.1016/j.atmosenv.2005.02.059doi:10.1016/j.atmosenv.2005.02.059, 2005. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Lindberg,~S., Bullock,~R., Ebinghaus,~R., Engstrom,~D., Feng,~X., Fitzgerald,~W., Pirrone,~N., Prestbo,~E., and Seigneur,~C.: A Synthesis of Progress and Uncertainties in Attributing the Sources of Mercury in Deposition, Ambio, 36, 19–33, 2007. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Mason,~R. P.: Mercury emissions from natural processes and their importance in the global mercury cycle, in: Mercury Fate and Transport in the Global Atmosphere: Emissions, Measurements and Models, edited by: Pirrone,~N. and Mason,~R. P., Chapter 7, Springer, 173–191, 2009. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Pfaffhuber, K. A., Berg, T., Hirdman, D., and Stohl, A.: Atmospheric mercury observations from Antarctica: seasonal variation and source and sink region calculations, Atmos. Chem. Phys., 12, 3241–3251, http://dx.doi.org/10.5194/acp-12-3241-2012doi:10.5194/acp-12-3241-2012, 2012. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Pirrone, N., Cinnirella, S., Feng, X., Finkelman, R. B., Friedli, H. R., Leaner, J., Mason, R., Mukherjee, A. B., Stracher, G. B., Streets, D. G., and Telmer, K.: Global mercury emissions to the atmosphere from anthropogenic and natural sources, Atmos. Chem. Phys., 10, 5951–5964, http://dx.doi.org/10.5194/acp-10-5951-2010doi:10.5194/acp-10-5951-2010, 2010. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Qureshi,~A., MacLeod,~M., and Hungerbühler,~K.: Quantifying uncertainties in the global mass balance of mercury, Global Biogeochem. Cy., 25, GB4012, http://dx.doi.org/10.1029/2011GB004068doi:10.1029/2011GB004068, 2011. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Slemr,~F., Schuster,~G., and Seiler,~W.: Distribution, Speciation, and Budget of Atmospheric Mercury, J. Atmos. Chem., 3, 407–434, 1985. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Slemr,~F., Brunke,~E.-G., Labuschagne,~C., and Ebinghaus,~R.: Total gaseous mercury concentrations at the Cape Point GAW station and their seasonality, Geophys. Res. Lett., 35, L11807, http://dx.doi.org/10.1029/2008GL033741doi:10.1029/2008GL033741, 2008. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> Slemr, F., Brunke, E.-G., Ebinghaus, R., and Kuss, J.: Worldwide trend of atmospheric mercury since 1995, Atmos. Chem. Phys., 11, 4779-4787, http://dx.doi.org/10.5194/acp-11-4779-2011doi:10.5194/acp-11-4779-2011, 2011. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> Soerensen,~A. L., Sunderland,~E. M., Holmes,~C. D., Jacob,~D. J., Yantosca,~R. M., Skov,~H., Christensen,~J. H., Strode,~S. A., and Mason,~R. P.: An Improved Global Model for Air-Sea Exchange of Mercury: High Concentrations over the North Atlantic, Environ. Sci. Technol., 44, 8574–8580, 2010. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> Sprovieri, F., Pirrone, N., Ebinghaus, R., Kock, H., and Dommergue, A.: A review of worldwide atmospheric mercury measurements, Atmos. Chem. Phys., 10, 8245–8265, http://dx.doi.org/10.5194/acp-10-8245-2010doi:10.5194/acp-10-8245-2010, 2010. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Strode,~S. A., Jaeglé,~L., Selin,~N. E., Jacob,~D. J., Park,~R. J., Yantosca,~R. M., Mason,~R. P., and Slemr,~F.: Air-sea exchange in the global mercury cycle, Global Biogeochem. Cy., 21, GB1017, http://dx.doi.org/10.1029/2006GB002766doi:10.1029/2006GB002766, 2007. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Temme,~C., Einax,~J. W., Ebinghaus,~R., and Schroeder,~W. H.: Measurements of Atmospheric Mercury Species at a Coastal Site in the Antarctic and over the South Atlantic Ocean during Polar Summer, Environ. Sci. Technol., 37, 22–31, 2003. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> van der Werf, G. R., Randerson, J. T., Giglio, L., Collatz, G. J., Mu, M., Kasibhatla, P. S., Morton, D. C., DeFries, R. S., Jin, Y., and van Leeuwen, T. T.: Global fire emissions and the contribution of deforestation, savanna, forest, agricultural, and peat fires (1997–2009), Atmos. Chem. Phys., 10, 11707–11735, http://dx.doi.org/10.5194/acp-10-11707-2010doi:10.5194/acp-10-11707-2010, 2010. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Wip, D., Warneke, T., Notholt, J., and Müller, D.: Variations of mercury concentrations in tropical Atlantic air, in preparation, 2012. </mixed-citation>
</ref>
</ref-list>
</back>
</article>