1Department of Chemical Engineering, Carnegie Mellon University, 5000 Forbes Ave, Pittsburgh, Pennsylvania 15213, USA
2Institute of Chemical Engineering Sciences (ICEHT), Foundation for Research and Technology Hellas (FORTH), Patras, Greece
3National Center for Atmospheric Science, Division of Environmental Health and Risk Management, School of Geography, Earth & Environmental Sciences University of Birmingham Edgbaston, Birmingham B15 2TT, UK
4School of Physics and Centre for Climate and Air Pollution Studies, National University of Ireland Galway, Galway, Ireland
5IEK-8II: Troposphere, Forschungszentrum Jülich, Jülich, Germany
6Department of Chemical Engineering, University of Patras, Patra, Greece
Received: 24 Feb 2012 – Discussion started: 18 Apr 2012
Abstract. Multigenerational oxidation chemistry of atmospheric organic compounds and its effects on aerosol loadings and chemical composition is investigated by implementing the Two-Dimensional Volatility Basis Set (2-D-VBS) in a Lagrangian host chemical transport model. Three model formulations were chosen to explore the complex interactions between functionalization and fragmentation processes during gas-phase oxidation of organic compounds by the hydroxyl radical. The base case model employs a conservative transformation by assuming a reduction of one order of magnitude in effective saturation concentration and an increase of oxygen content by one or two oxygen atoms per oxidation generation. A second scheme simulates functionalization in more detail using group contribution theory to estimate the effects of oxygen addition to the carbon backbone on the compound volatility. Finally, a fragmentation scheme is added to the detailed functionalization scheme to create a functionalization-fragmentation parameterization. Two condensed-phase chemistry pathways are also implemented as additional sensitivity tests to simulate (1) heterogeneous oxidation via OH uptake to the particle-phase and (2) aqueous-phase chemistry of glyoxal and methylglyoxal. The model is applied to summer and winter periods at three sites where observations of organic aerosol (OA) mass and O:C were obtained during the European Integrated Project on Aerosol Cloud Climate and Air Quality Interactions (EUCAARI) campaigns. The base case model reproduces observed mass concentrations and O:C well, with fractional errors (FE) lower than 55% and 25%, respectively. The detailed functionalization scheme tends to overpredict OA concentrations, especially in the summertime, and also underpredicts O:C by approximately a factor of 2. The detailed functionalization model with fragmentation agrees well with the observations for OA concentration, but still underpredicts O:C. Both heterogeneous oxidation and aqueous-phase processing have small effects on OA levels but heterogeneous oxidation, as implemented here, does enhance O:C by about 0.1. The different schemes result in very different fractional attribution for OA between anthropogenic and biogenic sources.
Revised: 20 Oct 2012 – Accepted: 23 Oct 2012 – Published: 16 Nov 2012
Murphy, B. N., Donahue, N. M., Fountoukis, C., Dall'Osto, M., O'Dowd, C., Kiendler-Scharr, A., and Pandis, S. N.: Functionalization and fragmentation during ambient organic aerosol aging: application of the 2-D volatility basis set to field studies, Atmos. Chem. Phys., 12, 10797-10816, doi:10.5194/acp-12-10797-2012, 2012.