<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing DTD v3.0 20080202//EN" "http://dtd.nlm.nih.gov/publishing/3.0/journalpublishing3.dtd">
<article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" article-type="research-article" dtd-version="3.0" xml:lang="en">
<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus GmbH</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-12-5807-2012</article-id>
<title-group>
<article-title>On the representation of immersion and condensation freezing in cloud models using different nucleation schemes</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ervens</surname>
<given-names>B.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Feingold</surname>
<given-names>G.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Chemical Sciences Division, NOAA Earth System Research Laboratory, Boulder, Colorado, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>06</day>
<month>07</month>
<year>2012</year>
</pub-date>
<volume>12</volume>
<issue>13</issue>
<fpage>5807</fpage>
<lpage>5826</lpage>
<permissions>
<license xlink:type="simple">
<license-p>This is an open-access article ditributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.</license-p>
</license>
</permissions>
<self-uri xlink:href="http://www.atmos-chem-phys.net/12/5807/2012/acp-12-5807-2012.html">This article is available from http://www.atmos-chem-phys.net/12/5807/2012/acp-12-5807-2012.html</self-uri>
<self-uri xlink:href="http://www.atmos-chem-phys.net/12/5807/2012/acp-12-5807-2012.pdf">The full text article is available as a PDF file from http://www.atmos-chem-phys.net/12/5807/2012/acp-12-5807-2012.pdf</self-uri>
<abstract>
<p>Ice nucleation in clouds is often observed at temperatures &gt;235 K,
pointing to heterogeneous freezing as a predominant mechanism. Many models
deterministically predict the number concentration of ice particles as a
function of temperature and/or supersaturation. Several laboratory
experiments, at constant temperature and/or supersaturation, report
heterogeneous freezing as a stochastic, time-dependent process that follows
classical nucleation theory; this might appear to contradict deterministic
models that predict singular freezing behavior.
&lt;br&gt;&lt;br&gt;
We explore the extent to which the choice of nucleation scheme
(deterministic/stochastic, single/multiple contact angles θ) affects the
prediction of the fraction of frozen ice nuclei (IN) and cloud evolution for
a predetermined maximum IN concentration. A box model with constant
temperature and supersaturation is used to mimic published laboratory
experiments of immersion freezing of monodisperse (800 nm) kaolinite
particles (~243 K), and the fitness of different nucleation schemes.
Sensitivity studies show that agreement of all five schemes is restricted to
the narrow parameter range (time, temperature, IN diameter) in the original
laboratory studies, and that model results diverge for a wider range of
conditions.
&lt;br&gt;&lt;br&gt;
The schemes are implemented in an adiabatic parcel model that includes
feedbacks of the formation and growth of drops and ice particles on
supersaturation during ascent. Model results for the monodisperse IN
population (800 nm) show that these feedbacks limit ice nucleation events,
often leading to smaller differences in number concentration of ice
particles and ice water content (IWC) between stochastic and deterministic
approaches than expected from the box model studies. However, because the
different parameterizations of θ distributions and time-dependencies
are highly sensitive to IN size, simulations using polydisperse IN result in
great differences in predicted ice number concentrations and IWC between the
different schemes. The differences in IWC are mostly due to the different
temperatures of the onset of freezing in the nucleation schemes that affect
the temporal evolution of the ice number concentration. The growth rates of
ice particles are not affected by the choice of the nucleation scheme, which
leads to very similar particle sizes. Finally, since the choice of
nucleation scheme determines the temperature range over which ice nucleation
occurs, at habit-prone temperatures (~253 K), there is the potential
for variability in the initial inherent growth ratio of ice particles, which
can cause amplification or reduction in differences in predicted IWC.</p>
</abstract>
<counts><page-count count="20"/></counts>
</article-meta>
</front>
<body/>
<back>
<ref-list>
<title>References</title>
<ref id="ref1">
<label>1</label><mixed-citation publication-type="other" xlink:type="simple"> Alpert, P. A., Aller, J. Y., and Knopf, D. A.: Initiation of the ice phase by marine biogenic surfaces in supersaturated gas and supercooled aqueous phases, Phys. Chem. Chem. Phys., 13, 44, 19882–19894, 2011. </mixed-citation>
</ref>
<ref id="ref2">
<label>2</label><mixed-citation publication-type="other" xlink:type="simple"> Archuleta, C. M., DeMott, P. J., and Kreidenweis, S. M.: Ice nucleation by surrogates for atmospheric mineral dust and mineral dust/sulfate particles at cirrus temperatures, Atmos. Chem. Phys., 5, 2617–2634, http://dx.doi.org/10.5194/acp-5-2617-2005doi:10.5194/acp-5-2617-2005, 2005. </mixed-citation>
</ref>
<ref id="ref3">
<label>3</label><mixed-citation publication-type="other" xlink:type="simple"> Avramov, A. and Harrington, J. Y.: Influence of parameterized ice habit on simulated mixed phase Arctic clouds, J. Geophys. Res., 115, D03205, http://dx.doi.org/10.1029/2009jd012108doi:10.1029/2009jd012108, 2010. </mixed-citation>
</ref>
<ref id="ref4">
<label>4</label><mixed-citation publication-type="other" xlink:type="simple"> Barahona, D.: On the ice nucleation spectrum, Atmos. Chem. Phys., 12, 3733–3752, http://dx.doi.org/10.5194/acp-12-3733-2012doi:10.5194/acp-12-3733-2012, 2012. </mixed-citation>
</ref>
<ref id="ref5">
<label>5</label><mixed-citation publication-type="other" xlink:type="simple"> Bigg, E. K.: The formation of atmospheric ice crystals by the freezing of droplets, Q. J. Roy. Meteor. Soc., 79, 342, 510–519, http://dx.doi.org/10.1002/qj.49707934207doi:10.1002/qj.49707934207, 1953. </mixed-citation>
</ref>
<ref id="ref6">
<label>6</label><mixed-citation publication-type="other" xlink:type="simple"> Broadley, S. L., Murray, B. J., Herbert, R. J., Atkinson, J. D., Dobbie, S., Malkin, T. L., Condliffe, E., and Neve, L.: Immersion mode heterogeneous ice nucleation by an illite rich powder representative of atmospheric mineral dust, Atmos. Chem. Phys., 12, 287–307, http://dx.doi.org/10.5194/acp-12-287-2012doi:10.5194/acp-12-287-2012, 2012. </mixed-citation>
</ref>
<ref id="ref7">
<label>7</label><mixed-citation publication-type="other" xlink:type="simple"> Bryant, G. W., Hallett, J., and Mason, B. J.: The epitaxial growth of ice on single-crystalline substrates, J. Phys. Chem. Solids, 12, 189–195, 1959. </mixed-citation>
</ref>
<ref id="ref8">
<label>8</label><mixed-citation publication-type="other" xlink:type="simple"> Chen, J.-P. and Lamb, D.: The theoretical basis for the parameterization of ice crystal habits: Growth by vapor deposition, J. Atmos. Sci., 51, 9, 1206–1221, 1994. </mixed-citation>
</ref>
<ref id="ref9">
<label>9</label><mixed-citation publication-type="other" xlink:type="simple"> Chen, J.-P., Hazra, A., and Levin, Z.: Parameterizing ice nucleation rates using contact angle and activation energy derived from laboratory data, Atmos. Chem. Phys., 8, 7431–7449, http://dx.doi.org/10.5194/acp-8-7431-2008doi:10.5194/acp-8-7431-2008, 2008. </mixed-citation>
</ref>
<ref id="ref10">
<label>10</label><mixed-citation publication-type="other" xlink:type="simple"> Christner, B. C., Morris, C. E., Foreman, C. M., Cai, R., and Sandis, D. C.: Ubiquity of biological ice nucleators in snowfall, Science, 319, 1214, http://dx.doi.org/10.1126/science.1149757doi:10.1126/science.1149757, 2008. </mixed-citation>
</ref>
<ref id="ref11">
<label>11</label><mixed-citation publication-type="other" xlink:type="simple"> Connolly, P. J., Möhler, O., Field, P. R., Saathoff, H., Burgess, R., Choularton, T., and Gallagher, M.: Studies of heterogeneous freezing by three different desert dust samples, Atmos. Chem. Phys., 9, 2805–2824, http://dx.doi.org/10.5194/acp-9-2805-2009doi:10.5194/acp-9-2805-2009, 2009. </mixed-citation>
</ref>
<ref id="ref12">
<label>12</label><mixed-citation publication-type="other" xlink:type="simple"> Cotton, R. J. and Field, P. R.: Ice nucleation characteristics of an isolated wave cloud, Q. J. R. Meteor. Soc., 128, 2417–2437, 2002. </mixed-citation>
</ref>
<ref id="ref13">
<label>13</label><mixed-citation publication-type="other" xlink:type="simple"> Cotton, W. R., Tripoli, G. J., Rauber, R. M., and Mulvihill, E. A.: Numerical Simulation of the Effects of Varying Ice Crystal Nucleation Rates and Aggregation Processes on Orographic Snowfall, J. Clim. Appl. Meteorol., 25, 11, 1658–1680, http://dx.doi.org/10.1175/1520-0450(1986)025&lt;1658:NSOTEO&gt;2.0.CO;2doi:10.1175/1520-0450(1986)025&lt;1658:NSOTEO&gt;2.0.CO;2, 1986. </mixed-citation>
</ref>
<ref id="ref14">
<label>14</label><mixed-citation publication-type="other" xlink:type="simple"> Crawford, I., Möhler, O., Schnaiter, M., Saathoff, H., Liu, D., McMeeking, G., Linke, C., Flynn, M., Bower, K. N., Connolly, P. J., Gallagher, M. W., and Coe, H.: Studies of propane flame soot acting as heterogeneous ice nuclei in conjunction with single particle soot photometer measurements, Atmos. Chem. Phys., 11, 9549–9561, http://dx.doi.org/10.5194/acp-11-9549-2011doi:10.5194/acp-11-9549-2011, 2011. </mixed-citation>
</ref>
<ref id="ref15">
<label>15</label><mixed-citation publication-type="other" xlink:type="simple"> Crawford, I., Bower, K. N., Choularton, T. W., Dearden, C., Crosier, J., Westbrook, C., Capes, G., Coe, H., Connolly, P. J., Dorsey, J. R., Gallagher, M. W., Williams, P., Trembath, J., Cui, Z., and Blyth, A.: Ice formation and development in aged, wintertime cumulus over the UK: observations and modelling, Atmos. Chem. Phys., 12, 4963–4985, http://dx.doi.org/10.5194/acp-12-4963-2012doi:10.5194/acp-12-4963-2012, 2012. </mixed-citation>
</ref>
<ref id="ref16">
<label>16</label><mixed-citation publication-type="other" xlink:type="simple"> Crosier, J., Bower, K. N., Choularton, T. W., Westbrook, C. D., Connolly, P. J., Cui, Z. Q., Crawford, I. P., Capes, G. L., Coe, H., Dorsey, J. R., Williams, P. I., Illingworth, A. J., Gallagher, M. W., and Blyth, A. M.: Observations of ice multiplication in a weakly convective cell embedded in supercooled mid-level stratus, Atmos. Chem. Phys., 11, 257–273, http://dx.doi.org/10.5194/acp-11-257-2011doi:10.5194/acp-11-257-2011, 2011. </mixed-citation>
</ref>
<ref id="ref17">
<label>17</label><mixed-citation publication-type="other" xlink:type="simple"> Curry, J.: Interactions among aerosols, clouds, and climate of the Arctic Ocean, Sci. Tot. Environ., 160/161, 777–791, 1995. </mixed-citation>
</ref>
<ref id="ref18">
<label>18</label><mixed-citation publication-type="other" xlink:type="simple"> Curry, J. A. and Khvorostyanov, V. I.: Assessment of some parameterizations of heterogeneous ice nucleation in cloud and climate models, Atmos. Chem. Phys., 12, 1151–1172, http://dx.doi.org/10.5194/acp-12-1151-2012doi:10.5194/acp-12-1151-2012, 2012. </mixed-citation>
</ref>
<ref id="ref19">
<label>19</label><mixed-citation publication-type="other" xlink:type="simple"> de Boer, G., Hashino, T., and Tripoli, G. J.: Ice nucleation through immersion freezing in mixed-phase stratiform clouds: Theory and numerical simulations, Atmos. Res., 96, 315–324, 2010. </mixed-citation>
</ref>
<ref id="ref20">
<label>20</label><mixed-citation publication-type="other" xlink:type="simple"> DeMott, P. J., Sassen, K., Poellot, M. R., Baumgardner, D., Rogers, D. C., Brooks, S. D., Prenni, A. J., and Kreidenweis, S. M.: African dust aerosols as atmospheric ice nuclei, Geophys. Res. Lett., 30, 1732, http://dx.doi.org/10.1029/2003GL017410doi:10.1029/2003GL017410, 2003. </mixed-citation>
</ref>
<ref id="ref21">
<label>21</label><mixed-citation publication-type="other" xlink:type="simple"> DeMott, P. J., Prenni, A. J., Liu, X., Kreidenweis, S. M., Petters, M. D., Twohy, C. H., Richardson, M. S., Eidhammer, T., and Rogers, D. C.: Predicting global atmospheric ice nuclei distributions and their impacts on climate, P. Natl. Acad. Sci., 107, 11217–11222, http://dx.doi.org/10.1073/pnas.0910818107doi:10.1073/pnas.0910818107, 2010. </mixed-citation>
</ref>
<ref id="ref22">
<label>22</label><mixed-citation publication-type="other" xlink:type="simple"> Diehl, K. and Wurzler, S.: Heterogeneous drop freezing in the immersion mode: Model calculations considering soluble and insoluble particles in the drops, J. Atmos. Sci., 61, 2063–2072, 2004. </mixed-citation>
</ref>
<ref id="ref23">
<label>23</label><mixed-citation publication-type="other" xlink:type="simple"> Diehl, K., Matthias-Maser, S., Jaenicke, R., and Mitra, S. K.: The ice nucleating ability of pollen:: Part II. Laboratory studies in immersion and contact freezing modes, Atmos. Res., 61, 125–133, http://dx.doi.org/10.1016/s0169-8095(01)00132-6doi:10.1016/s0169-8095(01)00132-6, 2002. </mixed-citation>
</ref>
<ref id="ref24">
<label>24</label><mixed-citation publication-type="other" xlink:type="simple"> Eidhammer, T., DeMott, P. J., and Kreidenweis, S. M.: A comparison of heterogeneous ice nucleation parameterizations using a parcel model framework, J. Geophys. Res., 114, D06202, http://dx.doi.org/10.1029/2008JD011095doi:10.1029/2008JD011095, 2009. </mixed-citation>
</ref>
<ref id="ref25">
<label>25</label><mixed-citation publication-type="other" xlink:type="simple"> Ervens, B., Feingold, G., Sulia, K., and Harrington, J.: The impact of microphysical parameters, ice nucleation mode, and habit growth on the ice/liquid partitioning in mixed-phase Arctic clouds, J. Geophys. Res., 116, D17,D17205, http://dx.doi.org/10.1029/2011jd015729doi:10.1029/2011jd015729, 2011. </mixed-citation>
</ref>
<ref id="ref26">
<label>26</label><mixed-citation publication-type="other" xlink:type="simple"> Field, P. R., Heymsfield, A. J., Shipway, B. J., DeMott, P. J., Pratt, K. A., Rogers, D. C., Stith, J., and Prather, K. A.: Ice in Clouds Experiment – Layer Clouds. Part 2: Testing characteristics of heterogeneous ice formation in lee wave clouds, J. Atmos. Sci., 69, 1066–1079, http://dx.doi.org/10.1175/jas-d-11-026.1doi:10.1175/jas-d-11-026.1, 2011. </mixed-citation>
</ref>
<ref id="ref27">
<label>27</label><mixed-citation publication-type="other" xlink:type="simple"> Fletcher, N. H.: Size effects in heterogeneous nucleation, J. Chem. Phys., 29, 572–576, 1958. </mixed-citation>
</ref>
<ref id="ref28">
<label>28</label><mixed-citation publication-type="other" xlink:type="simple"> Fletcher, N. H.: Active sites and ice nucleation, J. Atmos. Sci., 26, 1266–1271, 1969. </mixed-citation>
</ref>
<ref id="ref29">
<label>29</label><mixed-citation publication-type="other" xlink:type="simple"> Fridlind, A. M., Ackermann, A. S., McFarquhar, G., Zhang, G., Poellot, M. R., DeMott, P. J., Prenni, A. J., and Heymsfield, A. J.: Ice properties of single-layer stratocumulus clouds during the Mixed-Phase Arctic Cloud Experiment: 2. Model results, J. Geophys. Res., 112, D24202, http://dx.doi.org/10.1029/2007JD008646doi:10.1029/2007JD008646, 2007. </mixed-citation>
</ref>
<ref id="ref30">
<label>30</label><mixed-citation publication-type="other" xlink:type="simple"> Fukuta, N.: Experimental studies of organic ice nuclei, J. Atmos. Sci., 23, 191–196, 1966. </mixed-citation>
</ref>
<ref id="ref31">
<label>31</label><mixed-citation publication-type="other" xlink:type="simple"> Fukuta, N. and Schaller, R. C.: Ice Nucleation by Aerosol Particles. Theory of Condensation-Freezing Nucleation, J. Atmos. Sci., 39, 648–655, http://dx.doi.org/10.1175/1520-0469(1982)039&lt;0648:inbapt&gt;2.0.co;2doi:10.1175/1520-0469(1982)039&lt;0648:inbapt&gt;2.0.co;2, 1982. </mixed-citation>
</ref>
<ref id="ref32">
<label>32</label><mixed-citation publication-type="other" xlink:type="simple"> Gorbunov, B., Baklanov, A., Kakutkina, N., Windsor, H. L., and Toumi, R.: Ice nucleation on soot particles, J. Aerosol Sci., 32, 199–215, http://dx.doi.org/10.1016/s0021-8502(00)00077-xdoi:10.1016/s0021-8502(00)00077-x, 2001. </mixed-citation>
</ref>
<ref id="ref33">
<label>33</label><mixed-citation publication-type="other" xlink:type="simple"> Hallett, J. and Mason, B. J.: The Influence of Temperature and Supersaturation on the Habit of Ice Crystals Grown from the Vapour, P. Roy. Soc. Lond. A Math., 247, 440–453, 1958. </mixed-citation>
</ref>
<ref id="ref34">
<label>34</label><mixed-citation publication-type="other" xlink:type="simple"> Harrington, J. Y., Reisin, T., Cotton, W. R., and Kreidenweis, S. M.: Exploratory cloud resolving simulations of arctic stratus. Part II: Transition-season clouds, Atmos. Res., 51, 45–75, 1999. </mixed-citation>
</ref>
<ref id="ref35">
<label>35</label><mixed-citation publication-type="other" xlink:type="simple"> Hobbs, P. V. and Rangno, A. L.: Ice Particle Concentrations in Clouds, J. Atmos. Sci., 42, 2523–2549, http://dx.doi.org/10.1175/1520-0469(1985)042&lt;2523:ipcic&gt;2.0.co;2doi:10.1175/1520-0469(1985)042&lt;2523:ipcic&gt;2.0.co;2, 1985. </mixed-citation>
</ref>
<ref id="ref36">
<label>36</label><mixed-citation publication-type="other" xlink:type="simple"> Hoose, C., Kristjansson, J. E., Chen, J.-P., and Hazra, A.: A Classical-Theory-Based Parameterization of Heterogeneous Ice Nucleation by Mineral Dust, Soot, and Biological Particles in a Global Climate Model, J. Atmos. Sci., 67, 2483–2503, http://dx.doi.org/10.1175/2010JAS3425.1doi:10.1175/2010JAS3425.1, 2010. </mixed-citation>
</ref>
<ref id="ref37">
<label>37</label><mixed-citation publication-type="other" xlink:type="simple"> Jeffery, C. A. and Austin, P. H.: Homogeneous nucleation of supercooled water: Results from a new equation of state, J. Geophys. Res., 102, 25269–25279, 1997. </mixed-citation>
</ref>
<ref id="ref38">
<label>38</label><mixed-citation publication-type="other" xlink:type="simple"> Khvorostyanov, V. I. and Curry, J. A.: A new theory of heterogeneous ice nucleation for application on cloud and climate models, Geophys. Res. Lett., 27, 4081–4084, 2000. </mixed-citation>
</ref>
<ref id="ref39">
<label>39</label><mixed-citation publication-type="other" xlink:type="simple"> Khvorostyanov, V. I. and Curry, J. A.: The theory of ice nucleation by heterogeneous freezing of deliquescent mixed CCN: Part I: Critical radius, energy, and nucleation rate, J. Atmos. Sci., 61, 2676–2691, 2004. </mixed-citation>
</ref>
<ref id="ref40">
<label>40</label><mixed-citation publication-type="other" xlink:type="simple"> Khvorostyanov, V. I. and Curry, J. A.: The theory of ice nucleation by heterogeneous freezing of deliquescent mixed CCN: Part II: Parcel model studies, J. Atmos. Sci., 62, 261–285, 2005. </mixed-citation>
</ref>
<ref id="ref41">
<label>41</label><mixed-citation publication-type="other" xlink:type="simple"> Korolev, A. and Isaac, G.: Phase transformation in mixed phase clouds, Q. J. Roy. Meteor. Soc., 129, 19–38, 2003. </mixed-citation>
</ref>
<ref id="ref42">
<label>42</label><mixed-citation publication-type="other" xlink:type="simple"> Kulkarni, G. and Dobbie, S.: Ice nucleation properties of mineral dust particles: determination of onset RH$_i$, IN active fraction, nucleation time-lag, and the effect of active sites on contact angles, Atmos. Chem. Phys., 10, 95–105, http://dx.doi.org/10.5194/acp-10-95-2010doi:10.5194/acp-10-95-2010, 2010. </mixed-citation>
</ref>
<ref id="ref43">
<label>43</label><mixed-citation publication-type="other" xlink:type="simple"> Kulkarni, G., Fan, J., Comstock, J. M., Liu, X., and Ovchinnikov, M.: Laboratory measurements and model sensitivity studies of dust deposition ice nucleation, Atmos. Chem. Phys. Discuss., 12, 2483–2516, http://dx.doi.org/10.5194/acpd-12-2483-2012doi:10.5194/acpd-12-2483-2012, 2012. </mixed-citation>
</ref>
<ref id="ref44">
<label>44</label><mixed-citation publication-type="other" xlink:type="simple"> Kumai, M.: Electron microscope study of snow-crystal nuclei, J. Meteorol., 8, 151–156, http://dx.doi.org/10.1175/1520-0469(1951)008&lt;0151:emsosc&gt;2.0.co;2doi:10.1175/1520-0469(1951)008&lt;0151:emsosc&gt;2.0.co;2, 1951. </mixed-citation>
</ref>
<ref id="ref45">
<label>45</label><mixed-citation publication-type="other" xlink:type="simple"> Lamb, D. and Verlinde, H.: Physics and Chemistry of Clouds, 1st Edn., University Press, Cambridge, 584 pp., 2011. </mixed-citation>
</ref>
<ref id="ref46">
<label>46</label><mixed-citation publication-type="other" xlink:type="simple"> Lance, S., Shupe, M. D., Feingold, G., Brock, C. A., Cozic, J., Holloway, J. S., Moore, R. H., Nenes, A., Schwarz, J. P., Spackman, J. R., Froyd, K. D., Murphy, D. M., Brioude, J., Cooper, O. R., Stohl, A., and Burkhart, J. F.: Cloud condensation nuclei as a modulator of ice processes in Arctic mixed-phase clouds, Atmos. Chem. Phys., 11, 8003–8015, http://dx.doi.org/10.5194/acp-11-8003-2011doi:10.5194/acp-11-8003-2011, 2011. </mixed-citation>
</ref>
<ref id="ref47">
<label>47</label><mixed-citation publication-type="other" xlink:type="simple"> Langham, E. J. and Mason, B. J.: The Heterogeneous and Homogeneous Nucleation of Supercooled Water, P. Roy. Soc. Lond. A Math., 247, 493–504, 1958. </mixed-citation>
</ref>
<ref id="ref48">
<label>48</label><mixed-citation publication-type="other" xlink:type="simple"> Lüönd, F., Stetzer, O., Welti, A., and Lohmann, U.: Experimental study on the ice nucleation ability of size-selected kaolinite particles in the immersion mode, J. Geophys. Res., 115, D14201, http://dx.doi.org/10.1029/2009jd012959doi:10.1029/2009jd012959, 2010. </mixed-citation>
</ref>
<ref id="ref49">
<label>49</label><mixed-citation publication-type="other" xlink:type="simple"> Marcolli, C., Gedamke, S., Peter, T., and Zobrist, B.: Efficiency of immersion mode ice nucleation on surrogates of mineral dust, Atmos. Chem. Phys., 7, 5081–5091, http://dx.doi.org/10.5194/acp-7-5081-2007doi:10.5194/acp-7-5081-2007, 2007. </mixed-citation>
</ref>
<ref id="ref50">
<label>50</label><mixed-citation publication-type="other" xlink:type="simple"> Mason, B. J.: The growth of ice crystals in a supercooled water cloud, Q. J. Roy. Meteorol. Soc., 79, 441–441, http://dx.doi.org/10.1002/qj.49707934121doi:10.1002/qj.49707934121, 1953. </mixed-citation>
</ref>
<ref id="ref51">
<label>51</label><mixed-citation publication-type="other" xlink:type="simple"> McDonald, J. E.: Use of the electrostatic analogy in studies of ice crystal growth, Z. Angew. Math. Phys., 14, 610–619, 1963. </mixed-citation>
</ref>
<ref id="ref52">
<label>52</label><mixed-citation publication-type="other" xlink:type="simple"> McFarquhar, G., Zhang, G., Poellot, M. R., Kok, G. L., McCoy, R., Tooman, T., Fridlind, A. M., and Heymsfield, A. J.: Ice properties of single-layer stratocumulus clouds during the Mixed-Phase Arctic Cloud Experiment: 1. Observations, J. Geophys. Res., 112, D24202, http://dx.doi.org/10.1029/2007JD008633doi:10.1029/2007JD008633, 2007. </mixed-citation>
</ref>
<ref id="ref53">
<label>53</label><mixed-citation publication-type="other" xlink:type="simple"> Meyers, M., DeMott, P. J., and Cotton, W. R.: New primary ice-nucleation parameterizations in an explicit cloud model, J. Appl. Meteorol., 31, 708–720, 1992. </mixed-citation>
</ref>
<ref id="ref54">
<label>54</label><mixed-citation publication-type="other" xlink:type="simple"> Möhler, O., Field, P. R., Connolly, P., Benz, S., Saathoff, H., Schnaiter, M., Wagner, R., Cotton, R., Krämer, M., Mangold, A., and Heymsfield, A. J.: Efficiency of the deposition mode ice nucleation on mineral dust particles, Atmos. Chem. Phys., 6, 3007–3021, http://dx.doi.org/10.5194/acp-6-3007-2006doi:10.5194/acp-6-3007-2006, 2006. </mixed-citation>
</ref>
<ref id="ref55">
<label>55</label><mixed-citation publication-type="other" xlink:type="simple"> Morrison, H., Shupe, M. D., Pinto, J. O., and Curry, J. A.: Possible roles of ice nucelation mode and ice nuclei depletion in the extended lifetime of Arctic mixed-phase clouds, Geophys. Res. Lett., 32, L18801, http://dx.doi.org/10.1029/2005GL023614doi:10.1029/2005GL023614, 2005. </mixed-citation>
</ref>
<ref id="ref56">
<label>56</label><mixed-citation publication-type="other" xlink:type="simple"> Morrison, H., Pinto, J. O., Curry, J. A., and McFarquhar, G. M.: Sensitivity of modeled Arctic mixed-phase stratocumulus to cloud condensation and ice nuclei over regionally varying surface conditions, J. Geophys. Res., 113, D05203, http://dx.doi.org/10.1029/2007JD008729doi:10.1029/2007JD008729, 2008. </mixed-citation>
</ref>
<ref id="ref57">
<label>57</label><mixed-citation publication-type="other" xlink:type="simple"> Morrison, H., de Boer, G., Feingold, G., Harrington, J., Shupe, M. D., and Sulia, K.: Resilience of persistent Arctic mixed-phase clouds, Nat. Geosci., 5, 11–17, 2012. </mixed-citation>
</ref>
<ref id="ref58">
<label>58</label><mixed-citation publication-type="other" xlink:type="simple"> Murray, B. J., Wilson, T. W., Dobbie, S., Cui, Z., Al-Jumur, S. M. R. K., Mohler, O., Schnaiter, M., Wagner, R., Benz, S., Niemand, M., Saathoff, H., Ebert, V., Wagner, S., and Karcher, B.: Heterogeneous nucleation of ice particles on glassy aerosols under cirrus conditions, Nat. Geosci., 3, 233–237, 2010. </mixed-citation>
</ref>
<ref id="ref59">
<label>59</label><mixed-citation publication-type="other" xlink:type="simple"> Murray, B. J., Broadley, S. L., Wilson, T. W., Atkinson, J. D., and Wills, R. H.: Heterogeneous freezing of water droplets containing kaolinite particles, Atmos. Chem. Phys., 11, 4191–4207, http://dx.doi.org/10.5194/acp-11-4191-2011doi:10.5194/acp-11-4191-2011, 2011. </mixed-citation>
</ref>
<ref id="ref60">
<label>60</label><mixed-citation publication-type="other" xlink:type="simple"> Niedermeier, D., Hartmann, S., Shaw, R. A., Covert, D., Mentel, T. F., Schneider, J., Poulain, L., Reitz, P., Spindler, C., Clauss, T., Kiselev, A., Hallbauer, E., Wex, H., Mildenberger, K., and Stratmann, F.: Heterogeneous freezing of droplets with immersed mineral dust particles – measurements and parameterization, Atmos. Chem. Phys., 10, 3601–3614, http://dx.doi.org/10.5194/acp-10-3601-2010doi:10.5194/acp-10-3601-2010, 2010. </mixed-citation>
</ref>
<ref id="ref61">
<label>61</label><mixed-citation publication-type="other" xlink:type="simple"> Niedermeier, D., Shaw, R. A., Hartmann, S., Wex, H., Clauss, T., Voigtländer, J., and Stratmann, F.: Heterogeneous ice nucleation: exploring the transition from stochastic to singular freezing behavior, Atmos. Chem. Phys., 11, 8767–8775, http://dx.doi.org/10.5194/acp-11-8767-2011doi:10.5194/acp-11-8767-2011, 2011. </mixed-citation>
</ref>
<ref id="ref62">
<label>62</label><mixed-citation publication-type="other" xlink:type="simple"> Niemand, M., Möhler, O., Vogel, B., Vogel, H., Hoose, C., Connolly, P., Klein, H., Bingemer, H., DeMott, P., Skrotzki, J., and Leisner, T.: A particle-surface-area-based parameterization of immersion freezing on desert dust particles, J. Atmos. Sci., http://dx.doi.org/10.1175/jas-d-11-0249.1doi:10.1175/jas-d-11-0249.1, in press, 2012. </mixed-citation>
</ref>
<ref id="ref63">
<label>63</label><mixed-citation publication-type="other" xlink:type="simple"> Penner, J. E., Chen, Y., Wang, M., and Liu, X.: Possible influence of anthropogenic aerosols on cirrus clouds and anthropogenic forcing, Atmos. Chem. Phys., 9, 879–896, http://dx.doi.org/10.5194/acp-9-879-2009doi:10.5194/acp-9-879-2009, 2009. </mixed-citation>
</ref>
<ref id="ref64">
<label>64</label><mixed-citation publication-type="other" xlink:type="simple"> Phillips, V. T. J., DeMott, P. J., and Andronache, C.: An empirical parameterization of heterogeneous ice nucleation for multiple chemical species of aerosol, J. Atmos. Sci., 65, 2757–2783, 2008. </mixed-citation>
</ref>
<ref id="ref65">
<label>65</label><mixed-citation publication-type="other" xlink:type="simple"> Pinti, V., Marcolli, C., Zobrist, B., Hoyle, C. R., and Peter, T.: Ice nucleation efficiency of clay minerals in the immersion mode, Atmos. Chem. Phys. Discuss., 12, 3213–3261, http://dx.doi.org/10.5194/acpd-12-3213-2012doi:10.5194/acpd-12-3213-2012, 2012. </mixed-citation>
</ref>
<ref id="ref66">
<label>66</label><mixed-citation publication-type="other" xlink:type="simple"> Popovicheva, O., Kireeva, E., Persiantseva, N., Khokhlova, T., Shonija, N., Tishkova, V., and Demirdjian, B.: Effect of soot on immersion freezing of water and possible atmospheric implications, Atmos. Res., 90, 326–337, http://dx.doi.org/10.1016/j.atmosres.2008.08.004doi:10.1016/j.atmosres.2008.08.004, 2008. </mixed-citation>
</ref>
<ref id="ref67">
<label>67</label><mixed-citation publication-type="other" xlink:type="simple"> Roberts, P. and Hallett, J.: A laboratory study of the ice nucleating properties of some mineral particulates, Q. J. Roy. Meteor. Soc., 94, 25–34, http://dx.doi.org/10.1002/qj.49709439904doi:10.1002/qj.49709439904, 1968. </mixed-citation>
</ref>
<ref id="ref68">
<label>68</label><mixed-citation publication-type="other" xlink:type="simple"> Schnell, R. C. and Vali, G.: Biogenic ice nuclei: Part I. Terrestrial and marine sources, J. Atmos. Sci., 33, 1554–1564, 1976. </mixed-citation>
</ref>
<ref id="ref69">
<label>69</label><mixed-citation publication-type="other" xlink:type="simple"> Shaw, R. A., Durant, A. J., and Mi, Y.: Heterogeneous Surface Crystallization Observed in Undercooled Water, J. Phys. Chem. B, 109, 9865–9868, http://dx.doi.org/10.1021/jp0506336doi:10.1021/jp0506336, 2005. </mixed-citation>
</ref>
<ref id="ref70">
<label>70</label><mixed-citation publication-type="other" xlink:type="simple"> Solomon, S., Qin, D., Manning, M., Chen, Z., Marquis, M., Averyt, K. B., Tignor, M., and Miller, H. L.: Climate Change 2007 – The Physical Science Basis, Contribution of Working Group I to the Fourth Assessment Report of the IPCC, Intergovernmental Panel on Climate Change, Cambridge, United Kingdom and New York, NY, USA, 2007. </mixed-citation>
</ref>
<ref id="ref71">
<label>71</label><mixed-citation publication-type="other" xlink:type="simple"> Sulia, K. J. and Harrington, J. Y.: Ice aspect ratio influences on mixed-phase clouds: Impacts on phase partitioning in parcel models, J. Geophys. Res., 116, D21309, http://dx.doi.org/10.1029/2011jd016298doi:10.1029/2011jd016298, 2011. </mixed-citation>
</ref>
<ref id="ref72">
<label>72</label><mixed-citation publication-type="other" xlink:type="simple"> Takahashi, T., Endoh, T., Wakahama, G., and Fukuta, N.: Vapor diffusional growth of freefalling snow crystals between −3 and −23 °C, J. Meteorol. Soc. Jpn., 69, 15–30, 1991. </mixed-citation>
</ref>
<ref id="ref73">
<label>73</label><mixed-citation publication-type="other" xlink:type="simple"> Vali, G.: Quantitative Evaluation of Experimental Results an the Heterogeneous Freezing Nucleation of Supercooled Liquids, J. Atmos. Sci., 28, 402–409, http://dx.doi.org/10.1175/1520-0469(1971)028&lt;0402:QEOERA&gt;2.0.CO;2doi:10.1175/1520-0469(1971)028&lt;0402:QEOERA&gt;2.0.CO;2, 1971. \hack </mixed-citation>
</ref>
<ref id="ref74">
<label>74</label><mixed-citation publication-type="other" xlink:type="simple"> Vali, G.: Freezing rate due to heterogeneous nucleation, J. Atmos. Sci., 51, 1843–1856, 1994. </mixed-citation>
</ref>
<ref id="ref75">
<label>75</label><mixed-citation publication-type="other" xlink:type="simple"> Vali, G.: Repeatability and randomness in heterogeneous freezing nucleation, Atmos. Chem. Phys., 8, 5017–5031, http://dx.doi.org/10.5194/acp-8-5017-2008doi:10.5194/acp-8-5017-2008, 2008. </mixed-citation>
</ref>
<ref id="ref76">
<label>76</label><mixed-citation publication-type="other" xlink:type="simple"> Vali, G. and Stansbury, E. J.: Time-dependent characteristics of the heterogenous nucleation of ice, Can. J. Phys., 44, 477–502, 1966. </mixed-citation>
</ref>
<ref id="ref77">
<label>77</label><mixed-citation publication-type="other" xlink:type="simple"> Vonnegut, B. and Baldwin, M.: Repeated Nucleation of a Supercooled Water Sample that Contains Silver Iodide Particles, J. Clim. Appl. Meteorol., 23, 486–490, http://dx.doi.org/10.1175/1520-0450(1984)023&lt;0486:rnoasw&gt;2.0.co;2doi:10.1175/1520-0450(1984)023&lt;0486:rnoasw&gt;2.0.co;2, 1984. </mixed-citation>
</ref>
<ref id="ref78">
<label>78</label><mixed-citation publication-type="other" xlink:type="simple"> Wang, B. and Knopf, D. A.: Heterogeneous ice nucleation on particles composed of humic-like substances impacted by O&lt;sub&gt;3&lt;/sub&gt;, J. Geophys. Res., 116, D03205, http://dx.doi.org/10.1029/2010jd014964doi:10.1029/2010jd014964, 2011. </mixed-citation>
</ref>
<ref id="ref79">
<label>79</label><mixed-citation publication-type="other" xlink:type="simple"> Welti, A., Lüönd, F., Stetzer, O., and Lohmann, U.: Influence of particle size on the ice nucleating ability of mineral dusts, Atmos. Chem. Phys., 9, 6705–6715, http://dx.doi.org/10.5194/acp-9-6705-2009doi:10.5194/acp-9-6705-2009, 2009. </mixed-citation>
</ref>
<ref id="ref80">
<label>80</label><mixed-citation publication-type="other" xlink:type="simple"> Welti, A., Lüönd, F., Kanji, Z. A., Stetzer, O., and Lohmann, U.: Time dependence of immersion freezing, Atmos. Chem. Phys. Discuss., 12, 12623–12662, http://dx.doi.org/10.5194/acpd-12-12623-2012doi:10.5194/acpd-12-12623-2012, 2012. </mixed-citation>
</ref>
<ref id="ref81">
<label>81</label><mixed-citation publication-type="other" xlink:type="simple"> Wheeler, M. J. and Bertram, A. K.: Deposition nucleation on mineral dust particles: a case against classical nucleation theory with the assumption of a single contact angle, Atmos. Chem. Phys., 12, 1189–1201, http://dx.doi.org/10.5194/acp-12-1189-2012doi:10.5194/acp-12-1189-2012, 2012. </mixed-citation>
</ref>
<ref id="ref82">
<label>82</label><mixed-citation publication-type="other" xlink:type="simple"> Zobrist, B., Koop, T., Luo, B. P., Marcolli, C., and Peter, T.: Heterogeneous Ice Nucleation Rate Coefficient of Water Droplets Coated by a Nonadecanol Monolayer, J. Phys. Chem. C, 111, 2149–2155, 2007. </mixed-citation>
</ref>
</ref-list>
</back>
</article>